辽东宽甸东北沟钼矿二长花岗岩年代学、地球化学及Hf同位素特征

东北沟钼矿是辽宁宽甸地区近些年发现的大型隐爆角砾岩型钼矿床。文章首次对东北沟钼矿床赋矿围岩二长花岗岩进行LA-MC-ICP-MS锆石U-Pb定年,主量元素、微量元素和Hf同位素地球化学研究,锆石U-Pb定年结果表明,二长花岗岩形成年龄为(129.4±0.3)Ma(MSWD=0.83),为燕山期构造岩浆活动产物。地球化学成分上,岩石具有富硅(SiO_2=62.21%~83.21%)、高钾(K_2O/Na_2O=3.35~20.27)和富碱(K_2O+Na_2O=5.82%~12.23%)的特点,属于钾玄岩系列。岩石富集轻稀土元素(LREE/HREE=10.26~24.21),亏损重稀土元素,具有弱负铕异常(δEu=0.63~1.07),富集大离子亲石元素(如K、Rb、Pb)和不相容元素(如Th、U)的特征,相对亏损高场强元素(如Nb、Ta、P、Ti)。锆石Hf同位素分析结果表明,东北沟钼矿二长花岗岩的ε_(Hf)(t)值为介于-12.4~-8.5,二阶段模式年龄(t_(DM2))介于442~1610 Ma,反映岩浆源区可能来源于中元古界古老地壳的再熔融。结合区域构造演化,成岩成矿构造背景为早白垩世古太平洋板块向欧亚之下俯冲,岩石圈减薄的构造环境。     

Recognition of the early permian volcanic rocks and Its geological significance in chifeng region of inner Mongolia北大核心CSCD

In order to investigate the geological significance of the large area of volcanics in the Uplift bell of Mingshan in western Chifeng,When carrying out the I :5 million regional mineral geological survey in the area,Through the research work of field geology investigation, petrology, LA-1CP-MS zircon U-Pb isotopic dating and regional stratigraphic correlation and so on.Found that the volcano rocks in the area is different from the Late Jurassic-Early Cretaceous volcanic rocks. And the obvious green alteration phenomenon was developed : The dating results of the Hornblende andesite in the lower parts is 273. 6±2. 2 Ma,it should belong to the Permian Elitu formation^ The Volcanics in the area belong to Calc-Alkaline-high-k calc-Alkaline series volcanic rocks. And volcanic magma experienced the separation and crystallization of minerals, it was the product of the continuous evolution of cognate magma, having the Characteristics that from bottom to top Intermediate-Mafic to Acidic magmatic evolution and the REE content increased gradually 0 Studies suggest that the Formation of volcanic rocks in the area is related to the ancient Asian Ocean to the North China block subduction in the Late Paleozoic period . It should be formed in the Archean to Proterozoic crystalline basement and late devonian magma Kemelting eruption, the tectonic environment formation of the volcanics in this area was andreessen arcc.     

Ontogenic variation and effect of collection procedure on leaf biomechanical properties of Mediterranean seagrass Posidonia oceanica (L.) Delile

Leaf mechanical traits are important to understand how aquatic plants fracture and deform when subjected to abiotic (currents or waves) or biotic (herbivory attack) mechanical forces. The likely occurrence of variation during leaf ontogeny in these traits may thus have implications for hydrodynamic performance and vulnerability to herbivory damage, and may be associated with changes in morphologic and chemical traits. Seagrasses, marine flowering plants, consist of shoot bundles holding several leaves with different developmental stages, in which outer older leaves protect inner younger leaves. In this study we examined the long‐lived seagrass Posidonia oceanica to determine ontogenic variation in mechanical traits across leaf position within a shoot, representing different developmental stages. Moreover, we investigated whether or not the collection procedure (classical uprooted shoot versus non‐destructive shoot method: cutting the shoot without a portion of rhizome) and time span after collection influence mechanical measurements. Neither collection procedure nor time elapsed within 48 h of collection affected measurements of leaf biomechanical traits when seagrass shoots were kept moist in dark cool conditions. Ontogenic variation in mechanical traits in P. oceanica leaves over intermediate and adult developmental stages was observed: leaves weakened and lost stiffness with aging, while mid‐aged leaves (the longest and thickest ones) were able to withstand higher breaking forces. In addition, younger leaves had higher nitrogen content and lower fiber content than older leaves. The observed patterns may explain fine‐scale within‐shoot ecological processes of leaves at different developmental stages, such as leaf shedding and herbivory consumption in P. oceanica.     

