胶东郭家岭花岗闪长岩U--Pb年代学、地球化学特征及地质意义

郭家岭花岗闪长岩岩石地球化学特征表明其SiO2含量较高,为71.3%~73.28%,K2O=2.14%~4.29%,属于高钾钙碱性--钙碱性I型花岗岩。锆石LA--ICP--MS U--Pb年龄显示郭家岭花岗岩体成岩年龄为127.9±1.3 Ma,属早白垩世。岩石的Rb/Sr和Nb/Ta比值,以及暗色闪长质包体研究表明郭家岭花岗闪长岩为壳幔混合源,岩浆源区为具有幔源特征的新生镁铁质下地壳。结合区域地质分析认为郭家岭花岗闪长岩的形成与太平洋板块俯冲引起的大陆弧伸展作用最密切。     

内蒙古科右中旗地区梅勒图组安山岩年代学特征及其地质意义

对内蒙古科右中旗地区梅勒图组安山岩锆石LA--ICP--MS U--Pb年代学、锆石Hf同位素和岩石地球化学测试分析结果表明,梅勒图组安山岩形成时代约为早白垩世中期(123~125 Ma)。锆石εHf(t)=(+5.84~+9.34),一阶段Hf模式年龄为412~553 Ma。岩石地球化学分析表明,安山岩K2O含量较高,SiO2含量和Mg#值中等,富集大离子亲石元素,高场强元素Nb、Ta、Ti等明显亏损。这些特征反映出梅勒图组安山岩的源区为新形成的富集地幔。结合地球化学特征和区域大地构造背景,研究区梅勒图组安山岩的形成可能与太平洋板块俯冲作用后的陆内伸展环境有关。     

北祁连西段祁青构造混杂岩中的单颗粒锆石U-Pb年龄及其地质意义

在北祁连西段三岔口等6幅1∶5万区域地质调查中,对祁青构造混杂岩进行了调查研究,通过LA-ICPMS法单颗粒锆石U-Pb同位素测年,获得206Pb/238U表面加权平均年龄494±15Ma,相当于中寒武世,故将该混杂岩解体,部分归为中寒武世黑刺沟组。     

内蒙古敖汉旗克力代岩体锆石U-Pb年代及地球化学

通过LA-ICP-MS锆石U-Pb测年对内蒙古敖汉旗克力代岩体进行研究。结果表明,岩浆锆石的加权平均年龄为263±1 Ma,表明其结晶年龄为中二叠世。岩石地球化学分析表明,岩体具有高Si(SiO2=69.94%～72.56%),富ALK(Na2O+K2O=8.04%～9.23%),贫Fe(FeOT=1.50%～1.82%)、Mg(MgO=0.65%～0.86%)、Ti(TiO2=0.32%～0.35%)的特点;A/CNK值为0.87～0.93,为准铝质;A/NKC1.1,显示出I型花岗岩特征。固结指数(SI)为6.06～7.36,分异指数(DI)为88.82～91.82,说明岩体经历了较强的分异演化作用。稀土元素总量较低(ΣREE=91.76×10-6～143.16×10-6),轻稀土明显富集,重稀土相对亏损,LREE/HREE值平均为9.14,(La/Yb)N平均值为8.36,δEu平均值为0.58,为Eu亏损型。大离子亲石元素(LILE)Rb、K较富集,强烈亏损高场强元素(HFSE)Nb、Ti、Ta。因此,判定克力代岩体为高钾钙碱性I型花岗岩。结合测年结果和地球化学特征,判定该岩体为晚海西期华北板块和西伯利亚板块碰撞作用形成的同碰撞型花岗岩。     

