矿产资源开发中矿山地质环境问题响应差异性研究——以陕西潼关、大柳塔及辽宁阜新矿区为例

以陕西潼关、大柳塔及辽宁阜新矿区为例,采用对比分析的方法研究矿产资源开发中矿山地质环境问题差异性响应的主要因素。上述3个矿区矿产资源开发中矿山地质环境问题主要包括：20世纪90年代以前,陕西潼关金矿区是中国矿产资源开发秩序十分混乱的矿区之一,地下开采的采矿废石随意堆排导致了极为严重的矿山泥石流地质灾害及其隐患,＂三废＂无序排放导致土壤、河水及其底泥的重金属及氰化物污染严重,严重影响人体健康;地处生态环境脆弱带的陕西大柳塔煤矿区,20年大型机械化地下煤炭资源开采导致大面积地面塌陷及其链生的地下水含水层破坏严重,但矿区土地沙漠化程度总体没有呈现加重的趋势,水土环境重金属呈轻度污染;具有百年开发历史的辽宁阜新煤矿区,露天开采使土地生态破坏严重、边坡滑坡灾害频发、土地压占与破坏突出,地下开采引起的地面塌陷对地表建筑物及人居安全影响严重,但相对于金属矿区,该矿区水土环境重金属污染相对轻得多。对比上述3个矿区矿山地质环境问题,得到其差异性响应主要因素：矿产资源种类、原生地质环境条件、开采方式及矿山环境保护意识等。     

黔东铜仁地区寒武系热液白云岩特征及其成矿意义*

黔东铜仁地区寒武系清虚洞组和娄山关组中分布有多处热液白云岩,其形态包括块状、透镜状、角砾状等。通过露头及薄片观察、流体包裹体温度测定、稀土元素和锶同位素分析,笔者探讨了研究区不同类型热液白云岩的形成机制、热液性质与来源及其与铅锌成矿作用的关系。结果表明: (1)热液白云岩由中粗晶-巨晶鞍状白云石组成,形成温度为96~223 ℃,平均为155.86 ℃;盐度为8.28~16.15 wt% NaCl,平均为12.30wt% NaCl;具有轻稀土富集和Ce负异常特征,LREE/HREE为16.51,δCe为0.79, ⁸⁷Sr/⁸⁶Sr为0.708662。(2)块状和透镜状热液白云岩形成于交代作用较完全的环境,角砾状热液白云岩可能形成于水力破裂作用;白云石化流体可能来自包括震旦系碳酸盐岩在内的下伏地层,断层和裂缝为其运移通道。(3)白云石化流体与区域铅锌成矿流体温度、盐度和地球化学特征相近,来源相同或相似;热液白云岩中含有少量成矿物质,应形成于铅锌主成矿期前后。     

江西朱溪铜钨矿区煌斑岩LA-ICP-MS锆石U-Pb同位素定年及地质意义

江西朱溪超大型矽卡岩铜钨矿的重大找矿突破,确定了"南钨北铜"格局被打破,建立了"南钨北扩"的新格局,成矿相关岩浆岩的时代及构造属性的研究是分析"南钨北扩"科学问题的关键。朱溪铜钨矿区分布数条煌斑岩脉,在时空上与铜钨矿床有关。本文在详细野外调查、岩心编录和岩矿鉴定的基础上,利用激光剥蚀-电感耦合等离子体质谱技术(LA-ICP-MS)对朱溪铜钨矿区的煌斑岩进行锆石U-Pb法同位素精确测年,获得两组岩浆锆石年龄:其中一组锆石的206Pb/238U加权平均年龄为(856±10)Ma(MSWD=0.22),另一组锆石的206Pb/238U加权平均年龄为(160.3±2.1)Ma(MSWD=0.17)。分析研究认为:第一组年龄(856±10)Ma代表了新元古代早期华南古洋壳俯冲消减及杨子陆块与华夏陆块碰撞的岩浆作用;第二组年龄(160.3±2.1)Ma代表了晚侏罗世早期岩浆侵位事件,是在早侏罗世古太平洋板块向欧亚板块之下俯冲消减的背景下,导致早期岩石发生重熔,在燕山期侵位成岩,与朱溪所在的塔前—赋春成矿带内的成矿作用时间接近。本工作对煌斑岩同位素年代学的研究,为研究朱溪铜钨矿的成矿作用提供了理论依据。     

The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.     

