大兴安岭南段道伦达坝铜钨锡矿床成矿作用:来自锆石和独居石U-Pb和绢云母40Ar-39Ar年龄的约束

道伦达坝中型铜钨锡矿床位于大兴安岭南段,矿体呈脉状赋存于二叠系板岩及华力西期黑云母花岗岩的断裂破碎带中。道伦达坝矿床发育铜矿体、锡矿体、钨矿体、铜钨矿体、铜锡矿体、钨锡矿体和铜钨锡矿体。矿床的成矿过程可以划分为石英-萤石-白云母-电气石-锡石-黑钨矿阶段(Ⅰ阶段)、石英-萤石-黑钨矿-黄铜矿-毒砂-磁黄铁矿阶段(Ⅱ阶段)、石英-萤石-绢云母-黄铜矿-磁黄铁矿-黄铁矿-银矿物阶段(Ⅲ阶段)和方解石-石英-萤石-黄铁矿阶段(Ⅳ阶段)。道伦达坝矿床外围的张家营子岩体中的细粒花岗岩的LA-ICP-MS锆石U-Pb年龄为136.1±0.4Ma。Ⅱ阶段Cu-W共生矿体中2件独居石的LAICP-MS U-Pb年龄分别为136.0±2.3Ma和135.1±2.2Ma。Ⅲ阶段Cu矿体中1件独居石的LA-ICP-MS U-Pb年龄为134.7±2.8Ma。Ⅲ阶段铜矿体中1件绢云母的⁴⁰Ar-³⁹Ar坪年龄为138.8±0.47Ma,等时线年龄为140.0±1.1Ma。系统的定年结果表明,道伦达坝矿床的铜钨矿体和铜矿体均形成于早白垩世,它们属于同一个成矿系统;成矿与早白垩世高分异花岗岩有密切的成因联系。     

辽北法库变质杂岩的组成、变形与变质特点及构造属性

辽北法库变质杂岩的形成时代、大地构造属性及其与长春-延吉缝合带的形成过程一直以来都是众多地质学者关注的重要科学问题。本文试图通过U-Pb年代学以及物质组成分析、变形变质作用特点分析和区域对比的方法来建立法库变质杂岩的时空格架,大地构造归属及区域构造演化。通过详细的野外工作和镜下分析得到法库变质杂岩存在至少两期变形作用特点及角闪岩相-高绿片岩相至低绿片岩相的变质作用特点。通过对杂岩体中不同类型变质岩的锆石SHRIMP U-Pb年代学研究得到中志留世糜棱岩化黑云母花岗闪长岩原岩年龄为433±3Ma;晚志留世绢云长英质糜棱岩原岩年龄为423±5Ma;早二叠世绢云绿泥方解斜长糜棱岩原岩年龄为292±2Ma;早三叠世长英质糜棱岩原岩年龄为250±3Ma。通过区域对比,笔者认为法库变质杂岩为索伦-西拉木伦缝合带东延的一部分是长春-延吉缝合带的重要组成,其形成演化具有复合型造山的特点,具有复杂的构造演化史。     

兴蒙造山带晚古生代伸展减薄过程:来自内蒙林西地区岩体的地球化学证据

内蒙古林西县双井地区出露一套含暗色包体的花岗质岩体,位于双井片岩和房框子单元花岗质片麻岩接触带,该岩体对厘定古亚洲洋演化阶段、西伯利亚板块和阿穆尔板块最终碰撞缝合时限具有重要意义。本文对该岩体进行了详细的岩相学、岩石地球化学以及锆石U-Pb年代学研究,讨论了该岩体成因、岩浆源区以及研究区造山带地壳演化等问题。岩体中暗色包体和周边花岗岩大部分锆石记录了～285Ma和～270Ma两期年龄,少量锆石记录了～320Ma的较老年龄,表明该区域在晚石炭世就存在岩浆活动,并在～285Ma、～270Ma更为显著且岩浆活动具有幕式发生的特点,通过锆石的Ti温度计算得岩浆形成温度为～670℃。暗色包体相较周边花岗岩部分更富Al_2O_3(13.96%)、CaO(1.61%)、Na_2O(4.61%)以及Fe_2O_3(3.67%)、MgO(0.62%)、TiO_2(0.28%)、P_2O_5(0.08%)等,但贫K_2O(2.10%),但二者发育有一致的变形现象,具有相同的侵位时代(误差范围内一致)、相似的微量元素配分模式、相近的Sr-Nd-Hf同位素组成指示二者可能为同源岩浆不同演化阶段的产物。此外,暗色包体样品中,Zr/Hf比值介于31.74～37.08之间(接近原始地幔的Zr/Hf比值36.25),黑云母有壳源和壳幔混合源两种成因类型,I_(Sr)值介于0.7039-0.7055之间,ε_(Nd)(t)值介于-7.30～-5.87之间,锆石的ε_(Hf)(t)介于-3.58～6.72之间等地球化学特征均指示暗色包体的母岩浆在形成过程中有幔源物质的加入,以上特征显示岩体为壳幔混合源岩浆经历不同演化阶段后的产物。岩体中锆石Eu/Eu~*与地壳厚度的拟合结果显示研究区在 ca.290～270Ma 地壳经历了一次显著的减薄过程(ca.50～35km),为区域存在地幔物质上涌提供了动力学证据。结合前人资料,本次研究的含暗色包体的花岗质岩体属于大石寨期,其母岩浆的形成、侵位时代,以及壳幔混合源等地球化学特征精细地约束了该区大石寨期岩浆活动的发育时间及过程,为研究西拉木伦缝合带晚古生代构造演化提供了新证据,同时也清晰地指示出古亚洲洋在晚古生代末期并不处于大洋俯冲阶段,而是造山后的伸展裂解阶段。     

