青藏高原湖泊沉积研究及其进展

青藏高原湖泊沉积研究主要围绕青藏高原隆升和全球变化响应开展的。研究揭示了青藏高原隆升具有整体性、阶段性和后期加速性。中晚更新世以来和末次间冰期-冰期气候演化过程得到重建,并能够与冰芯和深海氧同位素记录对比;同时也存在M IS3阶段强烈暖湿和末次冰盛期冷湿等区域特征;新仙女木事件在湖泊沉积物也有明显记录。全新世研究表明青藏高原早期暖湿并经历冷事件,大暖期普遍出现高水位,后期气候向干冷化方向发展。湖泊沉积环境定量化重建也得到研究。青藏高原湖泊沉积应在高分辨率纹层沉积和环境指标定量分析基础理论方面加强研究。     

Experimental calibration of lake-sediment spectral reflectance to chlorophyll a concentrations: methodology and paleolimnological validation

Chlorophyll a preserved in lake sediments reflects, in part, past primary production. This study assesses the spectral properties of sedimentary chlorophyll a using visible-near infrared reflectance (VNIR) spectroscopy, with the objective of establishing a new, non-destructive paleolimnological proxy. Reflectance spectra were determined from a dilution series (n = 10) involving incremental additions of pulverized modern algae to a lake sediment matrix of low organic content. This enabled an assessment of the development of sediment reflectance spectra in relation to different sediment chlorophyll a concentrations, and subsequent regression of spectral features against measured concentrations of chlorophyll a and derivatives obtained by high performance liquid chromatography (HPLC). The experiment demonstrates that ubiquitous troughs in sediment reflectance near 675 nm are attributable to chlorophyll a and derivative compounds. A significant correlation (r ² = 0.98, P < 0.01) was obtained between the area of the reflectance trough in the 650–700 nm interval and summed concentrations of chlorophyll a, all derivative isomers, and degradational pheopigments. A simple linear inference model derived from this experiment was applied to a down-core sequence of VNIR spectra from a productive prairie lake (Alberta, Canada), where it produced inferred sediment chlorophyll a concentrations in concordance with HPLC measurements. Although a larger training set is desirable to further refine the inference model, the analyses reported here demonstrate that reflectance spectroscopy provides a rapid, semi-quantitative method for assessing the chlorophyll a content of lake sediments.     

Late Glacial and Holocene Palaeoenvironmental Changes in the Rostov-Yaroslavl’ Area, West Central Russia

Three lake sediment sequences (lakes Nero, Chashnitsy, Zaozer’e) from the Rostov-Jaroslavl’ region north of Moscow were studied to provide information on palaeoclimatic and palaeoenvironmental changes during the past 15,000 cal yr. The multi-proxy study (i.e., pollen, macrofossils, mineral magnetic measurements, total carbon, nitrogen and sulphur) is chronologically constrained by AMS ¹⁴C measurements. Lake Nero provided the longest sedimentary record back to ca. 15,000 cal yr BP, while sediment accumulation began around ca. 11,000 cal yr BP in the two other lakes, possibly due to melting of permafrost. Limnic plant macrofossil remains suggest increased lake productivity and higher mean summer temperatures after 14,500 cal yr BP. While the late glacial vegetation was dominated by Betula and Salix shrubs and various herbs, it appears that Betula sect. Albae became established as early as 14,000 cal yr BP. Major hydrological changes in the region led to distinctly lower lake levels, starting 13,000 cal yr BP in Lake Nero and ca. 9000 cal yr BP in lakes Chashnitsy and Zaozer’e, which are situated at higher elevations. These changes resulted in sedimentary hiatuses in all three lakes that lasted 3500–4500 cal yr. Mixed broad-leaved – coniferous forests were widespread in the area between 8200 and 6100 cal yr BP and developed into dense, species-rich forests between 6100 and 2500 cal yr BP, during what was likely the warmest interval of the studied sequences. Agricultural activity is documented since 500 cal yr BP, but probably began earlier, since Rostov was a major capital by 862 A.D. This apparent gap may be caused by additional sedimentary hiatuses around 2500 and 500 cal yr BP.     

