纤维滤池在石化废水深度处理中的应用

针对华锦集团废水处理及回用工程采用纤维滤池深度处理化工混合废水技术,使其出水达到《城镇污水处理厂污染物排放标准》(GB18918—2002)一级A排放标准,研究主要对纤维滤池的原理、设计参数、运行效果等进行实践探讨。运行结果表明:在稳定运行阶段,可实现进水量2 100 m3/h。进水化学需氧量(CODCr)平均浓度为50 mg/L,悬浮物(SS)浓度为15 mg/L,浊度平均浓度为15 mg/L,处理出水CODCr≤30 mg/L、SS≤10 mg/L、浊度≤10 mg/L。该工艺处理效果稳定,对SS和浊度处理效果显著。     

南充市人工湿地的规划研究

通过对传统污水处理的生化二级处理系统与人工湿地污水处理系统分析和比较，可以看出污水处理厂具有投资大、运行成本费高、并难以解决水质“富营养化”的缺点，而人工湿地污水处理系统具有投资少、运行成本低、出水质量好的优点。根据南充城市化进程的具体形势，提出在规划和建设生态城市方案中，建设人工湿地污水处理系统的设想，并就人工湿地的规模、区位选择、活水公园设计、预期效益分析等问题进行了详细的论证和阐述。     

Impacts of wastewater irrigation on soils and crops in suburban area of Shiraz, Iran

This preliminary work reported here dealt with potential impacts of wastewater irrigation on soils and crops sampled along the Koshk River canal in the suburban area of Shiraz City, Iran. It also attempts to assess the extent of heavy metal contamination in soils and crops and human exposure risk. For this purpose, samples including soils and plants were collected from two wastewater irrigated sites and a tubewell-irrigated site （marked by A, B and C）. Concentrations of the six heavy metals Ni, Pb, Cd, Zn, Cr and Cu were determined by AAS. Physical and chemical properties of soil samples were also determined. The PLIs and CF for soils and HQ （Hazard quotient） for some vegetables were calculated. The results showed that organic matter content increased from 22% to 30 % in wastewater-irrigated soils as compared to tubewell water irrigated and admixture water irrigated ones. The soil pH was raised by 2 units as a result of wastewater irrigation at site A compared to sites B and C. Wastewater irrigation also result in relatively high concentrations of Ni, Pb and Zn （275.5, 441.3 and 177 mg/kg, respectively） in wastewater irrigated soils over tubewell water irrigated soils. These levels are higher than the maximum permissible limits in unpolluted soils, indicating that a degree of contamination has occurred. This was confirmed by calculated PLIs and contamination factors in soil samples, The results also showed some crops cultivated at sites A and B contained high levels of Ni and Cd beyond the maximum permissible concentrations and those cultivated at site C. The concentrations of these heavy metals are within or very close to the critical levels. HQ indices and daily intake calculated in respect of metal contents in some vegetables （spinach, lettuce and celery） showed that toxic risk due to Cd in these vegetables and crops was greater than one. This study generally concludes that although the content of heavy metals did not reach toxic level, extensive use of untreated wastewater drawn from the Koshk River has obviously increased the contamination of Ni and Pb in soils and Cd in some vegetables cultivated along the canal, causing potential health risk in the long-term scense for consumers or local residents.     

Pretreatment of diosgenin wastewaters using polyferric sulfate as a main coagulant

Diosgenin is produced from Dioscrea L, mainly using D.zingiberensis as the raw material. During the process, particularly in the process of acidic hydrolysis, large quantities of high-strength wastewaters are discharged. The waste liquids are characteristic of strong acidity, usually with pH value less than 1, and high concentrations of organic matter with average CODcr （chemical organic demand） in the range of 20000-3000 mg/L. Without proper treatment, their free disposal would pose serious threat to natural ecosystem and cause considerable environmental problems. Since diosgenin wastewaters contain high load organics and acidity, appropriate pretreatment is needed before they are biologically degraded. Coagulation is a common method for eliminating colloid particles and/or high molecule organic chemicals from wastewaters. Poly-ferric sulfate is found to be most effective in removing organic matter. The objective of this study is to investigate the effectiveness and feasibility of poly-ferric sulfate to reduce CODcr and turbidity from diosgenin wastewaters. Due to its high acidic nature, the pH value of diosgenin wastewater was neutralized with Ca（OH）2 solution before being coagulated. Various factors that influence the coagulation process, such as pH value, the dosage of poly-ferric sulfate, polyelectrolyte aids and mixing conditions were examined in the experiments.     

