秦岭核桃坝石炭系深水相遗迹化石,沉积环境和古地理分析

研究剖面位于陕西凤县核桃坝，构造上属秦岭造山带的商丹缝合带。核桃坝剖面下部为浅海陆棚相粉砂岩、泥灰岩和灰岩；中、上部以重力流沉积为主。在中部浊积岩中产遗迹化石：Ｎｅｒｅｉｔｅｓ ｆｅｎｇｘｉａｎｅｎｓｉｓ ｉｃｈｎｏｓｐ．ｎｏｖ．，Ａｃａｎｔｈｏｒｈａｐｈｅ ｃｆ． Ａ． ｉｎｃｅｒｔａ Ｋｓｉａｚｋｉｅｗｉｃｚ，Ｃｈｏｎｄｒｉｔｅｓ ｉｃｈｎｏｓｐ．，Ｐｌａｎｏｌｉｔｅｓ ｉｃｈｎｏｓｐ．等。其     

遗迹化石与潮控滨线海泛面的识别及准层序相组合──以塔里木盆地下志留统塔塔埃尔塔格组为例

塔里木盆地下志留统塔塔埃尔塔格组主要由潮坪沉积组成。根据遗迹化石与沉积特征,固底控制的遗迹化石Ｇｙｒｏｌｉｔｈｅｓ常常与沉积性不连续面（海泛面）有关,潮控滨线中的准层序由三类岩相组成,其中含砾砂岩相（相Ａ）为潮道沉积,未见遗迹化石;含交错层理细砂岩相（相Ｂ）为砂坪沉积,仅见少量的遗迹化石Ｓｋｏｌｉｔｈｏｓ;强生物扰动粉砂岩、泥岩相（相Ｃ）为砂、泥混合坪沉积,发育有丰富的遗迹化石,代表Ｓｋｏｌｉｔｈｏｓ－Ｃｒｕｚｉａｎａ混合遗迹相。     

复杂应力条件下掺砾黏土真三轴试验

采用新型真三轴仪器,对掺砾黏土进行了复杂应力条件下加载试验,近似模拟了土石坝填筑期心墙土体单元的加荷过程。试验结果表明,由于土体单元处于复杂应力状态,即使是单向加载这样的简单加荷应力路径,在不同应力方向上的应力和变形也都呈现显著的应力各向异性。土石坝应力变形分析中坝体单元处于三向应力条件下,由于加载引起的应力各向异性对心墙乃至整个坝体的应力变形规律都有较大影响,合理的本构模型应该能够反映并描述这种复杂应力状态下的应力各向异性。     

Illite/smectite transformation in detrital glaucony during burial diagenesis of sandstone: A study from Siri Canyon – Danish North Sea

Detrital glaucony in the Palaeogene glauconitic sandstones in Siri Canyon, Danish North Sea, has been analysed from 15 exploration wells by X‐ray diffraction, electron microprobe and scanning electron microscopy. These sandstones consist of mixed‐layer illite/smectite and have a large variability in chemical composition and structure. In the most shallow wells (ca 1700 m), the glaucony is rich in Fe and consists of mixed‐layer illite/smectite with random‐interstratification (R = 0). In the depth interval from 1700 to 2000 m, the composition changes as Si is incorporated. The structure changes to ordered R = 1. Further increase in burial leads to the loss of Fe. Ordered R = 3 mixed‐layer illite/smectite is recognized from burial depths of 2200 m. The proportion of illite in illite/smectite mixed layers increases only slightly with depth and temperature. Although the structural changes generally are associated with chemical changes, they can also take place isochemically when the detrital glaucony is tightly embedded in earlier cement, which prevented chemical exchange. The glaucony transformation in the Siri Canyon sandstones partly reflects a supply of Si and partly significant loss of Fe. Thus, the glaucony transformation relates to the general diagenesis of the host sandstone. These sandstones are cemented by microquartz at an early stage, followed by precipitation of Fe‐rich grain‐coating berthierine or chlorite.     

全尾砂-废石混合回填膏体流动特性变化规律

质量浓度、废石掺量是影响尾砂-废石混合回填体流动特性的主要因素,研究这些因素对膏体流动性的影响规律,对于控制膏体流动性具有重要意义。采用改进的小型直剪装置进行混合回填体直剪试验,以黏聚力、内摩擦角、抗剪强度为依据,综合得出了混合回填膏体流动性变化规律。试验结果表明,膏体在受力变形前期呈较为明显的似弹性性质,随废石掺量增加,位移-剪应力曲线中阶梯状变化趋势增加;回填体黏聚力取决于质量浓度,内摩擦角受质量浓度和废石掺量影响程度基本相同,两者协同作用;质量浓度在80%～88%范围时,黏聚力随质量浓度增大呈非线性增大,内摩擦角与质量浓度呈S型变化趋势;抗剪强度随质量浓度的增大而增加,在82%～84%区间抗剪强度变化显著,流动性出现突变。     

