The hydrocarbon generation mechanism and the three-stage type model of hydrocarbon generation for carbonate source rocks

The diagenetic mechanism and process of carbonate rocks, which is different to that of clastic rocks, decides the existence of different existing state organic matters in carbonate rocks. This has been verified by both the microscopic observation of organic petrology and the analysis of organic geochemistry of many samples. Based on the hydrous pyrolysis simulation experiment of the low-mature carbonate rocks, the contrasting study on the yield and their geochemistry characteristics of different existing state soluble organic matters of a series of various maturity samples shows that the different existing state organic matters make different contributions to hydrocarbon generation during every evolution state. So that, the hydrocarbon generation process of carbonate rocks can be summarized as the following three stages: the first is the direct degradation of biogenic bitumen macromolecules during the immature stage, the second is the thermal degradation of a large amount of kerogen at the mature stage, the last stage is the expulsion or release of inclusion organic matter owing to the increased thermal expansion pressure during the high evolution stage. Part of achievements of the Eighth Five-Year National Science-Technology Key-Task Project “85-102-02-07”.     

晚白垩世中国东南沿岸山系与中南地区的沙漠和盐湖化

晚白垩世在中国东南沿古太平洋西岸地区形成了一条巨大的沿岸山系，其山峰高度在３５００—４０００ｍ之间，东西宽度近５００ｋｍ，挡住了东来的暖湿气流，使中南地区云梦泽内陆水域的广大平原和丘陵地变成了一个热带—亚热带干旱、炎热的半沙漠和盐湖地区，这一古地理和古气候格局一直持续到早第三纪末才开始改变。     

上扬子地台区晚古生代海相碳酸盐岩的碳,锶同位素研究

未经蚀变的海相碳酸盐岩的碳，锶同位素组成代表了原始海水的同位素组成，在确定样品末经显著蚀变的基础上，本文测定了上扬子地区晚古生代７条剖面２３８个海相碳酸盐岩样品的碳、锶同位素组成，分布了它们的测试结果和演化曲线，为其他相关研究提供了可利用的基础参照数据。     

洋岛,海山碳酸盐岩的沉积特征及其古地理意义

高出水面的洋岛和潜伏水下的海山普遍存在于现代地球表面的各大洋中，地质历史中存在的古洋岛和古海山也逐渐为人们所认识。笔者从地形特征，沉积学特征，成岩作用和生物学特征几个方面对洋岛，海山进行了分析，洋岛，海山通常具有洋岛型火山岩基底和碳酸盐盖层的双层式地层结构，具有低分异度，探讨了古洋岛，古海山的鉴别对于再造古海洋，古地理格局的现实意义。     

Biomarkers in the Molar Tooth （MT）-Bearing Limestones in the Jilin-Liaoning Area of China

The origin of Molar Tooth (MT) carbonates has been argued for more than 100 years, which are a kind of Proterozoic carbonates especially composed of microsparite with ptygmatically folded and sheet-like structures. Biomarkers detected in the microcalcsparite from the Wanlong and Xingmincun formations in the Jilin-Liaoning area showed there are abundant normal alkanes, isoprenoids, hopanes, steranes, alkylmethylcyclohexanes, and alkyleyclohexanes, indicating a diversity of biological source: long-chain isoprenoids, the major components of chlorophyll, such as C19, C20, a kind of major biomarkers synthesized early by isoprenoid monomers; hopanes a type of characteristic biomarkers from prokaryote, such as archaebacteria and cyanobacteria; sterane a biomarker for eukaryote; and two kinds of alkanes with C17, C18 as the main peaks representing aquatic bacteria and with C23, C24 as the main peaks representing fungi, respectively. Biomarker analysis showed that MT is the result of bacterial and algal activities, which is a kind of organisms between aerobic and anaerobic bacteria, reproducing well in normal or slightly saline sea water under weak oxidation-reduction conditions, resulting in rapid deposition of calcite as microsparite clue to some mechanisms.     

