搅拌球磨机在重钙粉超细粉碎中的应用

周期式搅拌球磨机是一种新型高效超细粉碎设备。本文研究了球磨机制备超细重钙粉过程中球料比、矿浆浓度、介质种类以及磨矿时间对制粉效果的影响。提出了适宜的工艺参数。结果表明,用球磨机可拷贝蜊粒径小于１ｕｍ的超细重钙粉,且产品粒度分布窄,磨矿效率高,工艺简单。     

On the relationship between flood and contributing area

Although it is well known that the vast majority of the time only a portion of any watershed contributes run‐off to the outlet, this extent is rarely documented. Also, the power law form of the streamflow and contributing area (Q‐A_c) relationship has been known for a half century, but it is uncommon for it to be quantified, and time series of contributing area extensive enough to calculate its frequency distribution are almost non‐existent. Data from the Canadian Prairies, where there are extensive estimates of contributing area during the median annual flood, imply that the power law coefficient for any Q‐A_c curve is a function of flow magnitude and return period. These data also suggest that regional flood frequency curves are a construct of Q‐A_c curves from individual basins. This paper will discuss research that attempted to reproduce the Q‐A_c curves for the La Salle River Watershed with a semidistributed numerical hydrological model, MESH‐PDMROF. The model simulated streamflow reasonably well (Nash Sutcliffe values = 0.62) compared with published examples of comparable models applied in the region. Estimates of the coefficient and exponent of the Q‐A_c power law function ranged from 0.08–0.14 and 0.9–1.12, respectively. These exponent values were lower than those of regional flood frequency curves and support the theory that regional flood frequency curves are a construct of Q‐A_c curves. Simulations of the area contributing to the median annual flood were lower (0.3) than those derived from independent topographic analysis (0.9) described in earlier literature though there is uncertainty in both these estimates. This uncertainty was extended across the flood frequency distribution and may be too large to definitively verify the study hypothesis.     

Run‐off processes from mountains to foothills: The role of soil stratigraphy and structure in influencing run‐off characteristics across high to low relief landscapes

The critical zone features that control run‐off generation, specifically at the regional watershed scale, are not well understood. Here, we addressed this knowledge gap by quantitatively and conceptually linking regional watershed‐scale run‐off regimes with critical zone structure and climate gradients across two physiographic provinces in the Southeastern United States. We characterized long‐term (~20 years) discharge and precipitation regimes for 73 watersheds with United States Geological Survey in‐stream gaging stations across the Appalachian Mountain and Piedmont physiographic provinces of North Carolina. Watersheds included in this analysis had <10% developed land and ranged in size from 14.1–4,390 km². Thirty‐four watersheds were located in the Piedmont physiographic province, which is typically classified as a low relief landscape with deep, highly weathered soils and regolith. Thirty‐nine watersheds were located in the Appalachian Mountain physiographic province, which is typically classified as a steeper landscape with highly weathered, but shallower soils and regolith. From the United States Geological Survey daily mean run‐off time series, we calculated annual and seasonal baseflow indices (BFI), minimum, mean, and maximum daily run‐off, and Pearson's correlation coefficients between precipitation and baseflow. Our results showed that Appalachian Mountain watersheds systematically had higher minimum daily flows and BFI values. Piedmont watersheds displayed much larger deviations from mean annual BFI in response to year‐to‐year variability in precipitation. A series of linear regression models between 21 landscape metrics and annual BFIs showed non‐linear and complex terrestrial–hydrological relationships across the two provinces. From these results, we discuss how distinct features of critical zone architecture, with specific focus on soil depth and stratigraphy, may be dominating the regulation of hydrological processes and run‐off regimes across these provinces.     

Historical variations in the stable isotope composition of mercury in a sediment core from a riverine lake: Effects of dams,pulp and paper mill wastes,and mercury from a chlor-alkali plant