鄂尔多斯盆地东部太原组古岩溶特征

鄂尔多斯盆地下二叠统太原组为碳酸盐与陆源碎屑混合沉积,主要由灰岩、岩屑石英砂岩、泥岩和煤岩组成。太原组沉积时期鄂尔多斯盆地东部为碳酸盐与陆源碎屑混合沉积的陆表海潮坪沉积体系和三角洲沉积体系。北部发育三角洲前缘沉积。南部发育碳酸盐潮下带—潮间带及陆源碎屑潮下带。太原组中普遍发育冲刷充填现象,说明短期的沉积间断发生频繁。太原组中岩溶角砾岩发育,主要为镶嵌状角砾岩,见到少量裂缝角砾岩和紊乱角砾岩。太原组中的岩溶形成于同生期,没有形成岩溶地貌。与现代碳酸盐沉积物相比,太原组灰岩具有较高的Mn和Fe含量,明显低的Sr含量和δ18O值。这是由于埋藏作用和淡水淋滤所引起的,低的Sr含量和δ18O值主要由淡水淋滤所致。与大多数地质学家研究得出的二叠纪生物和非生物成因的方解石的δ13C值相比较,太原组方解石的δ13C值无明显差异。宏观和微观特征均说明太原组存在古岩溶。岩溶作用使得灰岩的储集性能在一定程度上得到了改善。     

中国西北干旱环境的形成时代与成因探讨*

西北干旱环境的形成时代是我国古环境研究的重要问题。干旱环境的存在可据地层中风成沉积、风化沉积、水成沉积、古生物等信息综合确定。对塔里木、准噶尔、柴达木、河西走廊、陕甘宁等盆地的中、新生界干旱环境沉积记录分析表明,我国西北干旱沉积及其时代可上溯到晚侏罗世初期(约160Ma以来),其间可分为三大阶段:1)晚侏罗世至古近纪(约160~24Ma),以红色干旱沉积与亚热带干旱环境为主; 2)晚第三纪(约24.0~2.5Ma),以红色干旱沉积与亚热带干旱环境向灰、黄色干旱沉积与温带干旱环境逐渐过渡为特征;3)第四纪(约2.5Ma以来),以灰、黄色干旱沉积与温带干旱环境为主。干旱环境在晚侏罗世的大范围出现主要是侏罗纪全球气温回升、北亚热带北界北推引起的。相比可见,新近纪温带干旱环境的形成主要与古特提斯海关闭、青藏高原及盆地外围山脉的隆升等构造运动引起内陆盆地干旱效应的加强有关。进而推知,我国西北在新近纪出现的温带内陆干旱环境既是盆地外围高原、山脉隆升的重要直接结果,也是亚洲季风系统的重要直接形成因素。     

Environmental characteristics of Mid-Holocene recorded by lacustrine sediments from Lake Daihai, north environment sensitive zone, China

One of the goals for paleaoenvironmental research is to predict the tendency of future climate and environmental changes based on the understanding of the past. The key approach is to find similar pictures which happened in the past. By understanding the background and mechanism of the paleaoenvironmen- tal changes, reliable parameters and verifications can be provided for the numerical model to predict the tendency of future climate and environmental changes. The Mid-Holocene as the nearest …     

Rock magnetic and geochemical proxies for iron mineral diagenesis in a tropical lake: Lago Verde, Los Tuxtlas, East–Central Mexico

Magnetic and non-magnetic mineral analyses were conducted on a lacustrine sequence from Lago Verde in the tropical coast along the Gulf of Mexico that covers the last 2000 years. The site witnessed the transformation of the environment since the early Olmec societies until forest clearance in the last century. Through these analyses we investigated the processes that affected the magnetic mineralogy in order to construct a model of past environmental changes, and compare this model with the archeological record and inferred climatic changes in the northern hemisphere of tropical America. Volcanic activity has played a major influence on sediment magnetic properties, as a purveyor of Ti-magnetites/Ti-maghemites, and as a factor of instability in the environment. Anoxic reductive conditions are evident in most of Lago Verde's sedimentary record.