全国危机矿山接替资源找矿专项煤炭项目成果综述

煤炭是我国最重要的基础性能源,经过数十年高强度的开采和开发,一大批大中型矿山资源枯竭,成为危机矿山。通过煤炭资源找矿专项的实施,取得了重大的找矿进展：①新发现并查明了一批资源储量,延长了诸多危机矿山的服务年限;②对我国深部找煤勘查方法进行了初步总结;③丰富了我国聚煤作用研究的内容．使老矿山深部和外围找煤理论和方法得以完善;④在复杂地质条件勘查区（推覆体下、红层下及火成岩下）找煤取得突破性的进展。     

矿井深部巷道围岩变形浅析及控制

矿井深部巷道开挖后处于裂隙、塑性、弹性围岩包围范围内。通过计算对包围巷道围岩的3种圈层范围的力学性能进行分析,进而阐述了巷道的变形机制,得出了塑性圈层围岩内的应力应变表述式。对于选择巷道的支护机制,经济有效的控制裂隙化圈层范围的扩大,改善其应力状态,提高其自身的残余强度和承载能力,对深井巷道锚杆综合支护体系的选择,提供了一定的理论支持。     

权家河煤矿褶皱构造发育特征

系统分析了权家河煤矿不同规模褶皱构造的形态特征、组合方式和展布规律,探讨了造就褶皱构造发育特征的地质条件及其演化过程。从而为指导权家河煤矿生产和揭开渭北煤田地质构造发育规律的面纱提供了依据。      

清镇式铁矿矿石特征及加工技术性能探讨 ——以猫场铝土矿红花寨、白浪坝矿段铁矿床为例

贵州中部清镇、修文等地石炭系铝土矿底部的铁矿俗称为"清镇式铁矿",与黔中铝土矿共同赋存于下石炭统九架炉组之中。本文在实际勘探工作及通过勘探阶段在钻孔副样中采集的铁矿进行可选性试验基础上,以同类型的清镇市猫场铝土矿红花寨、白浪坝矿段铝土矿共生的铁矿为研究对象,指出该类型铁矿矿石自然类型为赤铁矿和褐铁矿;工业类型为需选铁矿石;矿石矿物主要为赤铁矿,部分赤铁矿水化为针柱状褐铁矿;脉石矿物则以白云石和方解石为主。矿石中可供利用的主要元素是铁,造渣组分主要是硅、铝,其次为钙、镁等。试验结果表明,该矿采用一粗一精一扫的强磁选试验可获得铁精矿TFe含量55. 58%,回收率80. 11%的良好指标,精矿中各元素含量达到H55-Ⅰ类赤铁精矿质量要求,在当前市场条件下采用推荐工艺处理该矿可获利。结论对黔中铝土矿资源的综合勘查开发具有借鉴意义。     

航磁梯度数据解释新方法在迁安铁矿勘探中的应用

为更加清晰和准确地利用磁梯度数据获得地质体的分布特征,笔者采用解析信号总水平导数法和梯度欧拉反褶积技术组合实现磁梯度数据的解释,解析信号总水平导数的极值可有效地圈定出矿体的分布范围,梯度欧拉反褶积法可有效地避免背景异常的干扰,从而准确地给出磁性体的位置和深度信息。理论模型证明解析信号水平导数法和梯度欧拉反褶积法的组合可准确地获得磁性体的水平范围和深度。应用于河北迁安地区磁梯度数据的解释,圈定出5个呈条带状分布的较大型铁矿藏,埋深在200~450 m。     

Simulation of groundwater level recovery in abandoned mines,Fengfeng coalfield,China

Abandoned mines are of high potential risk as they could be a large underground storage of pollutants(heavy metals and organic wastes, etc.). Various physical, chemical and biological reactions would take place when groundwater flows into underground spaces, which makes abandoned mine a huge potential hazard to groundwater environment. The recovery of groundwater level is one of the key elements controlling the reactions and causing such hazards. This paper simulated groundwater level recovery processes in the abandoned mines, Fengfeng coalfield by using the computer program FEFLOW. The paper integrated the pipe flow model, "three zones" model and groundwater inrush(discharge) model in the simulation of groundwater in the complex laneway-aquifer system. Groundwater flow in the laneway systems was considered pipe flow and described in Bernoulli equation. The water-bearing medium(coal seam roof) overlying the laneway systems was divided into "three zones" composed of the caving zone, fissure zone and bending zone based on the disruption degrees of previous mining. Groundwater in the Ordovician limestone aquifer(bottom of coal seam) flowing into laneway systems was considered a major inrush/recharge source, and its flow rate was calculated by an inrush(discharge) model which was newly developed in this study and incorporated into FEFLOW. The results showed that it would take approximately 95 days for groundwater in abandoned mines to recover to regional groundwater level elevation, and the total amount of water filling up would be about 1.41195×10~7 m~3, which is consistent with the actual data. The study could be of theoretical and practical significance to mitigate abandoned mines' hazards and improve mine groundwater utilization.