The Wabigoon River (Ontario, Canada) was affected by dams starting in 1898 and was polluted with pulp and paper mill wastes starting in 1913 and mercury from a chlor-alkali plant from 1962 to 1975. A dated sediment core from a riverine lake was analysed to investigate resultant changes in the biogeochemistry of mercury as revealed by variations in mercury isotope ratios and sediment chemistry. A total mercury maximum formed by the mercury pollution coincided with minimums in the δ-values of the ¹⁹⁸Hg/²⁰²Hg, ¹⁹⁹Hg/²⁰²Hg, ²⁰⁰Hg/²⁰²Hg, and ²⁰¹Hg/²⁰²Hg ratios, and the δ-values decreased in the order δ²⁰¹Hg > δ²⁰⁰Hg > δ¹⁹⁹Hg > δ¹⁹⁸Hg. Thus, mass-dependent fractionation caused depletion in lighter isotopes, implying evaporation of Hg(0) and pollution of the atmosphere as well as the river-lake system. Concurrently, mass-independent fractionation caused ¹⁹⁹Hg enrichment, possibly reflecting an independently documented upsurge in methylmercury production, and ²⁰¹Hg depletion, suggesting removal of methylmercury with anomalously high ²⁰¹Hg/¹⁹⁹Hg ratios by aquatic organisms and accumulation of ²⁰¹Hg-depleted inorganic Hg(II) in sediments. The δ²⁰¹Hg/δ¹⁹⁹Hg ratio rose abruptly when mercury pollution began, reflecting the resultant increase in methylmercury production, and remained high but gradually declined as the pollution abated, paralleling trends shown by methylmercury in aquatic organisms. The δ²⁰¹Hg/δ¹⁹⁹Hg ratio of pre-1962 background mercury increased ca. 1898 and ca. 1913–1929, suggesting accelerated methylmercury production due to stimulation of microbial activities by the damming of the river and the input of pulp and paper mill wastes, respectively. Other variations were linked to economic and technological factors that affected pulp and paper manufacture.     

Application of Maximum Entropy Distribution to the Statistical Properties of Wave Groups

The new distributions of the statistics of wave groups based on the maximum entropy principle are presented.The maximum entropy distributions appear to be superior to conventional distributions when applied to a limited amount of information.Its applications to the wave group properties show the effectiveness of the maximum entropy distribution.FFT filtering method is employed to obtain the wave envelope fast and efficiently.Comparisons of both the maximum entropy distribution and the distribution of Longuet-Higgins(1984) with the laboratory wind-wave data show that the former gives a better fit     

锯缘青蟹(Scylla serrata)幼体胃磨发育的比较研究

在青蟹幼体发育过程中，胃磨呈现出明显的变化。Ｚ１缺乏胃磨的结构，ＺⅡ开始出现中齿和侧齿的雏形，明显的可以识别的中齿和侧齿出现在ＺⅢ，．从ＺＶ开始胃磨已臻完善，除具有中齿和侧齿外，还出现了４个附属齿，包括两个附属的中齿和两个附属的侧齿。大眼幼体期，中齿和侧齿比ＺＶ更加尖锐，附属齿也更加锋利。在仔蟹前，中齿齿尖发生特化，形成垫状角质化区域，侧齿、附属齿更加锋利。这表明青蟹幼体发育过程中胃磨结构的变化与     

Separating climate change and human contributions to variations in streamflow and its components using eight time‐trend methods

Separating impacts of human activities and climate change on hydrology is essential for watershed and ecosystem management. Many previous studies have focused on the impacts on total streamflow, however, with little attentions paid to its components (i.e., baseflow and surface run‐off). This study distinguished the contributions of climate change and human activities to the variations in streamflow, baseflow, and surface run‐off in the upstream area of the Heihe River Basin, a typical inland river basin in northwest China, by using eight different forms of time‐trend methods. The isolated contributions to streamflow variation were also compared with those obtained by two Budyko‐based approaches. Our results showed that the time‐trend methods consistently estimated positive contributions of climate variability and human activities to the increases in streamflow and its components but with obviously varying magnitudes. With regard to streamflow, the time‐trend method double‐mass‐curve–Wei, with a physical basis, produced a reasonable smaller contribution of human activities than climate changes, inconsistent with the Budyko‐based approaches. However, all the other time‐trend methods led to contrary results. The contributions to baseflow variation diverged more significantly than those to streamflow and surface run‐off, ranging from 24% to 92% for human activities and from 8% to 76% for climate variability. In terms of surface run‐off, most of the time‐trend approaches produced smaller contributions of human activities (ranging from 21% to 49%) than climate change. The uncertainties associated with the various time‐trend approaches and the baseflow separation algorithm were revealed and discussed, along with some recommendations for future work.     

Climate moderates potential shifts in streamflow from changes in pinyon‐juniper woodland cover across the western U.S.