东昆仑地区驼路沟钴(金)矿床硅质钠长岩锆石U-Pb定年及Hf同位素特征研究

东昆仑驼路沟钴(金)矿床是青海省发现的首个独立大型喷流沉积型矿床,说明容矿围岩为一套海相火山-沉积岩系。本文在野外调查的基础上,对该矿区短沟矿段YM1坑口的硅质钠长岩进行岩石学、LA-ICP-MS锆石UPb年代学及Hf同位素分析。结果表明,区内钠长岩的形成年龄为(457.3±4.6)Ma,佐证了该矿区喷流作用成岩与成矿的同时性;另外获得9.20~1.10 Ga和2.40~2.50 Ga的2个年龄集中区,说明了研究区基底演化和源区物质的复杂性。Hf同位素显示为两个集中区,其中年龄峰值422~459 Ma的锆石获得εHf(t)值为-0.61~12.72,表明锆石母岩主要为新生的地壳物质,指示硅质钠长岩的形成与海底火山喷发作用密切相关;另外0.85~1.10 Ga的锆石εHf(t)值为-15.09~-0.07,其锆石母岩中主要为再造的古老地壳,表明该区基底源区物质的复杂性。通过区域对比分析,认为驼路沟矿区含矿火山-沉积岩系形成时代与钠长岩年龄、成矿年龄非常接近,喷流沉积时代应为晚奥陶世。     

晚中生代沂沭断裂带左旋韧性剪切与岩浆迁移规律

沂沭断裂带内部的岩浆侵入与断裂活动关系密切,开展沂沭断裂带内部岩浆年代学研究,对于沂沭断裂带构造背景研究具有积极的参考意义。选取沂沭断裂带内部的莒县浮来山正长岩体、边部的莒南官坊石英正长岩体及侵入该岩体的闪长玢岩脉,开展岩石学及年代学研究。首次发现晚中生代沂沭断裂带左旋韧性剪切,获得浮来山岩体的LA-ICP-MS锆石U-Pb年龄为(125.1±1.7) Ma,官坊岩体年龄为(125.6±2.0) Ma, 发生韧性变形的闪长玢岩脉年龄为(122.8±2.1) Ma。获得的125 Ma岩浆活动年龄与沂沭断裂带东侧的五莲变质核杂岩快速剥露(122~128 Ma)、诸城断陷盆地快速沉降的时间相吻合,该时期沂沭断裂带处于岩石圈减薄与破坏强烈的时期;闪长玢岩脉的122.8 Ma结晶年龄,与五莲变质核杂岩后构造岩体(石场、坊子岩体等)结晶年龄一致,该时期沂沭断裂带处于弱伸展状态,同时也说明胶东半岛岩石圈减薄具有时间上的一致性。晚中生代时期,沂沭断裂带两侧岩浆活动具有逆时针迁移的规律,这一规律可能与伊佐奈岐板块向欧亚板块俯冲的方向、角度、速度的变换有关。     

