碳中和目标下关键矿产在清洁能源转型中的作用、供需分析及其建议

在"碳中和"目标的驱动下，全球能源系统向清洁化、低碳化甚至无碳化发展已是大势所趋。针对向清洁能源转型的需求，采用了统计对比、分类汇总、综合分析等方法，分析研究了关键矿产在电池、电网、低碳发电和氢能等行业中的作用和需求。结合当前关键矿产产量的地理集中度高、项目开发周期长、资源质量下降等矿产供应和投资计划不能满足清洁能源转型的需求等问题，提出确保关键矿产多样性供应，推动价值链各环节的技术创新，扩大回收利用，增强供应链弹性和市场透明度，将更高的环境、社会和治理标准纳入主流程及加强生产者和消费者之间的国际合作等建议。     

我国藻菌生物成因的金矿研究

生物成矿作用分为生物直接成矿作用和生物间接成矿作用,生物直接成矿作用的标志结构为生物有机胶体结构。生物间接成矿作用的标志结构为“矿交代生物”结构,我国陕西二台子－半仓沟金矿,四川东北寨金矿、川甘拉尔玛金矿和云南金厂金矿等均为典型为实例,矿石中普遍含有多种金属矿物生物结构,还含多种生物有机组分。成矿物质具有多源性特征,硫同位素具混合型特征,矿床成型机制可与“人工碳吸附系统”聚金机制相类比,含金层位可     

Possible ways to decipher spatial distribution of mineral resources

Regularity of structural patterns can be connected to planetary disjunctive systems (paleosystems). A computerized universal model of these systems should be developed that may be helpful to predict unknown localities of mineral resources controlled by tectonic processes. The specific character of tectonic phenomena is to be respected in geomathematical models. Some suggestions for applications are given.     

Catalytic ozonation of phenol in water with natural brucite and magnesia

Catalytic ozonation has attracted much attention in treatment of wastewater for its mild conditions. Phenol and its ramifications are common components in a wide variety of wastewaters including those from coal conversion processes, coking plants, petroleum refineries and several chemical industries. In this paper, natural brucite and magnesia have been successfully used in catalytic ozonation of phenol. And the mechanisms of catalysis were also investigated. From Figs. 1 and 2, it can be found that both brucite and magnesia have remarkable catalysis on degradation of phenol and removal of Chemical Oxygen Demand （COD）. The pH of solutions on the process of ozonation alone, catalytic ozonation with brucites and with magnesia were 6.35-2.76, 10.18-8.52 and 10.58-10.83, respectively. It can be concluded that alkali environment plays a critical role for catalytic ozonation of phenol. We also found that the alkaline minerals reacted on the surface with oxalic acid and other low molecular-weight acids which are intermediate products in ozonation, but those intermediate products could be mineralized into carbon dioxide completely with enough ozonation time.     

GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.     

Reference Materials in Geoanalytical Research -Review for 2004 and 2005

This review gives an overview of the use and development of reference materials of geochemical and environmental interest in the literature of the years 2004 and 2005. In these years the performance of existing methods has been improved and new geochemical applications using new techniques have been developed. Accordingly, there was an increasing need for new reference materials, especially for in situ microanalysis and for precise stable isotope measurements. In addition, there was a notable trend for further characterisation of existing reference materials, mainly for the platinum-group elements. This review focuses on five topics: reference materials for platinum-group elements, reference glasses for in situ microanalysis, zircon reference materials, isotopic reference materials, and the development and certification of reference materials.     

四川盆地地下卤水资源优势及综合开发前景

四川盆地地下卤水自震旦系至白垩系各层系皆有分布。卤水具有分布广泛、资源丰富、品质优异、高承压及气卤同产等优势特点,是四川得天独厚的液态矿产资源。卤水中含有K+、Br-I、-、B3+、Li+、Sr2+、Rb+等多种有用组分,皆为国家紧缺和紧俏物质,其含量多数可达工业开采品位,为优质化工原料水,经济价值极高,综合开发利用前景广阔。     

Structural Evolvement of Heating Treatment of Mg/AI-LDH and Preparation of Mineral Mesoporous Materials

Although hydrotalcite, or layered double hydroxides （LDHs）, is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of （Mg, Al）-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like （Mg, Al）-oxide is transformed into a composite with periclase （MgO） and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition.     

Weathering characteristics of arctic islands in northern Norway

The arctic islands of the Lofoten-Vesterålen archipelago in northern Norway have a wide distribution of weathered land surfaces commonly located above 250 m with several apparent similarities. In order to investigate the characteristics of (deep) weathering in this region, northern Langøya and Hadseløya were chosen for in-depth analyses. Eight weathering profiles were excavated from various surfaces, and the stratigraphies were logged in detail. Material was collected throughout the weathering horizons, and all samples were subsequently analysed for clay mineralogy (< 63 μm fraction) and grain size distribution. The sampling strategy was complemented by samples from additional saprolites and other landforms such as moraines and rock glaciers. The XRD results indicate that the presence of secondary minerals, such as gibbsite (Al(OH)₃) and kaolinite (Al₂Si₂O₅(OH)₄), are very common throughout the profiles. Gibbsite is an extreme end product of silicate weathering and usually associated with a warmer and more humid climate, as found in Scandinavia during the Tertiary. The grain size analyses (< 63 μm) show that the finer silt fractions (< 8 μm) tend to be high in the profiles (20–40%), with significant amounts of clay (5–15%) demonstrating that the regolith itself is susceptible to frost sorting mechanisms.¹⁰Be exposure dates from in situ quartz knobs on tors and boulders of local origin suggest > 40,000 years of subaerial conditions. Considering the steady surface erosion, this figure should be viewed as an absolute minimum age estimate. Mapping of the superficial sediments and geomorphological features of the study areas has revealed several common morphological features, which indicate dominance of glacial and periglacial processes in the areas lying below the lower boundary of blockfields (c. 250 m). The weathering mantles are not a periglacial end product, but rather a relict tertiary landform that were modulated by permafrost processes as well as biological processes at later stages. The regolith cover constrain the vertical extension of warm-based Quaternary ice sheets challenging the notion of a parabolic ice mass consuming every mountain top of Lofoten and Vesterålen.     

秦皇岛市矿产开发引发的地质环境问题及对策

秦皇岛市矿产资源丰富,矿业已成为秦皇岛市特别是地方经济的支柱之一。伴随着矿业的发展,在矿产开发过程中引发的地质环境问题日益突出,如采空区地表变形(地面塌陷、地裂缝等)、岩溶塌陷、露天采矿边坡失稳、尾矿引发的泥石流、水土流失以及地貌景观的破坏等。这些地质环境问题主要分布在北部的山区和丘陵台地区。形成的原因复杂,主要有法制不健全、缺乏强制恢复机制、布局不合理、监管不到位、开采技术落后、不合理开采、资金缺乏以及从业者环保意识淡薄等方面的原因。对于矿山地质环境的保护,应采取加强立法、建立保证金制度、统一规划、加强监管、加大宣传力度以及建立责任追究制度等措施。