新疆萨尔朔克铜金多金属矿床成矿围岩锆石年龄、Hf同位素及其成矿背景

新疆萨尔朔克金铜多金属矿床产于中泥盆统阿舍勒组上亚组的中酸性火山岩-次火山岩中,地表以金(铜)矿化为主,矿体形态及空间分布严格受NNW向断裂破碎带控制,矿体呈脉状、透镜状。金(铜)矿石以蚀变岩型为主,其次为石英脉型,赋矿围岩为黄铁绢英岩化流纹斑岩。金主要赋存在微细粒黄铁矿等硫化物和脉石英中,黄铜矿常呈不规则细脉状出现。在地表100m以下,出现铅锌矿化,且向深部铅锌品位较高,一般3%~5%,最高达12%以上。流纹斑岩与金铜多金属矿关系密切。通过锆石U-Pb同位素测年和Hf同位素测试分析,获得流纹斑岩的成岩年龄为386.2±1.5Ma,εHf(t)在7~13之间,主要集中在8.5~12.5之间。上述结果表明,流纹斑岩可能形成于早泥盆世晚期活动大陆边缘环境,是俯冲增生的产物。铅锌矿化是386Ma流纹斑岩期后岩浆作用的产物,而金铜矿化则是在含矿流纹斑岩的基础上,经其后火山热液叠加作用发生的。     

新疆额尔宾山花岗岩侵位年龄和成因及其对南天山洋闭合时代的限定

额尔宾山花岗岩岩体位于南天山晚古生代侵入岩带,对该花岗岩进行锆石U-Pb定年获得296.1±1.8Ma的年龄,为早二叠世。岩石主量元素分析结果表明,该花岗岩的Si O2含量为66.96%~67.3%,富碱(Na2O+K2O=7.53%~7.97%),K2O/Na2O1(1.15~1.27),属高钾钙碱性系列岩石;Al2O3为15.56%~15.62%,Al2O3K2O+Na2O+Ca O,属于过铝型。岩石稀土元素配分模式呈现轻稀土元素(LREE)富集((La/Yb)N=27.03~30.62)、重稀土元素(HREE)亏损((LREE/HREE)=18.2~20.1)、具有中等程度的负Eu异常(δEu=0.64~0.68)。微量元素判别结果显示,其具有I-A型花岗岩过渡的特征。结合区域地质背景综合分析,初步认定该岩体可能形成于南天山同碰撞向后碰撞构造体制转换时期,据此可以推测南天山洋盆闭合时限至少应该在早二叠世以前。     

东昆仑东段巴隆地区朝火鹿陶勒盖花岗闪长岩体锆石U-Pb年龄、地球化学及其地质意义

东昆仑造山带晚古生代—早中生代由于布青山-阿尼玛卿洋的俯冲发育有大量岛弧型花岗岩类。选取东昆北巴隆地区朝火鹿陶勒盖花岗闪长岩体寄主岩和闪长质暗色微粒包体进行了岩相学、LA-ICP-MS锆石U-Pb年代学及地球化学研究。结果表明,岩体寄主岩的结晶年龄为242.3±1.3Ma,暗色微粒包体结晶年龄为241.2±0.8Ma,显示其形成于中三叠世;寄主岩和暗色微粒包体A/CNK值介于0.86~1.06之间,为准铝质-弱过铝质;稀土元素总量分别为119×10~(-6)~170×10~(-6)、189×10~(-6),稀土元素配分模式显示右倾型,具有负Eu异常;岩石富集Rb、Ba、Th等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素,具有弧岩浆岩特征。野外及岩相学特征均显示包体为基性岩浆进入酸性岩浆快速冷凝形成的,为俯冲板片断离导致幔源岩浆上侵形成的岩浆混合作用的产物,是布青山-阿尼玛卿洋俯冲晚期的岩浆记录。     

