Metamorphic processes: a celebration of the career contribution of Ron Vernon

This Special Issue is in celebration of the career contribution of Ron Vernon. It arises from the ‘Ron Vernon Symposium’, which was held as part of the 15th Australian Geological Convention in Sydney in 2000. To date Ron has published more than one hundred scientific papers, several books and contributed widely to international conferences. He is the doyen in the multidisciplinary field of microstructures, which spans petrology and structural geology. However, Ron's range is phenomenal, and he has contributed to many aspects of metamorphism, magmatism and rock deformation. He has drawn on data from his work in these areas to contribute widely to understanding thermal regimes, crustal evolution and tectonics, as exemplified by his ideas about HTLP metamorphism and emplacement of granites. Ron has followed the scientific method in his work; it has led him to many innovative interpretations, some of which undermined established dogma. By example, Ron has been a positive role model for the younger generation. However, for the older generation, he has been something of a bête noire! The papers in this Special Issue cover the range from low‐ to high‐grade metamorphism, from metasomatism to melting, from microstructures to tectonics, and from fieldwork to experiments. It is our hope that in reading them you will take time to think about what has been achieved in the past 40 years, and use this as motivation for what remains to be done.     

Microstructures of melt inclusions in anatectic metasedimentary rocks

The occurrence of crystallized and glassy melt inclusions (MI) in high‐grade, partially melted metapelites and metagraywackes has opened up new possibilities to investigate anatectic processes. The present study focuses on three case studies: khondalites from the Kerala Khondalite Belt (India), the Ronda migmatites (Spain), and the Barun Gneiss (Nepal Himalaya). The results of a detailed microstructural investigation are reported, along with some new microchemical data on the bulk composition of MI. These inclusions were trapped within peritectic garnet and ilmenite during crystal growth and are therefore primary inclusions. They are generally isometric and very small in size, mostly ≤15 μm, and only rarely reaching 30 μm; they occur in clusters. In most cases inclusions are crystallized (‘nanogranites’) and contain a granitic phase assemblage with quartz, feldspar and one or two mica depending on the particular case study, commonly with accessory phases (mainly zircon, apatite, rutile). In many cases the polycrystalline aggregates that make up the nanogranites show igneous microstructures, e.g. granophyric intergrowths, micrographic quartz in K‐feldspar and cuneiform rods of quartz in plagioclase. Further evidence for the former presence of melt within the investigated inclusions consists of melt pseudomorphs, similar to those recognized at larger scale in the host migmatites. Moreover, partially crystallized inclusions are locally abundant and together with very small (≤8 μm) glassy inclusions may occur in the same clusters. Both crystallized and partially crystallized inclusions often display a diffuse nanoporosity, which may contain fluids, depending on the case study. After entrapment, inclusions underwent limited microstructural modifications, such as shape maturation, local necking down processes, and decrepitation (mainly in the Barun Gneiss), which did not influence their bulk composition. Re‐homogenized nanogranites and glassy inclusions show a leucogranitic and peraluminous composition, consistent with the results of partial melting experiments on metapelites and metagraywackes. Anatectic MI should therefore be considered as a new and important opportunity to understand the partial melting processes.     

Quartz microstructures and deformation conditions in the Hatagawa shear zone, north-eastern Japan

Abstract Meso- and microscale structural analyses were carried out in the Hatagawa shear zone, north-eastern Japan. The shear zone is a sinistral strike–slip ductile shear zone, and has a 1-km wide north-south trending region where quartz mean grain size of approximately 35 μm does not vary significantly. Two types of quartz microstructures, A and B, occur in the western and eastern part of the shear zone, respectively. The lattice preferred orientation (LPO) patterns are characterized by a type I crossed girdle in the samples with the quartz microstructure A, and a Y maximum in the samples with the quartz microstructure B. The microstructures under optical and transmission electron microscopes indicates that the quartz recrystallization occurred predominantly by progressive subgrain rotation in microstructure A, and by both progressive subgrain rotation and grain boundary migration in microstructure B. This suggests different deformation conditions in the western and eastern parts of the shear zone. Quartz LPO patterns, presence of myrmekite, feldspar compositions, and dislocation density also suggest difference in the deformation conditions. The syn-deformation temperature in the western part of the shear zone was lower than that of the eastern part of the shear zone. The stress in the western part of the shear zone was higher than that of the eastern part of the shear zone. The difference in the deformation conditions would affect not only the quartz microstructure, but also the quartz LPO patterns and the presence of myrmekite around K-feldspar porphyroclasts.     