Disposal of wastewater containing Congo Red by synthesizing layer double hydroxide in-situ

Based on the principle of synthesis, a new method was put forward to dispose Congo Red anion-containing dyestuff from wastewater and its feasibility was also examined. The principle of the method is described as follows： Mg^2＋ and Al^3＋ are hydrolyzed to form Mg/Al-LDH by adding Mg^2＋, Al^3＋ and NaOH in wastewater containing anion dyestuff, which is selectively intercalated with the interlayer of LDH in order to balance positive structural charge. While Mg^2＋ and Al^3＋ are co-precipitated to form LDH, the anion dyestuff in wastewater will be removed by LDH synthesized in-situ, as is confirmed by X-ray diffraction analysis of settlings and chemical analysis of aqueous samples. In this work, we studied the influence of Mg/Al mole ratio, pH value, time and temperature of reaction on the removal of anion dyestuff and the use of Mg and Al. The experimental results showed the maximum removal efficiency of anion dyestuff could be attained when pH value was 9.0, and Mg/Al mol ratio was 2 ： 1, reaction duration was 2 hours, and the effect of temperature was not remarkable, and the removal efficiency could reach 100%. Meanwhile, the Mg and Al added could be made good use of. This technology has the advantage of extraordinary efficiency of wastewater disposal.     

Lead removal from wastewater using faujasite tuff

The Jordanian chabazite-phillipsite tuff and faujasite-phillipsite tuff have suitable mineralogical and technical properties that enable them to be used for ion-exchange processes. These include suitable grain size and total cation exchange capacity, acceptable zeolite content, good attrition resistance and high packed-bed density. The chabazite-phillipsite tuff (ZE1 and ZE2) has an excellent efficiency to remove Pb and an acceptable efficiency to remove Fe, Cu, Zn and Ni from effluent wastewater of a battery factory and other industries. The faujasite-phillipsite tuff (ZE3) is 6.97 times more efficient than the ZE1 and ZE2. A bed of ZE3 (1,000 kg) loaded in a 1.17-m³ column is capable of cleaning about 2,456 m³ of the effluent from the factory at a cost of US $200/ton. The wastewater is contaminated with 20 ppm Pb in the presence of competing ions including Ca (210 ppm), Na (1,950 ppm) and Fe (169 ppm). This quantity of wastewater is equivalent to 120 working days of effluent discharge from the factory at a flow rate of 20 m³/day.     

利用13X沸石分子筛净化含Pb~(2+)废水的实验研究

采用静态间歇法 ,实验研究了含Pb2 +废水的 pH值及吸附时间对 13X沸石分子筛吸附Pb2 +性能的影响 ,得出了最佳去除效果的优化条件为 :废水的 pH值接近中性 ,吸附时间 10min。通过吸附实验 ,确定了在Pb2 +初始浓度为 2 0mg/L的条件下 ,13X沸石对Pb2 +的吸附量为 2 1 4 2mg/g ,即每克沸石净化含Pb2 +废水的最大体积量约为 75 0mL。解析实验表明 ,加入沉淀剂 ,浓缩洗脱液中的Pb2 +即以PbS的形式生成沉淀 ,为回收金属铅提供了可能 ;13X沸石在循环使用 5次的条件下 ,对废水中Pb2 +的吸附率仍高达 98% ,重复使用性能良好。经处理后的净化水中Pb2 +的浓度小于 0 4mg/L ,显著低于国家废水排放标准GB8978 88的指标 ( 1 0mg/L)。 13X沸石对Pb2 +的主要吸附形式是离子交换和表面络合反应。     

C/B法城镇污水处理技术简介

目前我国城市污水处理普遍采用的工艺为普通活性污泥法、氧法沟法、SBR法及AB法等。这些工艺虽然运行稳定，达到可靠，但投资大、运行费用高。鉴于我国的经济发展水平与发达国家有较大的差距，污染治理的资金投入有限，提出必须研究适合我国国情的高效、低耗、低成本的城市污水处理技术。阐述了C/B法的C段和B段污水处理技术，指出由于该技术是化学强化处理技术与生物滤池技术的有机结合，综合了化学处理与生物处理技术的优点，具有可分阶段实施、投资省、运行费用低、占地少、有效去除磷、氨、氮等优点。     

高浓度有机废水化学和物理法处理技术综述

介绍国内外高浓度有机废水应用化学和物理方法处理技术进展 ,通过比较各种化学和物理方法的优缺点 ,得出探讨性结论 ,即采用一种方法难以完全处理高浓度有机废水 ,需经二段或三段处理方法处理后 ,才能达到排污标准。     

红树林湿地系统污染生态及其净化效果的研究概况

红树林湿地系统处于淡水和海水的交互地带,具有净化水体的功能。随着大量污水、废物源源不断地排放入海,红树林湿地的水体净化功能正日益受到重视。综合国内外学者的相关研究成果,对红树林湿地系统的污染生态及其净化效果方面的研究概况进行了综述。目前,红树林湿地系统污染生态的研究主要集中在不同污染物的排放对红树林及生态环境的影响上,包括对红树植物的生长和生理生态的影响,污染物在红树植物中的累积以及污染物对红树林区沉积物、藻类、底栖动物的影响等方面上。研究结果表明,红树林对重金属、石油及污水等污染物有较强的耐性,且红树林植物和林下的土壤都有吸收多种污染物的能力,对污染物有较强的净化效果。红树林湿地系统的研究还有待于进一步深入,红树林湿地资源处于濒危状态,需加强管理和保护,所有的实验项目应在非保护区中进行。