135~130 Ma: 大别山第二次“去根”时间？

大别杂岩主要由早白垩世侵入岩和三叠纪变质岩组成。它的四周是四条区域性韧性剪切带:郯城—庐江断裂,商城—麻城断裂,襄樊—广济断裂和晓天—磨子潭断裂。其中,晓天—磨子潭断裂和襄樊—广济断裂在早白垩世具有相反的走滑剪切方向:北侧的边界断裂(晓天—磨子潭断裂)是一个左行剪切断裂,而南侧的边界断裂(襄樊—广济断裂)是一个右行剪切断裂。在大别杂岩内部,早白垩世低角度剪切面理的倾伏向以SE向或NW向为主。这些晚期剪切面理上的拉伸线理的倾伏向同样为SE或NW向。大别杂岩总体具有朝SE向挤出和顶部相对朝NW向剪切的构造特征。这些表明晚中生代是该杂岩演化的重要阶段。该杂岩的边界断裂和内部构造特征指示其晚期抬升是沿造山带方向(SE—NW)以低角度方式进行的。这一过程直接导致高压-超高压变质岩和同构造岩浆岩被抬升至近地表。同时,年代学研究表明:大别杂岩(扬子板块东北缘地壳)在晚侏罗世—早白垩世经历大规模混合岩化的时间为145~135 Ma,同造山岩浆作用的时间为145~135 Ma,后造山火山-岩浆活动的时间为135~120 Ma。因此,该杂岩中三叠纪高压-超高压变质岩所记录的早白垩世抬升过程不是印支事件的后续,而是燕山期陆内造山及随后发生的伸展过程有关。尽管这一陆内造山事件的起始时间至今仍不确定,但大别山未变形岩体(130~120 Ma)的年代学研究结果和我们新测得的同构造伟晶岩脉的锆石U-Pb年龄(130 Ma)为早白垩地壳变形提供了良好的上限制约。这样,大别山经历了三叠纪碰撞造山和伸展,晚侏罗世—早白垩世陆内造山-伸展二次过程。     

新疆西准噶尔达尔布特蛇绿岩套柳树沟镁铁质杂岩SHRIMP锆石U-Pb年龄及地球化学特征

对新疆西准噶尔达尔布特蛇绿岩套柳树沟镁铁质杂岩中橄榄辉长岩、蛇纹石化橄榄辉长岩、辉长岩和蚀变辉长岩地球化学分析表明:辉长岩和蚀变辉长岩具有钙碱性和拉斑玄武岩的双重特征,橄榄辉长岩和蛇纹石化橄榄辉长岩属镁铁质堆积岩,为蛇绿岩组成单元;稀土总量较高,具微弱正Eu异常,稀土元素配分模式为略左倾平坦型,与SSZ型镁铁质堆晶岩稀土配分模式相同;微量元素蛛网图上,富集大离子亲石元素Cs、K、Th、U,相对亏损高场强元素Nb、Ta,可能代表俯冲板片的流体交代上覆地幔楔使地幔岩石发生部分熔融。地球化学构造环境判别柳树沟镁铁质岩石岩浆源区为亏损型地幔向富集型地幔过渡的适度富集型地幔,其形成的最佳模型是在成熟岛弧基础上裂谷化形成的一个不成熟的类似边缘海性质弧后盆地,不具成熟大洋或盆地那样的洋壳-上地幔结构,在盆地扩张初期岩浆具岛弧特征,随着盆地被进一步打开,镁铁质岩石具N-MORB特征。对辉长岩采用SHRIMP锆石U-Pb同位素年龄测试,获得特柳树沟镁铁质岩石的结晶时间为314.9±1.7 Ma。     

粤北大瑶山地区前泥盆纪地层中的火山岩特征及LA-ICP-MS锆石U-Pb年龄

通过1︰5万地质填图及剖面测制,作者在粤北大瑶山地区的震旦-寒武纪地层中首次发现多层火山岩,岩性主要为火山-沉积碎屑岩类的变质凝灰质不等粒岩屑石英砂岩、变质凝灰质不等粒长石石英砂岩、沉凝灰岩等,局部见变流纹质熔结凝灰岩。对变流纹质熔结凝灰岩、变质凝灰质砂岩用LA-ICP-MS法测定锆石U-Pb年龄,206Pb/238U年龄介于614~2869 Ma之间,年龄值较为分散,说明碎屑锆石是多来源的。火山岩年龄数据与地层时代归属矛盾,粤北大瑶山地区前泥盆纪地层的时代归属值得进一步探讨。     

冀北承德盆地九龙山组凝灰岩夹层LA-ICP-MS锆石U-Pb定年及其地质意义

冀北承德盆地中生代侏罗纪地层序列较齐全,但作为关键层位之一的九龙山组一直缺乏高精度年代学的约束。笔者首次对九龙山组凝灰岩夹层进行了LA-ICP-MS锆石U-Pb高精度定年,获得凝灰岩中岩浆锆石206Pb/238U加权平均年龄164.1±1.3 Ma。综合研究及对比表明,九龙山组的时限为158~164Ma,属中侏罗世晚期至晚侏罗世早期,对应于国际地层表的牛津期至卡洛维期,其沉积时间相对短暂。在此基础上,更新了研究区侏罗系年代地层柱状图,该认识对于深入研究燕山地区中生代侏罗纪地层格架及构造岩浆演化过程具有重要意义。     

Metallogenic and Metamorphic Age of the Hongtoushan Copper–Zinc Massive Sulfide Deposit,Liaoning Province,China