内蒙古东乌旗沙麦钨矿床的成矿时代

内蒙古东乌旗沙麦钨矿位于贺根山断裂带以北的兴蒙造山系二连-东乌旗弧盆带内,为岩浆期后高温热液黑钨矿石英脉型矿床。采用黑钨矿Sm-Nd同位素分析获得黑钨矿的形成年龄为137.9±1.7Ma,采用TIMS锆石U-Pb同位素定年获得赋矿黑云母花岗岩的形成年龄为139.1±0.93Ma,据此提出,沙麦钨矿床的形成时代为燕山晚期,这与区域上大兴安岭西坡主要金属矿床的形成年龄数据相吻合。黑钨矿的初始ε_(Nd)值为正值,与中亚造山带内大量花岗岩的εNd值均为正值的特点相一致,表明其来源于亏损地幔源。     

新疆东准乌须克劳格岩体LA-ICP-MS锆石U-Pb年龄、Hf同位素特征及其地质意义

新疆东准噶尔琼河坝地区近年来找矿获得重大突破,发现了一系列重要的矿产,这些矿产基本上围绕该地区出露面积最大的乌须克劳格岩体分布。该岩体组成比较复杂,主要岩性为二长花岗岩和花岗闪长岩。采用LA-ICP-MS技术测得花岗闪长岩和二长花岗岩锆石~(206)Pb/~(238)U年龄分别为428.9±1.9Ma和427.2±1.7Ma,被解释为岩石的结晶年龄。2类岩石都属于过铝质-钙碱性系列花岗岩,具有较高的铝、钙含量,K_2O/Na_2O值普遍偏低,介于0.15~0.40之间;稀土元素配分曲线呈现右倾特征,稀土元素总量较低,轻稀土元素相对富集,负Eu异常不明显;在微量元素原始地幔标准化蛛网图上,高场强元素Th、Nb、Ta、P、Ti等相对亏损,大离子亲石元素Rb、Ba、U、K、Sr等相对富集,具有高Ba、Sr含量和高(La/Yb)_N、Sr/Y值,显示出高Ba-Sr花岗岩的特征;同时岩体具有高正ε_(Hf)(t)值和年轻的模式年龄。这些地球化学和同位素特征表明,晚志留世乌须克劳格岩体是大陆边缘弧环境下大洋板片熔融的产物。     

蒙古戈壁阿尔泰巴音陶勒盖地区二长花岗岩LA-ICP-MS锆石U-Pb年龄及其地质意义

蒙古戈壁阿尔泰省巴音陶勒盖地区地处南戈壁-阿尔泰构造带南缘,区内构造活动活跃,中酸性侵入岩比较发育。采用LA-ICP-MS锆石U-Pb测年技术,对区内二长花岗岩中的锆石进行同位素年龄研究。阴极发光图像显示,锆石颗粒多为自形-半自形,且有明显的初始岩浆振荡环带,少见蚀变微区,结合较高的Th/U值(0.65~1.79),断定其为典型的岩浆成因锆石;30颗锆石的~(206)Pb/~(238)U年龄加权平均值为300.2±0.9Ma,显示二长花岗岩成岩时代为晚石炭世,代表了华力西中期的一次构造-岩浆事件,为约束南戈壁-阿尔泰构造带晚石炭世深成岩浆活动时限提供了新证据。     

对湖北大洪山地区一套紫红色砂-砾岩系沉积年代的再认识——碎屑锆石U-Pb年龄及其地质意义

湖北大洪山地区花山群六房咀组之上不整合覆盖了一套紫红色砂-砾岩。这套岩石的沉积时代存在争议,一种观点认为是南华纪早期;另一种观点认为是晚侏罗世。利用LA-ICP-MS分析技术,对这套碎屑沉积岩进行了碎屑锆石U-Pb测年,获得有效年龄数据125组,年龄值变化范围较大(3223~771Ma),主要集中于新太古代末—古元古代早期(约2500Ma)、古元古代(约2000Ma)和新元古代(约800Ma)3个时间段。对比鄂东南地区和三峡地区莲沱组岩石学特征和碎屑锆石年龄分布特征,认为其具有相似的物源,这套岩系沉积时代应该为南华纪早期而非晚侏罗世。综合分析扬子地块的前寒武纪年龄,认为扬子地块可能存在大量未岀露的新太古代末—古元古代早期(约2500Ma)基底,约2500Ma的岩石应该是扬子地块深部基底的重要组成部分。扬子地块存在广泛的古元古代(约2000Ma)岩浆活动,这期岩浆活动可能是Columbia超大陆聚合在扬子地块的响应。新元古代(约800Ma)扬子地块北缘存在Rodinia超大陆裂解同期裂谷,裂谷内基性岩可能为大洪山地区南华纪地层中基性岩砾石的物源。