量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。     

ELECTROCHEMICAL CORROSION BEHAVIOR OF STEEL IN THE JUNCTURE AREA OF SEA CLAY AND SAND

Corrosion behavior of steel in the juncture area of sea clay and sand was studied. The results show that galvanic corrosion occurred between steel samples buried in sea clay and sand, and that the polarity of the galvanic cell reversed after some testing later. The cause of reversing of polarity is discussed.     

PROPAGATION OF 30—60 DAY LOW FREQUENCY OSCILLATIONS AND THEIR INFLUENCE UPON THE SUBTROPICAL WESTERLIES JET STREAM DURING NORTHERN HEMISPHERE WINTER

Based on daily ECMWF gridpoint data of two winters during 1981—1983 including an ENSOyear,propagation of low frequency oscillations(LFO)during Northern Hemisphere winters andtheir influences upon 30—60 day oscillations of the subtropical jet stream are studied with the sta-tistical methods as complex empirical orthogonal function(CEOF)and so on.Results show that inthe winter of a normal year(1981—1982),30—60 day oscillations in the subtropical zone aremainly in the northern and southern flanks of exit region of jet stream.In the ENSO year(1982—1983),they are mainly in the vicinity of entrance and exit regions of jet stream.Intraseasonalchanges of subtropical jet stream manifested themselves as latitudinal fluctuation or longitudinalprogression or regression of about 40 day period.There are marked differences between propagat-ing passages of low frequency modes responsible for changes of subtropical jet stream in the normalyear(1981—1982)and in the ENSO year(1982—1983).Changes of oscillation amplitude showobvious phases.In general,the one in late winter is stronger than that in early winter,strongestone occurs in February.     

Optical Flash of GRB 990123: Constraints on the Physical Parameters of the Reverse Shock

The optical flash accompanying GRB 990123 is believed to be powered by the reverse shock of a thin shell. With the best-fit physical parameters for GRB 990123 and the assumption that the parameters in the optical flash are the same as in the afterglow, we show that: 1) the shell is thick rather than thin, and we have provided the light curve for the thick shell case which coincides with the observation; 2) the theoretical peak flux of the optical flash accounts for only 3×10~-4 of the observed. In order to remove this discrepancy, the physical parameters, the electron energy and magnetic ratios, εe and εB, should be 0.61 and 0.39, which are very different from their values for the late afterglow.     

FARMLAND AND URBAN AREA DYNAMICS MONITORING INCHINA USING REMOTE SENSING AND SPATIALSTATISTICS METHODOLOGY

1 INTRODUCTIONGlobal change research involves much geo-objectsand geo-process, such as climate and environmentalchange, substance and energy cycling, land-use/land-cover change (LUCC), interactivity between human and nature, etc.. So it need cooperation frommany research communities including international research programs groups such as IGBP (InternationalGeosphere-Biosphere Programme IPCC (Intergovemmental Panel on Climate Change), IHDP (InternationalHuman Dimension Program o…     

香蕉新品系“93-1”选育初报

从香蕉(Musa AAA)组织培养繁殖后代中,选育出特长果指香蕉新品系“93-1”,主要特点为植株表现中矮秆(216 cm),茎粗中等(67.1 cm),苗期叶色浓绿,叶形椭圆形,叶形比(长/宽)1.91,叶尖急尖,叶基凹陷呈耳垂状;果穗7~12梳,平均8.07梳/穗,穗长81.6 cm,单穗重22.8 kg,单果重213.5 g,果指数123.4条/穗,果指特长(25.8 cm);可溶性固形物含量21.8%;全生育期321d(春植)至368 d(夏植),约44片叶。“93-1”适宜在广东雷州半岛及海南岛栽培种植。     

A note on turbulent perturbations of salinity in a partially mixed estuary

Measurements of salinity perturbations in a partially mixed estuary have been used to evaluate the usefulness of an inductive salinometer and to determine some of the characteristics of the salinity perturbations. The salinometer performed satisfactorily under most conditions. Although internal wave like effects were present, the turbulence fluctuations were dominant. The salinity fluctuations and the turbulent fluxes $\text{sw}$ and $\text{su}$ were found to behave in a manner similar to the density fluctuations in a thermally stratified atmospheric boundary layer and a laboratory open channel flow. A quadrant analysis suggested that the contribution of each quadrant to the turbulent flux changed with Ri. The turbulence parameters ν and c_γ were found to decrease and increase respectively as Ri increases.     

Results from the Whole Earth Telescope — Indian contributions

The Indian team at ISRO has been part of the Whole Earth Telescope (WET) team since 1988 when we first participated in the campaign on V471 Tau. We have been part of many other observing campaigns over the last decade. This presentation traces the circumstances leading to our joining the WET team and how useful the coverage from the Indian longitude has been. The results of several pulsators from the WET runs during which we participated are also described. These include PG1159-035 the prototype of the GW Vir type of stars, RE J 0751+14 a cataclysmic variable, PG 1336-018 a binary with an sdB pulsator and finally HR 1217 a roAp star. The paper concludes with what the limitations are in our observations and how we can overcome them in the future.     

Evolution of Polytropic Reimann Disks in Halos

The equilibrium of elliptical Riemann disks with a polytropic equation of state and their evolution under the influence of viscosity and gravitational radiation inside spheroidal halos with a relative surface mass density k. The evolutionary trajectory of a disk inside a halo with k<0.5, which is analogous to the evolution of an isolated disk, differs from that of a disk inside a denser halo.     

STUDY ON GIS FOR YIELD ESTIMATION BY REMOTE SENSING IN JILIN MAIZE BELT

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