二纺蛛总科（蜘蛛目：新蛛下目）蜘蛛化石研究进展

二纺蛛总科包括5个现生科、5个化石科以及一些科级位置未定的化石物种,是蜘蛛目中较为古老的一个类群。目前已知最早的二纺蛛总科化石记录可以追溯到早侏罗世,但分子系统发育研究推测其起源时间为二叠纪。二纺蛛总科蜘蛛在中生代最为繁盛,化石物种相对较多,是蜘蛛化石类群的重要组成部分。而现生二纺蛛总科蜘蛛十分稀少,且主要分布在热带和亚热带地区。近年来的系统发育研究认为二纺蛛总科可能是复杂生殖器类的姐妹群,是蜘蛛演化研究的关键类群。因此,本文对二纺蛛总科分类系统的研究历史进行了回顾,总结了二纺蛛总科化石类群在不同地质历史时期的组成和分布,统计了二纺蛛总科蜘蛛化石的名录。目前,二纺蛛总科蜘蛛化石分类研究基础薄弱,部分化石类群的系统位置存疑,二纺蛛总科内部系统发育关系尚不清晰。在将来的研究中,需要利用多种技术手段获取化石材料的形态学信息,打好分类学基础;结合化石类群和现生类群进行系统发育分析;进而联系古地理、古生态、生物学行为等研究,全方位分析二纺蛛总科的自然演化历史。     

混合表面活性剂存在下镓与O—Cl—PF显色反应的研究

本文研究了在pH 6.5-7.8的(CH_2)_6N_4-HCl缓冲介质中,CDMAA和TritonX-100对Ga与o-Cl-PF和F~-显色反应的增敏作用。结果表明,Ga-o-Cl-PF-F-CDMAA-TritonX-100多元配合物λ_(max)为565nm,表观摩尔吸光系数ε=1.74×10~5L·mol~(-1)·Cm~(-1),Ga含量在0～6.0μg/25ml范围内符合比尔定律,用合成样和标样进行本方法考验,结果满意。     

Interaction of crustal and mantle materials,sources of trace elements during the formation and evolution of Early Paleozoic Li-rich granite-pegmatite systems in southeastern Tuva

We present new data on the age, composition, and environments of formation of granites of the Kystarys complex and the associated Li-rich rare-element pegmatites of the South Sangilen pegmatite belt including the large Tastyg lithium deposit. It has been established that they formed during the Early Paleozoic collisional orogeny in the Tuva-Mongolian massif at the Cambrian-Ordovician boundary. The granites of the Kystarys complex are moderately alkaline high-K rocks and are enriched in Zr, Nb, Y, and REE; therefore, they are classified as postcollisional, transitional to within-plate (A-type). The spodumene pegmatites of the South Sangilen pegmatite belt are similar to the above granites in age and isotopic and geochemical parameters, which suggests a paragenetic relationship between these rocks. Pegmatites form several pegmatite fields within the belt, which differ in trace-element signatures. In addition to predominant Li, Cs, and Ta, specific to all spodumene pegmatites (LCT family), pegmatites of two fields have high contents of Nb, Y, REE, and Zr, which are indicator elements of NYF family pegmatites. It has been established that the formation of spodumene pegmatites with combined LCT-NYF geochemical signatures was preceded by the intrusion of dikes of monzogabbro with the geochemical characteristics of OIB and of alkali aegirine granites and by the formation of associated metasomatites enriched in Zr, Nb, Y, and REE. Based on the geological, mineralogical, and geochemical data, we substantiate the hypothesis of the formation of Li-bearing granite-pegmatite melts from a mixed source resulted from the influence of fluids of an alkaline igneous complex of mantle genesis on the crustal protolith.     

塔里木盆地英买力地区原油地球化学特征与族群划分

塔里木盆地英买力地区油气成因复杂,采用多馏分、多组分化学成分分析及单体烃碳同位素分析途径,对该区海相、陆相油进行精细分析。结果表明,英买力油田主要有两大类油组,分别是南部YM2井区的海相油(I类)和北部YM7井区的陆相油(Ⅱ类),各自具有典型的海相油与陆相油的特征。进一步分析表明,两大油组内部仍有分异。将第二油组进一步分为两亚类,以中、古生界产层为主的正常黑油和重质油为一类(Ⅱa),以古近系为主的凝析油为另一类(Ⅱb)。两亚类原油正构烷烃单体烃同位素稍有差异,芳烃组成与分布具有显著差异。较之于Ⅱa原油,Ⅱb原油富含联苯系列与氧芴系列、不同类型芳烃系列中以低分子量同系物占绝对优势,其正构烷烃单体烃碳同位素更重,与相邻的羊塔克地区原油表现出一定的相似性,表明两者之间有一定的成因联系,前者可能为混源油,由位于库车坳陷中拜城凹陷提供两种陆相烃源岩。英买力地区陆相油并非以往确认的一种成因类型,可能至少由两套性质迥异的中生界烃源岩供烃。英买力地区第一类海相油(I类)尽管生物标志物特征相近,但分析原油的单体烃碳同位素具有显著差异,同样存在油气混源的可能。英买力地区海、陆相原油特征与成因的深入剖析,对于该区精细油源确认、油气成藏机制乃至油气资源评价具有重要意义。