高温高压下水岩界面反应与金的迁移富集

高温高压下水岩界面反应与金的迁移富集王玉荣阚小凤王志强（中国科学院广州地球化学研究所，广州５１０６４０）关键词水岩界面反应自发电池实验地球化学本实验以哈达门沟［１］及东坪金矿［２］为地质背景，研究钾长石岩中金矿化富集的物理化学条件。该区金矿既与早期变...     

Science and the desertification debate

Desertification is an environmental issue that has major environmental and social dimensions, and which has been controversial in a number of respects. The recent UN Convention on Desertification and Drought places considerable emphasis on the social dimensions of the problem and the role local peoples and NGOs have to play in tackling it. When desertification first became regarded as a major issue in the 1970s, science was seen to have a major role in understanding and solving the problem, but in some circles has been regarded as failing to contribute usefully. This paper explores the nature of scientific contributions, why science may have been seen to fail to serve the needs of policy-makers, and why scientific findings may have been misinterpreted in broader circles dealing with the issue. It concludes by identifying areas where science has still a valuable role to play in an issue that is now perhaps regarded as more political and social than scientific.     

不整合界限地层单位确立及划分的重要意义──兼论华北地层区不整合界限地层单位的划分和命名

在进行岩石地层划分时，有必要进行不整合界限地层单位的划分。不整合界限地层单位是顶底以不整合界面为限，而由有关联的若干个基本岩石地层单位──组（群）组成的组合。和岩石地层单位一样，是自然界存在的客观实体。初步建议华北地区划分为８个不整合界限地层单位：桑干河序列、五台山序列、滹沱河序列、秦幽序列、冀鲁序列、三晋序列、燕辽序列、河海序列。不整合界限地层单位的划分、确立，是进行地层格架分析、进行层序地层学研究的前提，有利于以岩石地层单位（即以不整合界限地层单位）编制小比例尺地质图。     

湖泊沉积物-水界面营养元素的生物地球化学作用和环境效应 Ⅰ.界面氮循环及其环境效应

发生在沉积物-水界面的剧烈生物地球化学作用对沉积物和上覆水体具重要的环境效应，然而此方面研究很少。本文通过云贵高原四个湖泊湖水和孔隙水NH和NO剖面，沉积物柱芯不同结合态氮含量剖面分布，界面扩散通量，影响氮循环的因素及它们季节性变化规律等的对比研究，初步揭示了湖泊沉积物一水界面的氮循环及其环境效应。     

岩盐及芒硝中各种化合物质量分数的计算

本文以等物质的量的反应规则建立了岩盐、芒硝中各种化合物的质量分数的计算公式。这些公式既符合法定计量单位的要求，又方便计算。     

Oxygen Isotope Exchange Kinetics Between Coexisting Minerals and Water in the Aral Granite Pluton of the Altay Mountains, Northern Xinjiang

Coexisting quartz, feldspar and biotite vary widely in their δ18O values and display a remarkable 18O/16O disequilibrium relation; especially, a quartz-feldspar reversal (△ 18OQUartz_feldspar< 0) exsists in the Aral granite pluton of the Altay Mountains, northern Xinjiang. The 18O / 16O exchange reaction definitely occurred between granite and water. Initial δ18O values of the granite and exotic fluid are evaluated by the mass balance consideration. The conventional method of discrimination between various magma derivations simply with δ18O values of either whole rock or separate minerals is misleading and unreliable. Experiments carried out by the authors show that the 18O / 16O exchange reaction is not accompanied by what geologists describe as petrological and mineralogical alteration effect. This decoupling relation implies that exchange reaction occurs at a relatively high temperature during subsolidus-postmagmatic cooling of magmas. The exchange mechanism is mainly diffusion-controlled. It is     

5－（4－羧基苯偶氮）－8－（对甲苯磺酰氨基）－喹啉与金显色反应研究及应用

以８－氨基喹啉为母体，合成了新试剂５－（４－羧基苯偶氮）－８－（对甲苯磺酰氨基）－喹啉（ＣＰＴＳＱ），研究了它与Ａｕ的显色反应，在ＣＴＭＡＢ存在下，于ｐＨ１０～１３的ＮａＯＨ介质中，ＣＰＴＳＱ与Ａｕ形成２：１紫蓝色络合物，最大吸收峰位于６１０ｎｍ，摩尔吸光系数１．０×ｌ０５Ｌ·ｍｏｌ－１·ｃｍ－１，Ａｕ含量在０～１．２ｍｇ／Ｌ内符合比尔定律。方法选择性好，灵敏度高，操作简便，已用于金矿石样品中Ａｕ的测定，结果满意。     

应力波与可滑移岩石界面间的相互作用研究

研究了应力波与用节理刚度系数描述的线性滑移岩石界面间的相互作用，给出了其透、反射波幅的一般表达式。通过应力波垂直人射界面时的具体分析，反映出岩石界面的节理刚度对应力波传播的重要影响，并揭示了岩石界面对应力波的高频滤波作用。     

高温超高压下Ni40Mn30Fe30与叶蜡石反应的研究

本文对Ｎｉ４０Ｍｎ３０Ｆｅ３０合金与在不同焙烧温度下得到的含水叶蜡，在高温超高压下的反应进行了实验研究，温度测至１４２０℃，压是至５．５ＧＰａ，研究了该反应的物质－化学机制，以及反应速率与温度，压力，含水量等参数的关系，对高压下物质迁移运动的固有特征进行了探讨。