鄂尔多斯盆地奥陶系海相碳酸盐岩生烃性能与中部长庆气田气源成因研究

用激光 -荧光显微镜等有机岩石学方法 ,挑选样品中有明显生、排烃现象的碳酸盐岩 ,再以测定的这类碳酸盐岩的有机碳含量为依据 ,确定本区高成熟碳酸盐气源岩残余有机碳的下限指标用 0 .13%～ 0 .14 %比较合理。根据碳酸盐岩储层孔隙中充填沥青和皮膜状残余沥青的分布和含量 ,论证了陕参 1井等奥陶系碳酸盐岩地层在地质历史中 ,存在若干油气有效储层。采用连续升温 ,步进取样的热模拟实验方法 ,揭示了本区煤与碳酸盐岩干酪根随热演化作用增强 ,烃类气体产物的干燥系数增大 ,δ1 3C1 、δ1 3C2 明显变重的规律 ,并根据样品实验结果推算 ,本区石炭系—二叠系煤最大生气阶段的δ1 3C1 应为 - 2 7‰～ - 2 8‰ ,碳酸盐岩最大生气阶段的δ1 3C1 应为- 31.7‰～ - 33‰。在气源成因判识中 ,根据主生气期阶段对天然气成藏储聚的贡献最大、甲烷碳同位素较重以及长庆气田风化壳气藏天然气δ1 3C1 重值区并不与石炭系—二叠系煤的镜质组反射率高值区匹配的现象等进行气源判识 ,认为长庆奥陶系风化壳气藏 ,具有下古生界海相碳酸盐岩气与上古生界石炭系—二叠系煤成气的混源成因     

碳酸盐岩储层缝洞发育带预测:以塔河油田为例

塔河油田碳酸盐岩为古岩溶喀斯特化与受后期构造叠置改造的孔、洞、缝等组成的非均质储层,储层具有规模不同、空间形态不规则、充填性质各异的复杂组合特征以此为对象通过分解地震波场不同特征信号,开发了一系列针对不同储层目标的叠前叠后地震预测技术,不同特征地震预测结果经综合叠置验证分析,实现了残丘体上叠置的孔、洞、缝及古地貌的精细刻画及表征,展示了缝洞空间纵横交错的叠置关系,提高了复杂储层空间展布规律的认识及精确定位。     

成像测井技术在碳酸盐岩水平井中的应用

塔里木盆地北部地区碳酸盐岩油藏储层，非均质性较强，只依靠常规测井判断碳酸盐岩裂缝、溶孔、溶洞很困难．利用地层微电阻率扫描成像(FMI)，对碳酸盐岩水平井储层进行定性分析、定量解释，并能准确识别出碳酸盐岩目的层裂缝的性质、大小、开度、溶蚀孔洞原生孔隙、次生孔隙的发育情况等．同时并利用测试、酸压资料验证了使用成像测井判断裂缝的有效性．     

High-pressure experimental growth of diamond using C–K2CO3–KCl as an analogue for Cl-bearing carbonate fluid

High-pressure, high-temperature diamond growth experiments have been conducted in the system C–K₂CO₃–KCl at 1050–1420 °C, 7.0–7.7 GPa. KCl is of interest because of the strong effect of halogens on the phase relations of carbonate-rich systems [Geophys. Res. Lett. 30 (2003) 1022] and because of the occurrence of KCl coexisting with alkali silicate–carbonate fluids in natural-coated diamond [Geochim. Cosmochim. Acta 64 (2000) 717]. We have used system C–K₂CO₃–KCl as an analogue for these mantle fluids in diamond growth experiments. The presence of KCl reduces the potassium carbonate liquidus to ≤1000 °C at 7.7 GPa, allowing it to act as a solvent catalyst for diamond growth at temperatures below the continental geotherm. This is a reduction on the minimum diamond growth temperature reported in the alkali-carbonate–C–O–H system [Lithos 60 (2002) 145]. Diamond growth using carbonate solvent catalysts is characterised by a relatively long induction period. However, the addition of KCl also reduced the period for diamond growth in carbonate to 5 min; no such induction period appears to be necessary. It is suggested that KCl destabilises carbonate, allowing greater solubility and diffusion of carbon.     

基于二维小波变换的FMI图象分割

为了从FMI资料中定量提取参数，一个重要的步骤是从实际FMI资料中分离出反映溶孔、溶洞、裂缝的子图像。本文给出的方法，考虑图像像元邻域的特征，应用二维小波变换求出目标与背景边缘的点集，按这个边缘点集的坐标点所对应的原图像像素灰度值的平均值作为分割阈值进行图像分割。实际资料处理表明，应用这种方法可以从实际的FMI资料中准确地分割出孔洞、裂缝的子图像并且可以按深度段连续自动处理，为后续定量计算参数奠定了良好基础。