丁二酸桥联双核铜Cu(C_3N_2H_4)_2(C_4H_5O_4)_2晶体的超分子结构及形貌特征

用XRD,SEM和TEM研究新型配合物Cu(C3N2H4)2(C4H5O4)2的超分子结构和微观形貌,并对新型晶体的平衡外形进行模拟计算,结果表明:该配合物分子具有丁二酸桥联的双核铜结构,中心铜离子处在2个咪唑和4个丁二酸以单齿配位组成的八面体中心,在ab平面,分子中有十四元大环,环内Cu(1)-Cu(2)原子间距为0.8031nm,C(2)-C(2′)为0.4183nm;在ac平面,沿着[010]方向分子内呈现凹的六边形纳米级孔洞;沿[100]方向分子依靠弱的氢键作用,层状堆积成三维超分子结构。此外,随着丁二酸的碳链沿[001]方向无限延伸,形成以铜离子为交叉中心的带状拓扑构型。SEM观察到晶体表面形成有明显的凹坑,区域呈现层状阶梯,说明晶体在(100)面遵照台阶-扭折模型呈层状生长结晶。TEM微区形貌像显示晶体存在条纹和缺陷结构,整体保持柱状构型,这与模拟的晶体平衡外形呈柱状一致。模拟结果表明晶体最易外显晶面为(100)面,外显比例达41.247%,这与晶体超分子层沿[100]方向通过氢键作用堆积,键作用力较弱密切相关。     

甘肃河西走廊早期冶炼活动及影响的炭屑化石记录

炭屑化石的显微结构研究是根据木材的解剖特征（组成木材的细胞与组织的形态和排列方式）确定燃烧植物的类型,重建古植被和古环境,探讨人类活动对环境的影响。火石梁和缸缸洼青铜冶炼点位于河西走廊西北部、黑河流域下游巴丹吉林南缘沙地中,散布了大量的炭屑化石遗存。通过炭屑化石3个切面（横切面、径切面和弦切面）显微结构特征研究,比对现代切片标本和木材解剖图版,识别和确定炭屑化石的木材种属,确定 2100～1860BC期间的青铜冶炼所用木材为柽柳、杨属、柳属、蓼科4种乔灌木植物,火石梁和缸缸洼地区大量乔、灌群落生长要比目前荒漠生态环境优越的多。先民的青铜冶炼活动导致乔木和灌木植物被大量砍伐,植被盖度急剧降低,对生态环境产生重大影响,是1900BC左右杨属、柳属和蓼科乔灌木植物基本消失的主要原因。     

Test and evaluation of a moored microstructure recorder

A new moored microstructure recorder （MMR） is designed, developed, tested, and evaluated. The MMR directly measures the high-frequency shear of velocity fluctuations, with which we can estimate the dissipation rate of turbulent kinetic energy. We summarize and discuss methods for estimating the turbulent kinetic energy dissipation rate. Instrument body vibrations contaminate the shear signal in an ocean field experiment, and a compensating correction successfully removes this contamination. In both tank test and ocean field experiment, the dissipation rate measured with the MMR agreed well with that measured using other instruments.     

Staurolite porphyroblast controls on local bulk compositional and microstructural changes during decompression of a St–Bt–Grt–Crd–And schist (Ancasti metamorphic complex,Sierras Pampeanas,W Argentina)

The staurolite–biotite–garnet–cordierite–andalusite–plagioclase–muscovite–quartz metapelitic mineral assemblage has been frequently interpreted in the literature as a result of superimposition of various metamorphic events, for example, in polymetamorphic sequences. The assemblage was identified in schists from the Ancasti metamorphic complex (Sierras Pampeanas of Argentina) where previous authors have favoured the polymetamorphic genetic interpretation. A pseudosection in the MnNCKFMASH system for the analysed XRF bulk composition predicts the stability of the sub‐assemblage staurolite–biotite–garnet–plagioclase–muscovite–quartz, and the compositional isopleths also agree with measured mineral compositions. Nevertheless, the XRF pseudosection does not predict any field with staurolite, andalusite and cordierite being stable together. As a result of more detailed modelling making use of the effective bulk composition concept, our interpretation is that the staurolite–biotite–garnet–plagioclase–muscovite–quartz sub‐assemblage was present at peak metamorphic conditions, 590 °C and 5.2 kbar, but that andalusite and cordierite grew later along a continuous P–T path. These minerals are not in mutual contact and are observed in separate microstructural domains with different proportions of staurolite. These domains are explained as a result of local reaction equilibrium subsystems developed during decompression and influenced by the previous peak crystal size and local modal distribution of staurolite porphyroblasts that have remained metastable. Thus, andalusite and cordierite grew synchronously, although in separate microdomains, and represent the decompression stage at 565 °C and 3.5 kbar.     