青藏高原东北缘祁连山三叠系砂岩碎屑锆石U-Pb定年及其物源分析

三叠系沉积物广泛覆盖青藏高原东北缘,其中松潘—甘孜地区三叠系的沉积物得到了较系统的研究,但是青藏高原北缘的祁连山三叠系盆地的研究却较为缺乏。为了丰富相关研究和揭示区域构造演化的特点,通过古水流方向统计、砂岩中碎屑矿物统计和碎屑锆石U-Pb测年等方法对祁连山三叠纪盆地物源进行系统研究。结果表明,祁连山三叠系盆地的古流向主要有南东向、正南向、南西向,物源来自岩浆弧和大规模褶皱造山作用的混合区。祁连山三叠系砂岩中的碎屑锆石的年龄谱主要峰值集中在250~290 Ma、360~460 Ma、1 600~2 000 Ma和2 200~2 600 Ma这4个年龄段。通过对比分析华北板块、华南板块中和秦祁昆中央造山带中岩浆锆石年龄谱特征可知:1 600~2 000 Ma和2 200~2 600 Ma年龄段的锆石来自华北板块,360~460 Ma年龄段的锆石来自北祁连造山带,250~290 Ma年龄段的锆石来自东昆仑的火山岛弧。此外,600~1 000 Ma年龄段锆石很少,这些锆石来自扬子板块,表明在三叠纪扬子克拉通和华北克拉通发生碰撞形成了秦岭造山带,阻断了来自扬子克拉通的物源。     

新特提斯洋晚白垩世演化特点:来自泽当共国日二长花岗岩年代学、地球化学及Sr-Nd同位素证据

为加深对西藏泽当地区新特提斯洋演化的认识,对西藏泽当蛇绿混杂岩带内的共国日二长花岗岩进行了岩石学、岩石地球化学、同位素及年代学等研究,研究显示:共国日二长花岗岩岩体规模小、岩性稳定,LA-ICP-MS锆石U-Pb年龄为(90.40±0.68)Ma,属晚白垩世;岩石地球化学具高硅、富铝、富钾、低钛和准铝质钙碱性花岗岩特征;轻稀土富集、重稀土亏损,具明显的负Eu异常,微量元素表现为相对富集Rb、K、Ba、Th、U等大离子亲石元素,显著亏损Nb、P、Ti等高场强元素;(⁸⁷Sr/⁸⁶Sr)_i=0.705 708~0.706 284,(¹⁴³Nd/¹⁴⁴Nd)_i=0.512 689~0.512 716,ε_Nd(t)=2.00~2.51。以上特征表明,位于泽当蛇绿混杂岩带内的共国日二长花岗岩属于I型花岗岩,由正常岛弧岩浆形成,应为晚白垩世新特提斯洋向北俯冲形成的岛弧环境下俯冲带上部地壳部分熔融的产物,其不属于泽当蛇绿岩的组成部分,表明在90 Ma前泽当洋内弧已经消失。     

U-Pb Zircon and Re-Os Molybdenite Geochronology of theW-Mo Mineralized Region of South Qinling,China, andtheir Tectonic Implications

A W-Mo mineralized region is located along the northern margin of the South Qinling tectonic belt of China. WMo mineralization occurs mainly in Cambrian–Ordovician clastic and carbonate rocks, and the ore bodies are structurally controlled by NW–SE-and NNE–SSW-striking faults. Evidence for magmatism in the area is widespread and is dominated by intermediate–felsic intrusives or apophyses, such as the Dongjiangkou, Yanzhiba, Lanbandeng, and Sihaiping granitic bodies. Quartz-vein-type mineralization and fault-controlled skarn-type mineralization dominate the ore systems, with additional enrichment in residual deposits. At present, there are few or insufficient studies on(1) the age of mineralization,(2) the relationship between intermediate–felsic granite and W-Mo mineralization,(3) the source of ore-forming materials,and(4) the metallogenic and tectonic setting of the mineralized area. In this paper, we present geochronology results for numerous intrusive granitic bodies in the South Qinling tectonic belt. U-Pb zircon geochronology of the Lanbandeng monzogranite and Wangjiaping biotite monzogranite yields ages of 222.7 ± 2.3 and 201.9 ± 1.8 Ma, respectively. In contrast to the Late Triassic age of the Lanbandeng monzogranite, the age of the newly discovered Wangjiaping biotite monzogranite places it at the Triassic–Jurassic boundary. Re-Os molybdenite geochronology on the Qipangou W-Mo deposit yielded a model age of 199.7 ± 3.9 Ma, indicating the deposit formed in the early Yanshanian period of the Early Jurassic. Granitoid intrusions in the mineralized area are characterized by composite granite bodies that crystallized at ca.240–190 Ma. While there were multiple stages of intrusion, most occurred at 210–220 Ma, with waning magmatic activity at 200–190 Ma. The Re-Os age of molybdenite in the region is ca. 200–190 Ma, which may represent a newly discovered period of W-Mo metallogenesis that occurred during the final stages of magmatism. The heat associated with this magmatism drove ore formation and might have provided additional ore-forming components for metallogenesis(represented by the Wangjiaping biotite monzogranite). Ore materials in the mineralized area were derived from mixed crustal and mantle sources. Enrichment of the region occurred during intracontinental orogenesis in the late Indosinian–Yanshanian, subsequent to the main Indosinian collision. At this time, the tectonic environment was dominated by extension and strike-slip motion.     

