天然黏土矿物和腐殖酸对纳米乳化油吸持的实验研究

为探讨天然黏土矿物及有机质对纳米乳化油在多孔介质中迁移滞留的影响，本文选取高岭石和蒙脱石这两种黏土矿物以及有机质的典型代表腐殖酸，开展了单一矿物、有机质及有机矿质复合物对纳米乳化油的吸持批实验研究，并运用比表面积全分析、扫描电镜(SEM)、傅里叶红外光谱(FTIR)、X射线衍射(XRD)等技术手段探讨了吸持机理。实验结果表明，介质对纳米乳化油的吸持均符合Freundlich模型；单一矿物及腐殖酸对纳米乳化油的吸持能力表现为：蒙脱石>腐殖酸>高岭石，有机矿质复合样品的吸持能力表现为：蒙脱石-腐殖酸>高岭石-腐殖酸，且均大于其对应的单一样品，出现了“1+1>2”的现象，表明介质组成越复杂，对纳米乳化油的吸持滞留程度越大。进一步分析证实，纳米乳化油主要通过氢键和疏水作用吸持在矿物和腐殖酸表面，表面结构性质是高岭石和蒙脱石吸持过程中的主导因素，因此蒙脱石具有更强的吸持能力，而腐殖酸的吸持主要通过颗粒间聚集作用来实现；对于复合样品，吸持主要通过氢键、配体交换和疏水作用结合来实现。腐殖酸与矿物的复合会增加吸持位点并且增强矿物表面疏水性，从而促进吸持。腐殖酸与纳米乳化油的共吸...     

Significance of selective crystal entrainment and differential crystal-melt separation in petrogenesis of granites from the Tongbai orogen

Partial melting has been shown to be an important mechanism for intracrustal differentiation and granite petrogenesis. However, a series of compositional differences between granitic melt from experiments and natural granites indicate that the processes of crustal differentiation are complex. To shed light on factors that control the processes of crustal differentiation, and then the compositions of granitic magma, a combined study of petrology and geochemistry was carried out for granites (in the forms of granitic veins and parautochthonous granite) from a granulite terrane in the Tongbai orogen, China. These granites are characterized by high SiO₂ (>72 wt%) and low FeO and MgO (<4 wt%) with low Na₂O/K₂O ratios (<0.7). Minerals in these granites show variable microstructures and compositions. Phase equilibrium modelling using P–T pseudosections shows that neither anatectic melts nor fractionated melts match the compositions of the target granites, challenging the conventional paradigm that granites are the crystallized product of pure granitic melts. Based on the microstructural features of minerals in the granites, and a comparison of their compositions with crystallized minerals from anatectic melts and minerals in granulites, the minerals in these granitoids are considered to have three origins. The first is entrained garnets, which show comparable compositions with those in host granulites. The second is early crystallized mineral from melts, which include large plagioclase and K-feldspar (with high Ca contents) crystals as well as a part of biotite whose compositions can be reproduced by crystallization of the anatectic melts. The compositions of other minerals such as small grained plagioclase, K-feldspar and anorthoclase in the granites with low Ca contents are not well reconstructed, so they are considered as the third origin of crystallized products of fractionated melts. The results of mass balance calculation show that the compositions of these granites can be produced by mixing between different proportions of crystallized minerals and fractionated melts with variable amounts of entrained minerals. However, the calculated modal proportions of different crystallized minerals (plagioclase, K-feldspar, biotite and quartz) in the granites are significantly different from those predicted by melt crystallization modelling. Specifically, some rocks have lower modes of biotite and plagioclase, whereas others show lower K-feldspar modes than those produced by melt crystallization. This indicates that the crystallized minerals would be differentially separated from the primary magmas to form the evolved magmas that produce these granites. Therefore, the crystal entrainment and differential melt-crystal separation make important contributions to the composition of the target granites. Compared with leucogranites worldwide, the target granites show comparable compositions. As such, the leucogranites may form through the crystal fractionation of primary granitic magmas at different extents in addition to variable degrees of partial melting.     

坦桑尼亚纳钦圭阿石墨成矿带地质特征及成因初析

纳钦圭阿石墨成矿带位于坦桑尼亚南部林迪—姆特瓦拉地区,近年来发现一系列大型、超大型优质晶质石墨矿,尚未见系统报道.该成矿带东西宽约40 km,南北长约120 km,区域岩性为一套中高变质的片麻岩、片岩、石英岩、大理岩、角闪岩等,局部混合岩化强烈.地层呈NE-NEE向展布,局部平卧褶皱、鞘褶皱等发育,断裂构造以NE向为主...     

双频毫米波雷达反演云微物理参数的模拟研究北大核心

根据雷达探测的云回波雷达反射率因子和多普勒速度,利用两种独立的双频反演算法,估算了云微物理参数。利用离散偶极子近似(Discrete Dipole Approximation,DDA)计算了云滴后向散射截面和衰减截面,根据模拟数据实验了三种频段组合的反演结果,探讨算法对滴谱参数、粒子形状的敏感性,比较两种方法反演水云和冰云的优劣。结果表明:双频比(Dual-Frequency Ratio,DFR)和多普勒速度差(Doppler Difference of Velocity,DDV)在水云中都可独立推导中值直径(D_(0)),但在高频波段,基于DFR的算法对雨、云水和水汽的衰减非常敏感,而基于DDV的方法受衰减的影响较小。鉴于高频波段衰减完全订正的困难性,水云的DDV反演方法比DFR更直接准确。对于冰云,DFR的技术相较于DDV的方法具有明显的优势,因为两频段处的DFR在冰云中的动态范围更大,而DDV的动态范围相对于系统和测量误差较小。