孤岛油田中二中区开发中后期微型构造研究

从油田开发实际出发，系统总结了影响微型构造精度的主要因素、微型构造研究的方法及合理工作程序。以河流动力学理论等为依据，以孤岛油田中二中区380口井的测井测井资料及取心资料为基础，总结了研究区馆陶组上段3-5砂层组各小层的微型构造类型及特征，认为微型构造主要与河道侵蚀下切、古地形、差异压实作用等非构造作用因素有关。探讨了微型构造对油井生产及剩余油分布的影响或控制作用。     

云南墨江含金脆—韧剪切构造带中显微构造的矿物地球化学研究

墨江－元江镍金矿床是哀牢山构造－成矿带上一个十分典型和重要的矿床，在野外实测构造岩石地层层序、矿物学详细填图的基础上，采用X射线粉晶衍射分析、扫描电镜、电子探针微区分析及矿物－构造－地球化学等方法，对墨江镍金矿床中含金脆－韧性剪切构造带的物质组成进行详细研究。显微构造的矿物地球化学研究是一种构造筛分新方法。脆性构造主要表现为含镍金石英脉－硅质岩－黄铁矿硅质岩中普遍发育碎裂岩化及裂隙，碎裂岩化－裂隙构造是深源热流体叠加成矿的储矿构造和运移上升通道，脆性剪切变形过程中伴有粘土化蚀变，粘土矿物主要有铬水云母、铬高岭石、多水铬高岭石、绿铬高岭石、铬蒙脱石、铬迪开石、铬埃洛石和绿鳞石等。在含金脆－韧剪切构造带中，铬绢云母－铬水云母－铬伊利石系列和铬绿泥石的矿物具（脆）韧剪切变形特征，在韧剪切变形过程中伴有强烈的热流体以及H2O为主要组分的矿化剂作用。     

Assessing the extent of disequilibrium and overstepping of prograde metamorphic reactions in metapelites from the Bushveld Complex aureole, South Africa

Andalusite–staurolite–biotite hornfels metamorphosed beneath the mafic layered rocks of the Bushveld Complex, South Africa, preserves a detailed record of the relative timing of porphyroblast growth and metamorphic reactions. The sequence inferred from microstructures shows considerable overlap of the period of growth of porphyroblasts of staurolite, cordierite, biotite and andalusite, and the persistence over a similar interval of the reactant porphyroblastic phase chloritoid. This is inconsistent with calculations of equilibrium phase relations, and implies that disequilibrium processes controlled the prograde reaction sequence, despite the slow heating rates involved (1 °C per 10 000 yr). The early appearance of cordierite by a metastable reaction and its subsequent disappearance indicates that delayed nucleation of porphyroblastic phases, rather than simply sluggish reaction, is required to account for the sequence of growth. The predicted reactions for the first appearance of andalusite and staurolite have low entropy of reaction, and do not occur until they have been overtaken in terms of reaction affinity by high‐entropy devolatilisation reactions involving the breakdown of chlorite. Once the porphyroblasts have nucleated, metastable chloritoid‐breakdown reactions also contribute to their growth. The implied magnitude of the critical overstepping for andalusite nucleation is around 5 kJ mole^?1 (equivalent to 40 °C for the chlorite‐breakdown reaction), and that for other phases is expected to decrease in the order andalusite>staurolite>cordierite. Coupling between nucleation rate, crystal growth rates and the resulting grain size distribution suggests that the rate constants of natural reactions are at least an order of magnitude lower than those measured in the laboratory. Pseudomorphs after chloritoid and cordierite conserve volume but not Al or other species of low mobility, suggesting a breakdown mechanism controlled by an interface process such as the slow dissolution of the refractory porphyroblast phase, rather than by a transport step.     