Geochemistry and Tectonic History of Seamount Remnants in the Xingshuwa Subduction Accretionary Complex of the Xar Moron Area,Eastern Margin of the Central Asian Orogenic Belt

This study focuses on the geology, geochemistry, zircon U-Pb geochronology and tectonic settings of the three types of seamount basalts from the Xingshuwa subduction accretionary complex in the Xar Moron area, eastern margin of the Central Asian Orogenic Belt(CAOB). The seamount remnants are composed of carbonate 'cap' sediments, large volumes of pillow and massive basalts, carbonate breccia slope facies and radiolarian cherts. Group 1 basalts are characterized by high contents of P2 O5 and TiO2 with alkaline affinity and LREE enrichment, indicating that they are derived from intraplate magma. Group 2 basalts display N-MORB LREE depletion patterns, indicating that they were formed at a mid-ocean ridge. Group 3 basalts have shown distinct Nb depletion and high Th/Yb ratios, indicating that they were generated in an island arc tectonic setting. The zircon U-Pb age of Group 1 basalt sample XWT18-131 is 576.4 ± 9.4 Ma, suggesting that the oceanic island seamount was the product of intraplate magmatism related to a mantle plume or 'hot spot' in the late Neoproterozoic. The zircon U-Pb age of Group 2 basalt sample XWT18-132 is 483 ± 22 Ma, indicating that the Paleo-Asian Ocean(PAO) was continuously expanding in the Early Ordovician. The zircon U-Pb age of Group 3 basalt sample XWT18-101 is 240.5 ± 8.2 Ma, suggesting that this area underwent the evolutionary path of ocean-continent transition, developing towards continentalization during the Middle Triassic. Thus, we believe that there was both mantle plume-related intraplate magmatism and intraoceanic subduction during the evolution of the PAO, the CAOB possibly being an evolutionary model of an intraoceanic subduction and mantle plume magmatism complex.     

扬子陆块西缘江浪穹窿超基性岩的成因:锆石U-Pb定年、岩石地球化学及Sr-Nd同位素

江浪穹窿位于扬子陆块西缘,本文作者在穹窿南部新发现一套侵入于二叠系及志留系的超基性岩,岩石主要由蛇纹石(约60%)、橄榄石(约30%)和少量磁铁矿(约5%)、角闪石(约5%)组成。为探讨超基性岩的成因,本文进行了LA-ICP-MS锆石U-Pb定年、岩石地球化学及Sr-Nd同位素研究。定年结果表明,超基性岩中发育大量2427~430 Ma的捕获锆石,最年轻一组岩浆锆石²⁰⁶Pb/²³⁸U加权平均年龄为222.3±4.4 Ma(MSWD=1.9,n=6)。主微量元素分析显示岩石：(1)具有低的SiO₂含量(46.76%~39.07%)、高的Mg#值(82.3~74.0)与Cr、Co、Ni丰度;(2)稀土元素含量(ΣREE平均31.8 μg/g)与(La/Yb)_N值(5.26~1.38)偏低,稀土配分型式较为平坦,具有较弱的Ce负异常(Ce/Ce^*=0.80~0.67);(3)富集大离子亲石元素Rb、Ba和U,亏损高场强元素Zr和Hf;(4)(Th/Yb)_PM值(29.8~1.56)、(Th/Ta)_PM值(0.22~0.03)、(La/Nb)_PM值(1.91~0.39)及La/Sm值(5.88~1.11)较低。Sr-Nd同位素分析显示,超基性岩具有较低的(⁸⁷Sr/⁸⁶Sr)_i值(0.706872~0.702598)和高的ε_Nd(t)值(8.02~5.64),成分接近于亏损地幔和岛弧玄武岩,计算表明地壳物质的混染程度低于5%。结合前人研究成果,本文认为超基性岩结晶年龄为222.3 Ma,可能形成于古特提斯洋闭合阶段的岛弧背景;原始岩浆来自高度部分熔融的地幔源区,上升侵位过程中可能经历了铬铁矿与橄榄石的分离结晶作用。此外,捕获锆石的年龄谱反映江浪穹窿很可能存在太古宙—古元古代变质基底,并且具有Rodinia超大陆会聚—裂解以及泛非事件的地质年龄记录。