Pinyon‐juniper (PJ) cover has increased up to 10‐fold in many parts of the western U.S. in the last 140+ years. The impacts of these changes on streamflows are unclear and may vary depending on the intra‐annual distribution and amount of precipitation. Given the importance of streamflow in the western U.S., it is important to understand how shifts in PJ woodland cover may produce changes in streamflow across the region's diverse hydroclimates. To this end, we simulated the land surface water balance with contrasting woodland and grassland cover with the Hydrologiska Byråns Vattenbalansavdelning (HBV) model at a 4‐km resolution across the distribution of PJ woodlands in the western U.S. We used shifts in evapotranspiration (ET) between woodland and grassland cover as a proxy for potential changes in streamflows. Comparison of HBV model results with paired catchment studies indicated the model reasonably simulated annual decreases in ET with changes from woodland to grassland cover. For the northern and western ecoregions of the PJ distribution in the western U.S. where precipitation predominantly occurs in the winter, HBV simulated a 25 mm (37%) annual decrease in ET with conversion to grassland from woodland. Conversely, in southern ecoregions of PJ distribution with prominent summer monsoons, annual differences in ET were only 6 mm (19%). Our results suggest that only 29% of the PJ distribution, compared to an estimated 45% based on precipitation amount alone, has the potential for meaningful increases in streamflow with land cover change from woodland to grassland.     

A finite element model for simulating surface run‐off and unsaturated seepage flow in the shallow subsurface

This work introduces water–air two‐phase flow into integrated surface–subsurface flow by simulating rainfall infiltration and run‐off production on a soil slope with the finite element method. The numerical model is formulated by partial differential equations for hydrostatic shallow flow and water–air two‐phase flow in the shallow subsurface. Finite element computing formats and solution strategies are presented to obtain a numerical solution for the coupled model. An unsaturated seepage flow process is first simulated by water–air two‐phase flow under the atmospheric pressure boundary condition to obtain the rainfall infiltration rate. Then, the rainfall infiltration rate is used as an input parameter to solve the surface run‐off equations and determine the value of the surface run‐off depth. In the next iteration, the pressure boundary condition of unsaturated seepage flow is adjusted by the surface run‐off depth. The coupling process is achieved by updating the rainfall infiltration rate and surface run‐off depth sequentially until the convergence criteria are reached in a time step. A well‐conducted surface run‐off experiment and traditional surface–subsurface model are used to validate the new model. Comparisons with the traditional surface–subsurface model show that the initiation time of surface run‐off calculated by the proposed model is earlier and that the water depth is larger, thus providing values that are closer to the experimental results.     

Run‐off formation in a humid,temperate headwater catchment using a combined hydrological,hydrochemical and isotopic approach (Jizera Mountains,Czech Republic)

The formation of baseflow and stormflow was examined in the 1.18 km² part of the headwater catchment Uhlí?ská, Jizera Mountains, Czech Republic, over the period 2007–2011, by means of run‐off data and environmental tracers ¹⁸O and SiO₂. The baseflow, computed using the digital filter approach BFLOW, contributes 67% to total streamflow and has a mean residence time of 12.3 months. It is formed by groundwater discharge from the valley deluviofluvial granitic sediments, in combination with soil water in weathered layers on hillslopes during rainfall and snowmelt periods. The prevailing source of the groundwater is the infiltration of snowmelt water. Analysis of 20 run‐off events and their hysteretic patterns demonstrated that the stormflow water has a residence time of about 4 months and is generated by preferential flow on hillslopes combined by soil matrix drainage. Because of slower flow in the soil matrix, the enrichment of pore water in SiO₂ is more pronounced. The stormflow and snowmelt water flowing via preferential pathways of upslope minerals soils pushes the pre‐event groundwater through the pathways in wetlands to the stream, and the wetland can be therefore considered as groundwater supplied. This mechanism has been found to be typical for the groundwater‐supplied headwater catchments of the Jizera Mountains and can be also assumed in other mountainous headwaters of the granitic massif in Central Europe. The main methodological contribution of this study are the residence time calculations stratified by baseflow and event flow, identifying run‐off components of different travel times to streams and linking them with geochemical run‐off sources. This achievement was possible because of a comprehensive dataset on hydrology, stable isotopes and silica hydrochemistry in all relevant run‐off generation components. This concept indicates that a possible long‐term change in snowmelt may affect the run‐off regime of headwater catchments to climate or land‐use changes. Copyright © 2013 John Wiley & Sons, Ltd.