远安地堑上白垩统红花套组压实剪切型变形带的微观结构与地层渗透性关系解析

孔隙性砂岩中形成的压实剪切型变形带及其周围的渗透性特征是变形带研究的重要内容之一,由于变形带宽度常为毫米级别,常规渗透率测试方法因分辨率的限制无法满足研究需求。选取远安地堑上白垩统红花套组中不同规模的单条变形带、小型及中大型簇状变形带样品,在对其微观结构进行详细研究的基础上,采用具有高分辨率测试功能的AUTOSCAN进行密集测试,建立了连续渗透率剖面。结果显示,渗透率低值点与变形带有显著对应关系,在渗透率线扫描曲线中呈下拉尖峰特征;不同变形带渗透率异常低值点存在差异,变形带厚度大则异常程度高;不同微观结构要素的渗透率降低程度不同,渗透率由低至高依次为：大型簇状变形带的核心碎裂带<小型簇状变形带的核心碎裂带<带间区域<单条变形带核心碎裂带<边缘过渡区<围岩。分析认为,虽然变形带的厚度和渗透率探测孔的大小会影响探测结果,但变形带的微观结构才是控制渗透率降低程度不同的本质原因。中大型簇状变形带的核心碎裂带密集发育且连续性好,很可能对流体渗流、油气运移等造成较大影响;而单条变形带由于延续性较差,很难真正阻碍流体渗流,而是会增强岩石整体的各向异性特征。     

Microstructure,metamorphism, thermochronology and P-T-t-deformation history of the Port aux Basques gneisses,south-west Newfoundland,Canada*

Abstract The Port aux Basques gneisses comprise three lithostratigraphic units separated by major fault zones: the Grand Bay Complex; the Port aux Basques Complex; and the Harbor le Cou Group. A similar regionally developed polyphase history of penetrative deformation characterizes each of these units. Thickening during D1 produced rare recumbent folds (F1) and an axial planar schistosity (S1), overprinted by D2 recumbent folds (F2), and transposed during development of a locally penetrative, differentiated crenulation cleavage (S2). In western sectors of the area, D2 was associated with NW-directed reverse shearing. The NE-trending structural grain reflects D3 transpression, partitioned into dextral transcurrent movement along major shear zones and development of upright-to-steeply inclined, periclinal folds (F3) and a variably penetrative schistosity (S3). Amphibolite facies metamorphism increases in grade from west to east across the area. Microstructures, including porphyroblast-matrix foliation relations and internal textural unconformities in garnet, indicate episodic porphyroblast nucleation and growth, which reflect a prograde traverse sequentially across univariant reactions during syntectonic metamorphism. Garnet, kyanite and staurolite porphyroblasts are wrapped by the S2 foliation, but each may contain trails of inclusions that define S1; commonly these trails preserve early stages of S2 crenulation cleavage development. Progressive and sequential reaction out of kyanite, staurolite and muscovite in favour of sillimanite, garnet, biotite and K-feldspar, and the development of an increasing volume of anatectic migmatite in south-eastern sectors of the area record syn- to late-D2 peak metamorphic conditions. Microstructural relationships and petrogenetic grid considerations indicate clockwise trajectories in P-T space for units of the Port aux Basques gneisses. Peak metamorphic conditions are estimated to have been 620–650° C at ≤8kbar in the west and 700–750° C at ≤8 kbar in the east. Titanite from an upper amphibolite facies calc-silicate gneiss yields U-Pb ages of c. 420 Ma, interpreted to date cooling shortly after the thermal peak in these gneisses. Variable D3 strain was associated with some recrystallization of hornblende and micas. ⁴⁰Ar/³⁹Ar hornblende plateau isotope correlation ages range from c. 419 to c. 393 Ma, from east to west across the area, and are interpreted to record cooling through c. 500° C coeval with or soon after D3 deformation. The range in ages may record the effects of heterogeneous D3 deformation and differential uplift from south-east to north-west associated with displacement on major shear zones. ⁴⁰Ar/³⁹Ar muscovite plateau ages cluster at c. 390 Ma, and date cooling through c. 375° C during regional exhumation. Cooling rates are moderate to fast and may indicate a component of tectonic exhumation. The Port aux Basques gneisses are a product of Silurian collisional tectonics. The higher grade of metamorphism in comparison with adjacent areas of the Canadian Appalachians is interpreted to reflect greater thickening due to juxtaposition of the St Lawrence promontory (Laurentian margin) with the Cabot promontory (Avalonian margin) during closure of the Iapetus Ocean.     

