西藏双湖地区南措铜金矿区花岗闪长岩锆石U-Pb年代学、岩石地球化学及成因

对南措铜金矿区与成矿相关的黑云母花岗闪长岩体进行了岩相学、锆石U-Pb年代学、岩石地球化学等方面的研究。结果表明:该岩体年龄为153.40±0.67 Ma,属晚侏罗世。岩石为准铝质-过铝质岩石,属钙碱性系列。LaN/YbN=9.31~12.65,轻重稀土元素分馏明显,δEu=1.21~1.66,Eu表现为正异常;样品微量元素表现为相对富集大离子亲石元素(LILE)K、与高场强元素(HFSE)Sr、Zr,而亏损高场强元素(HFSE)U、Nb、Ce、Nd、P的特征。岩体具有I型花岗岩特征。样品Zr/Hf值为42.23~45.82,平均值为44.2;Rb/Sr比值为0.07~0.19,平均值为0.13;Nd/Th值为1.65~2.18,平均为1.99,具壳源岩浆的特征,并有地幔物质混入。样品的Mg#值为49.80~57.22,Sr值为443.3~874.9,Yb值为0.80~1.39,Y值为8.96~16.60,Na2O/K2O2(2.18~2.97),为洋壳型埃达克岩,并在上升过程中可能有少量地幔楔物质混入。结合前人研究成果认为,该花岗闪长岩形成于晚侏罗世班公湖—怒江洋盆向北俯冲的火山弧环境。     

不同方法评价喀斯特煤矿区农田土壤重金属生态风险比较

采用TCLP法、内梅罗综合污染指数、嵌入Igeo综合污染指数法等方法对贵州织金县某煤矿区周边农田土壤重金属进行评价。土壤中Cd、Cr、Cu、Ni、Hg和Zn的含量范围分别为0.79～2.08 mg·kg-1、144.20～464.40 mg·kg-1、91.63～187.50 mg·kg-1、48.13～104.47 mg·kg-1、0.14～2.33 mg·kg-1、144.35～265.89 mg·kg-1,所有土壤样点的Cd、Cr、Cu和Ni含量均已超过国家土壤环境质量二级标准,部分土壤样点的Hg和Zn含量超过二级标准。TCLP法评价结果所有土壤样点均未受到重金属污染;内梅罗综合污染指数法评价结果为农田土壤重金属生态风险处于安全水平;嵌入Igeo综合污染指数法评价结果表明,90%的土壤达到中度污染以上,其中65%的土壤处于中度污染,25%的土壤受到中度至重度污染;潜在生态危害指数法评价表明,所有土壤样点重金属均处于轻微生态风险水平。针对不同评价方法得出的结果存在差异的情况,在评价土壤重金属污染状况时,应根据评价目标的差异选择合适的评价方法。      

微波等离子体原子发射光谱法测定偏远矿区海泡石中的主微量元素

海泡石是具有层状结构的含水富镁硅酸盐黏土矿物,其中无机元素含量是揭示其成矿物质来源、成矿流体性质和矿床成因的重要依据,通常采用电感耦合等离子体发射光谱/质谱法(ICP-OES/MS)进行测定,等离子体(ICP)的高温激发会产生成大量谱线干扰,维持ICP稳定工作需使用高纯氩气,持续供气对于偏远矿区海泡石的检测还将面对气体采购和运输不便的问题。本文基于微波等离子体原子发射光谱(MP-AES)的低温激发技术减少光谱干扰,建立了准确测定偏远矿区海泡石中主量元素Mg、Al、Ca、Fe、K、Na和微量元素Cu、Zn、Mn、Pb含量的分析方法。利用硝酸-盐酸-氢氟酸混合酸对海泡石进行微波消解,避免了样品处理过程中分析元素的损失,加快了样品处理速度,同时提高了样品溶液的稳定性。通过选择各元素光谱线的分析波长,并利用快速线性干扰校正(FLIC)技术校正光谱干扰,以Lu为内标元素校正基体效应,提高了灵敏度和准确度。各元素的检出限为0.19～14.6μg/L。海泡石国家标准物质(GBW07138)各元素测定值与认定值的相对误差在-5.0%～6.7%之间。本方法具有检出限低、线性范围宽、结果准确等优点;MP-AES采用自带的氮气发生器为等离子体提供氮气作为工作气,无需引入复杂气体,提高了分析效率,尤其适用于气体采购和运输不便的偏远矿区。     

老盐井组井型互换再利用工程实践

水平钻井连通水溶采卤一直是开采井矿盐资源最常用和最经济有效的手段,但由于地层条件复杂、饱和卤水结晶、套管破损等因素造成盐井组采卤运行过程中通道堵塞,一直是制约盐井组运行年限的主要原因。近些年,对堵塞井组修治常用方法有憋压、通井、开窗侧钻,其中水平井开窗侧钻重新对接现有溶腔在很多盐田区块修井中被广泛应用。在河北宁晋石盐田Y2-Y4井组修井过程中,存在老溶腔无法再利用的情况,此时老溶腔成为井组二次对接的“累赘”。在该区块首次采用井组井型互换（水平井改直井,直井改水平井）的方法,避开了老溶腔,实现了老井组的再利用。     