The Hongtoushan copper–zinc deposit is the only large Archean volcanogenic massive sulfide (VMS) deposit in China. This paper presents new information on the timing of metallogenesis and metamorphism of the deposit, including new cathodoluminescence (CL) images, and Th U^?1 and LA–ICP–MS U–Pb dating on zircons of the biotite–plagioclase gneiss and plagioclase–amphibole gneiss that host the deposit. The CL images and Th U^?1 ratios indicate that the zircons within the gneiss are of metamorphic origin. LA–ICP–MS dating of the plagioclase–amphibole gneiss yielded the upper intercept ages of 2549 Ma, and the biotite–plagioclase gneiss yielded the upper intercept ages of 2552 Ma and 2550 Ma correspondingly, indicating that the mineralization of the deposit occurred at around 2550 Ma. The rims of zircons within these host rocks yielded younger U–Pb ages at 2529, 2520 and 2515 Ma, identical to the age of felsic intrusive rocks in the study area. This suggests that the Hongtoushan VMS deposit underwent initial metamorphism and deformation at around 2520 Ma by the intrusion of granite magmas.     

Geochronology and fluid inclusion study of the Yinjiagou porphyry–skarn Mo–Cu–pyrite deposit in the East Qinling orogenic belt,China

The Yinjiagou Mo–Cu–pyrite deposit of Henan Province is located in the Huaxiong block on the southern margin of the North China craton. It differs from other Mo deposits in the East Qingling area because of its large pyrite resource and complex associated elements. The deposit’s mineralization process can be divided into skarn, sulfide, and supergene episodes with five stages, marking formation of magnetite in the skarn episode, quartz–molybdenite, quartz–calcite–pyrite–chalcopyrite–bornite–sphalerite, and calcite–galena–sphalerite in the sulfide episode, and chalcedony–limonite in the supergene episode. Re–Os and ⁴⁰Ar–³⁹Ar dating indicates that both the skarn-type and porphyry-type orebodies of the Yinjiagou deposit formed approximately 143 Ma ago during the Early Cretaceous. Four types of fluid inclusions (FIs) have been distinguished in quartz phenocryst, various quartz veins, and calcite vein. Based on petrographic observations and microthermometric criteria the FIs include liquid-rich, gas-rich, H₂O–CO₂, and daughter mineral-bearing inclusions. The homogenization temperature of FIs in quartz phenocrysts of K-feldspar granite porphyry ranges from 341 °C to >550 °C, and the salinity is 0.4–44.0 wt% NaCl eqv. The homogenization temperature of FIs in quartz–molybdenite veins is 382–416 °C, and the salinity is 3.6–40.8 wt% NaCl eqv. The homogenization temperature of FIs in quartz–calcite–pyrite–chalcopyrite–bornite–sphalerite ranges from 318 °C to 436 °C, and the salinity is 5.6–42.4 wt% NaCl eqv. The homogenization temperature of FIs in quartz–molybdenite stockworks is in a range of 321–411 °C, and the salinity is 6.3–16.4 wt% NaCl eqv. The homogenization temperature of FIs in quartz–sericite–pyrite is in a range of 326–419 °C, and the salinity is 4.7–49.4 wt% NaCl eqv. The ore-forming fluids of the Yinjiagou deposit are mainly high-temperature, high-salinity fluids, generally with affinities to an H₂O–NaCl–KCl ± CO₂ system. The δ¹⁸O_H2O values of ore-forming hydrothermal fluids are 4.0–8.6‰, and the δD_V-SMOW values are between −64‰ and −52‰, indicating that the ore-forming fluids were primarily magmatic. The δ³⁴S_V-CDT values of sulfides range between −0.2‰ and 6.3‰ with a mean of 1.6‰, sharing similar features with deeply sourced sulfur, implying that the sulfur mainly came from the lower crust composed of poorly differentiated igneous materials, but part of the heavy sulfur came from the Guandaokou Group dolostone. The ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb values of sulfides are in the range of 17.331–18.043, 15.444–15.575, and 37.783–38.236, respectively, which is generally consistent with the Pb isotopic signature of the Yinjiagou intrusion, suggesting that the Pb chiefly originated from the felsic–intermediate intrusive rocks in the mine area, with a small amount of lead from strata. The Yinjiagou deposit is a porphyry–skarn deposit formed during the Mesozoic transition of a tectonic regime that is EW-trending to NNE-trending, and the multiepisode boiling of ore-forming fluids was the primary mechanism for mineral deposition.