哀牢山-红河剪切带左行走滑作用起始时间约束

位于哀牢山-红河剪切带NW延伸方向上的点苍山变质杂岩体遭受强烈的左行走滑剪切变形、变质作用改造,岩石中保存了典型的高温矿物组合以及由它们构成的宏观和微观高温变形构造特征,其中糜棱岩中具有极其发育的长石矿物拉伸线理而形成典型的L与LS型构造岩是其一个明显的特征。本文对点苍山地区高温糜棱岩主要矿物开展了显微构造与矿物变形、变形机制及组构分析,并对于遭受高温糜棱岩化改造的一个花岗质岩体开展了SHRIMP锆石U-Pb定年分析。结果表明岩石中长石、角闪石、石英等主要矿物具有典型的达角闪岩相条件下的高温晶质塑性变形和动态生长特征,它们也为走滑剪切变形活动提供了充分的微观构造证据。对于点苍山高温糜棱岩化改造的眼球状或似斑状二长花岗岩的显微构造分析结果表明,这套花岗质岩石从走滑剪切前期岩浆的侵位之后经历了早期强烈的岩浆期后交代作用—亚岩浆流动—高温固态塑性剪切变形的递进演化过程。由此可见,岩浆的上升与就位受左行走滑剪切作用的制约,岩体又遭受了强烈剪切变形改造。同时对这套构造前期就位花岗质岩石中的锆石进行定年分析,获得33.88±0.32Ma的岩浆结晶年龄,为此,我们有充分的理由认为,在点苍山地区哀牢山-红河剪切带左行走滑剪切作用的起始时间至少应该为早渐新世30.88±0.32Ma。     

Deformation microstructures of olivine in peridotite from Spitsbergen, Svalbard and implications for seismic anisotropy

To understand the deformation mechanism and seismic anisotropy in the uppermost mantle beneath Spitsbergen, Svalbard, in the Arctic, the deformation microstructures of olivine in the peridotite of Spitsbergen were studied. Seismic anisotropy in the upper mantle can be explained mainly by the lattice-preferred orientation (LPO) of olivine. The LPOs of the olivine in the peridotites were determined using electron backscattered diffraction patterns. Eight specimens out of 10 showed that the [100] axis of the olivine was aligned subparallel to the lineation and that the (010) plane was subparallel to the foliation, showing a type A LPO. In the other two specimens the [100] axis of olivine was aligned subparallel to the lineation and both the [010] and [001] axes were distributed in a girdle nearly perpendicular to the lineation, showing a type D LPO. The dislocation density of the olivine in the samples showing a type D LPO was higher than that in the samples showing a type A LPO. The result of an Fourier transformation infrared study showed that both the types A and D samples were dry. These observations were in good agreement with a previous experimental study ( Tectonophysics , 421 , 2006, 1 ): samples showing a type D LPO for olivine were observed at a high stress condition and samples showing both types A and D LPO were deformed under dry condition. Observations of both strong LPOs and dislocations of olivine indicate that the peridotites studied were deformed by dislocation creep. The seismic anisotropy calculated from the LPOs of the olivine could be used to explain the seismic anisotropy of P - and S -waves in the lithospheric mantle beneath Spitsbergen, Svalbard.     

NaCl溶液饱和膨胀土的压缩特性及其微观机制

孔隙溶液浓度及组份改变会影响膨胀土颗粒间作用力,改变微观孔隙结构,从而影响土体的物理力学特性。为此,以宁明膨胀土为研究对象,采用不同浓度NaCl溶液制备泥浆预固结重塑样开展一维压缩试验和压汞试验,研究化学作用对重塑天然膨胀土的压缩性和微观孔隙结构的影响规律。结果表明：随着渗透吸力增加,颗粒间水化能力降低,物理化学力使土颗粒由分散状态转变为集聚体状态,形成了集聚体内孔和集聚体间孔,土体表现出双峰孔隙分布特征。预固结样（压力为20 kPa）的初始孔隙比随渗透吸力增加而减小,进而导致固结屈服应力增加;但是渗透吸力对压缩性影响不大,压缩指数和回弹指数基本不变。此外,利用固结系数计算了土体的渗透系数,随着竖向压力增加渗透系数降低;当竖向压力小于200 kPa时,随着渗透吸力增加,渗透系数先增加后减小,但是竖向压力超过200 kPa后,渗透系数变化不大。分析发现,渗透吸力增加导致大孔隙增加,渗透系数增加,但同时密实度增加会导致渗透系数降低,低竖向压力下渗透性受密实度和微观孔隙结构变化耦合作用控制。     

砂土微观结构样品制备技术及量化方法研究

土体的微观结构是决定其工程特性的重要内在因素,但对于砂土而言,如何制备适合微观分析的样品以及快速准确量化结构参数一直面临诸多挑战。为此,提出一种真空冷冻干燥?注胶相结合的砂土样品制备技术,该技术可在有效去除土样水分的同时保持样品原状结构不被扰动,并可用于后续加工处理。针对不同粒度的砂土样品,分别使用扫描电子显微镜和光学显微镜对制备的试样进行观察,基于自主研发的土体微观结构定量分析系统SMAS对拍摄的照片进行精细量化分析,提出了由土颗粒数量、颗粒周长、表观孔隙率、形状系数、等效直径、分形维数和形态比等参数构成的量度指标体系对砂土样品微观结构特征进行定量评价。研究结果表明：提出的真空冷冻干燥?注胶相结合的砂土样品制备技术具有操作简单、稳定可靠等特点,能有效维持砂土的原状结构;比较而言,扫描电镜更适用于粉细砂的微观结构分析,而光学显微镜更适用于中粗砂的微观结构分析;SMAS能有效识别微观结构图像中的土颗粒及孔隙,为定量分析砂土或其他土体的微观结构特征提供了高效的工具。