Direct observations of magnetic minerals and ratios of geochemical (Fe, Ti), and ferrimagnetic (χf) and paramagnetic (χp) susceptibility (χ) data, are used as parameters for magnetite dissolution (χp/χ, Fe/χf), and precipitation (χf/Ti) of magnetic minerals. Intense volcanic activity and anoxia are recorded before A.D. 20, leading to the formation of framboidal pyrite. Increased erosion, higher evaporation rates, lower lake levels, anoxia and reductive diagenesis in non-sulphidic conditions are inferred for laminated sediments between A.D. 20–850. This deposit matches the period of historical crisis and multiyear droughts that contributed to the collapse of the Maya civilization. Dissolution of magnetite, a high organic content and framboidal pyrite point to anoxic, sulphidic conditions and higher lake levels after A.D. 850. Higher lake levels in Lago Verde broadly coincide with the increased precipitation documented during the Medieval Warm Period (A.D. 950–1350) in the northern tropical and subtropical regions of the American continent. For the Little Ice Age (A.D. 1400–1800), the relatively moist conditions inferred are in concordance with the glacial advances recorded in central Mexico. Higher erosion rates reflect destruction of the rainforest over the last 40 years.     

Comparison of components and distribution of heavy metals in sediments, suspended particulate matter and surface coatings in natural waters

Solid phases, such as surface coatings （SC）, suspended particulate matter （SPM） and deposited sediments （DS）, contribute to the pool of heavy metals in natural waters. Their existing and forming conditions lead to potential differences in enrichment capacity of pollutants, chemical compositions and crystals. In this study, the contents of heavy metals in SC, SPM and DS were determined by GF-AAS after digestion with a mixture of concentrated HNO3 and HClO4. The selective extraction method was employed to remove Fe, Mn oxides and organic matters and associated heavy metals （Cu, Pb, Zn）. X-ray diffraction analyses were performed to characterize the crystals in the samples. The results showed that no significant difference in the contents of Fe-oxides in DS, SPM and SC was found, but the contents of Mn-oxides and organic matter follow the order of SC〉SPM〉DS. The significant crystal characters were observed in DS, SPM and SC, and the kinds of minerals and crystallization degree follow the order of DS〉SC〉SPM. In addition, quartz was the most important matter of crystals in the solid phases. Enrichment capacity follows the order of SPM〉SC〉DS for Pb, Cu and Zn. Organic matter was the major sorbent for Cu, and Mn oxides and organic matter played an important role in the enrichment of Zn. However, Pb was absorbed mainly by Fe oxides. Moreover, compared with Fe oxides and organic matter, Mn oxides had a great enrichment capacity for these metals. Although DS, SPM and SC were formed in the same water system, contents of chemical components, crystals and enrichment capacities to heavy metals were obviously different.     

Geochemical dissociation of major and trace elements in bed and suspended sediment phases of the phosphate mines effluent water, Jordan

The bed and suspended (slime) sediment phases associated with effluent water that are produced from phosphate-ore-upgrading process at Al-Abyad mine in the southern part of Jordan were analyzed chemically and mineralogically. The results show that the effluent water is highly oxic and mildly alkaline in nature. The geochemical behavior of each phase was controlled by the effluent water physicochemical parameters, sediment particle size, mineralogical constituents of the studied phases, and the prevailing climatic nature of the area. Bed sediments have higher concentrations of many elements than slime. Accordingly, the bed sediments can be considered as a sink rather than a pool for many elements. The geochemical dissociation of major oxides and trace elements between bed and slime sediments was evident using t test, particularly between P₂O₅, SiO₂, CaO, K₂O, Mn, Sr, Y, and Co, and to lesser extent, V, U, Zn, and Cr. This might be attributed to effluent water characteristics, mineralogy, and the presence of fine-grained materials. The spatial distribution of major oxide and trace element concentrations along the stream drainage exhibited a slight increase with distance either in bed or slime sediment phases. However, they increased suddenly at the last three sampling sites, which might be due to the abundance of fine-grained materials that are mainly composed of clay minerals (montmorillonite) that would enhance the adsorption process. Moreover, the XRD results confirmed the existence of elemental geochemical dissociation as a function of mineral control.