Two-stage exhumation of subducted Saxothuringian continental crust records underplating in the subduction channel and collisional forced folding (Krkonoše-Jizera Mts., Bohemian Massif)

The Krkonoše-Jizera Massif in the northern part of the Variscan Bohemian Massif provides insight into the exhumation mechanisms for subducted continental crust. The studied region exposes a relatively large portion of a flat-lying subduction-related complex that extends approximately 50 km away from the paleosuture. wide extent of HP-LT metamorphism has been confirmed by new P-T estimates indicating temperatures of 400–450 °C at 14–16 kbar and 450–520 °C at 14–18 kbar for the easternmost and westernmost parts of the studied area, respectively. A detailed study of metamorphic assemblages associated with individual deformation fabrics together with analysis of quartz deformation microstructures and textures allowed characterisation of the observed deformation structures in terms of their subduction-exhumation memory. An integration of the lithostratigraphic, metamorphic and structural data documents a subduction of distal and proximal parts of the Saxothuringian passive margin to high-pressure conditions and their subsequent exhumation during two distinct stages. The initial stage of exhumation has an adiabatic character interpreted as the buoyancy driven return of continental material from the subduction channel resulting in underplating and progressive nappe stacking at the base of the Teplá-Barrandian upper plate. With the transition from continental subduction to continental collision during later stages of the convergence, the underplated high-pressure rocks were further exhumed due to shortening in the accretionary wedge. This shortening is associated with the formation of large-scale recumbent forced folds extending across the entire studied area.     

Incipient metamorphism and deformation in the Variscides of SW Dyfed, Wales: first steps towards isotopic equilibrium

Incipient metamorphism accompanying thrusting, folding and cleavage development has been investigated in a varied sequence of Palaeozoic sediments near the Variscan front in SW Dyfed, Wales. The aim was to evaluate a critical stage in the progression from heterogeneous sediment, whose detrital phases are neither in equilibrium with one another, nor with pore fluids, through indurated sedimentary rock to metamorphic rock comprising newly formed crystals that equilibrated with one another as they grew. Quartz veins are widely developed in the area, especially in the more psammitic lithologies, while finer grained rocks became cleaved during tectonic deformation. Mineralogical constraints and fluid inclusion measurements suggest maximum temperatures around 200-310d? C (slightly higher in the Marloes-Musselwick Thrust Sheet than in other parts of the structural succession) at depths of the order of 6-13 km. Quartz veins yield distinctly heavier oxygen isotopic compositions than detrital quartz grains in the adjacent wall rocks, although care must be taken in interpreting the data because slivers of detrital grains may become incorporated into veins, while matrix detrital grains may incorporate veinlets or rims of newly formed quartz. It is concluded that vein quartz grew in isotopic equilibrium with a fluid phase whose isotopic composition was primarily controlled by exchange with phyllosilicates, not detrital quartz grains. Vein and matrix quartzes from the Marloes-Musselwick Thrust Sheet are distinctly lighter (δ¹⁸O_veins=+14 to +18% and δ¹⁸O_matrix=+11 to +14%) than those from other thrust sheets (δ¹⁸O =+17 to +20% and +14 to +17%, respectively). We conclude that vein quartz and phyllosilicate grains in cleavage domains probably attained equilibrium with a locally buffered pore fluid at the peak of metamorphism, but many relict grains of different chemical and isotopic composition remained elsewhere in the rock. Local fluid migration along veins and through cleavage lamellae facilitated the attainment of equilibrium, but there is little evidence for large-scale infiltration of externally derived fluids. With further metamorphism the quartz in these rocks would attain an isotopic composition intermediate between that of the heavy vein material and light detritus which coexist here.