气候变化与人类活动对石家庄市藁城区地下水位埋深的影响分析

为了探寻石家庄市藁城区地下水埋深动态变化规律,以藁城区2001—2018年的年降水量、地下水人工开采量等数据为基础,对藁城区地下水位埋深进行研究。首先采用P-Ⅲ型曲线法确定降水序列的丰、平、枯年份,分析不同降水量情况下地下水位埋深变化规律;其次,利用地下水开采潜力系数法和灰色关联度法对人工开采量和地下水位埋深的关系进行研究。结果表明：1）藁城区地下水位埋深在2001—2016年逐渐增大,在2016—2018年趋于减小,2016年为转折点;在空间上藁城区地下水位埋深呈现出北部埋深小、南部埋深大的特征,北部水位埋深较同期南部水位埋深要浅5~10 m。2）降水是驱动藁城区地下水位埋深变化的重要因素,枯水年水位埋深变幅在0.8~1.5 m之间,平水年水位埋深变幅在0.3~1.2 m之间,丰水年水位埋深变幅在0.3~1.1 m之间。主灌期（3—6月）的地下水位埋深增加速率均为cm/d级,非主灌期（7—10月）的地下水位埋深减少速率均为mm/d级。3）人工开采是驱动藁城区地下水位埋深变化的主导因素,其中农业开采量占人工开采量的80%。综上认为,藁城区一直处于严重超采状态,地下水累计超采量每增加1亿m³,地下水位埋深增加0.45 m。     

Migration and speciation transformation mechanisms of mercury in undercurrent zones of the Tongguan gold mining area,Shaanxi Loess Plateau and impact on the environment

In order to study the migration and transformation mechanism of Hg content and occurrence form in subsurface flow zone of gold mining area in Loess Plateau and its influence on water environment, the field in-situ infiltration test and laboratory test were carried out in three typical sections of river-side loess, alluvial and proluvial strata in Tongguan gold mining area of Shaanxi Province, and the following results were obtained: (1) The source of Hg in subsurface flow zone is mainly caused by mineral processing activities; (2) the subsurface flow zone in the study area is in alkaline environment, and the residual state, iron and manganese oxidation state, strong organic state and humic acid state of mercury in loess are equally divided in dry and oxidizing environment; mercury in river alluvial or diluvial strata is mainly concentrated in silt, tailings and clayey silt soil layer, and mercury has certain stability, and the form of mercury in loess is easier to transform than the other two media; (3) under the flooding condition, most of mercury is trapped in the silt layer in the undercurrent zone where the sand and silt layers alternate with each other and the river water and groundwater are disjointed, and the migration capacity of mercury is far less than that of loess layer and alluvial layer with close hydraulic connection; (4) infiltration at the flood level accelerates the migration of pollutants to the ground; (5) the soil in the undercurrent zone is overloaded and has seriously exceeded the standard. Although the groundwater monitoring results are safe this time, relevant enterprises or departments should continue to pay attention to improving the gold extraction process, especially vigorously rectify the small workshops for illegal gold extraction and the substandard discharge of the three wastes, and intensify efforts to solve the geological environmental problems of mines left over from history. At present, the occurrence form of mercury in the undercurrent zone is relatively stable, but the water and soil layers have been polluted. The risk of disjointed groundwater pollution can not be ignored while giving priority to the treatment of loess and river alluvial landform areas with close hydraulic links. The research results will provide a scientific basis for water conservancy departments to groundwater prevention and control in water-deficient areas of the Loess Plateau.     

Detection of coffee berry necrosis by digital image processing of landsat 8 oli satellite imagery

Coffee berry necrosis is a fungal disease that, at a high level, significantly affects coffee productivity. With the advent of surface mapping satellites, it was possible to obtain information about the spectral signature of the crop on a time scale pertinent to the monitoring and detection of plant phenological changes. The objective of this paper was to define the best machine learning algorithm that is able to classify the incidence CBN as a function of Landsat 8 OLI images in different atmospheric correction methods. Landsat 8 OLI images were acquired at the dates closest to sampling anthracnose field data at three times corresponding to grain filling period and were submitted to atmospheric corrections by DOS, ATCOR, and 6SV methods. The images classified by the algorithms of machine learning, Random Forest, Multilayer Perceptron and Naive Bayes were tested 30 times in random sampling. Given the overall accuracy of each test, the algorithms were evaluated using the Friedman and Nemenyi tests to identify the statistical difference in the treatments. The obtained results indicated that the overall accuracy and the balanced accuracy index were on an average around 0.55 and 0.45, respectively, for the Naive Bayes and Multilayer Perceptron algorithms in the ATCOR atmospheric correction. According to the Friedman and Nemenyi tests, both algorithms were defined as the best classifiers. These results demonstrate that Landsat 8 OLI images were able to identify an incidence of the coffee berry necrosis by means of machine learning techniques, a fact that cannot be observed by the Pearson correlation.     

黄土山区煤层群分层开采地表位移规律分析

为了研究黄土山区地形对煤层群开采地表位移的影响,以榆林某矿为地质原型,利用数值软件模拟地表为近水平、正坡、负坡、凸面和凹面五种地形条件下煤层群开采。结果表明:黄土山区地形的变化,对煤层群开采顶板垂直应力影响不明显,对地表位移影响较大;单向坡开采,斜坡滑移引起的下沉量在坡顶与开采沉陷量形成“叠加”,在坡底形成“抵消”;在组合坡中,煤层群开采地表位移量相差很大,说明在变坡点附近地表位移较为复杂。     

基于时空聚类的出租车载客热点区域挖掘研究

针对出租车运营过程缺少路径优化指导造成运营能力分布不均、空载率高的问题,本文以成都市安装有GPS设备的出租车所采集的轨迹数据为研究对象,以提高出租车效益为目标,采用了一种基于网格的出租车载客热点聚类算法,通过对出租车GPS轨迹数据进行处理和聚类分析,充分挖掘出租车载客热点区域,从而为出租车的运营者和管理者提供信息决策服务。