X射线粉晶衍射-拉曼光谱法研究含甲烷双组分水合物结构及谱学特征

天然气水合物的晶体结构主要取决于客体分子种类与组成,目前单组分水合物的结构和谱学特征较为明确,但多组分水合物相关研究较少.为解决多组分水合物的结构识别问题,探讨其谱学特征,本文实验合成了甲烷-丙烷(CH4-C3 H8)和甲烷-四氢呋喃(CH4-THF)两种含CH4双组分水合物以及CH4、C3 H8和THF等三种单组分水...     

DEM analysis of granular crushing during simple shearing

In this study, simple shear tests on breakable polydisperse granular materials were simulated using two-dimensional discrete element method (DEM). A new technique of generating polydisperse DEM samples with a smooth and continuous particle size distribution curve was proposed. A modified breakage criterion was introduced to reflect the contact force anisotropy of particles in the numerical sample. The simulation results showed that during the simple shearing, grain crushing in the sample mainly occurred in the contraction process and decreased gradually when the sample began to dilate. As the shearing proceeded to a larger strain, the grain crushing tended to a stable value. This grain crushing trend was in accordance with the evolution of the average normal contact forces of particles in the sample during shearing. The average normal contact forces of potential breakage particles increased in the contraction process and decreased in the dilatancy process. A decrease in the average normal contact forces of potential breakage particles resulted in the decrease in grain crushing during the later stage of shearing.     

准噶尔盆地阜康凹陷北部三工河组储层非均质性综合研究

阜康凹陷为准噶尔盆地的富烃凹陷之一,其北部斜坡带为有利油气聚集区,上侏罗统三工河组发育辫状河三角洲,因其储集砂体面积大、厚度大受到较大关注。由于油气仍有较大挖掘潜力,同时油井水驱效果逐渐变差等问题逐渐显现,需要对研究区三工河组储层非均质性进行综合研究。利用岩心、录井、测井和地震资料,通过层内、层间和平面非均质性的详细研究,发现三工河组储集层的宏观非均质性很强,三工河组二段最强。利用压汞、核磁共振、恒速压汞、粒度、薄片分析和扫描电镜等资料,通过对三工河组储集层的孔喉、颗粒以及填隙物非均质性进行详细研究,发现三工河组储集层的微观非均质性很强。储集层非均质性受控于沉积背景、成岩作用和异常压力,综合认为三二段相较于三一段更有利于成藏。     

应用荧光显微技术判别吐哈盆地储层含油水性

通过在荧光镜下的油水特征实验，分别得出油、油包水、水包油、含油水、水的荧光特征，然后对吐哈盆地单井储层的油层、水层荧光特征反复实验，并与试油结果对比，归纳总结出了油层、水层及油水界面的识别标志。油层特征主要为荧光发光较好且均匀、大面积油包水；水层特征主要为荧光发光不均匀，可动水普遍，并出现水包油现象；油水界面特征主要为荧光从均匀发光过渡到不均匀发光，孔隙由可动油充填过渡到由可动水充填。提出了吐哈盆地储层含油规律性，从而为探井试油、油层划分提供了准确可靠的依据。     

A light and transmission electron microscopic study ofHexamite capsularis sp. nov. (Diplomonadina: Hexamitidae) in fish (Xenocypris dividi)

A diplomonad flagellateHexamita capsularis sp. nov. from the posterior intestine of the fish (Xenocypris dividi) from Liangzi Lake, Hubei Province, is described. The flagellate was oval, with smooth surface and homogenous cytoplasm, 6.21±0.28 μm in length, 3.43±0.48 μm in width and with an elliptical capsule. Two recurrent flagellae arranged between two nuclei ran longitudinally to the posterior end. Fibrillar bands connected the accessory organelles of two cytostomal tubes, the body depressed at the posterior end of the body. This work is a part of the M. S. thesis of Xiao Wu-han and was supported by the National Natural Science Foundation of China (Grant No. 3870489).     

Chinese Bio-oxidation Gold Extraction Technology Reaches International Advanced Level

In Liaoning, Hunan, Guangxi, Guizhou, Gansu, Sichuan, Anhui, Jilin and other provinces in China, there is a wide occurrence of metal quantity over 1000 tons of refractory gold ores, principally because of low gold recoveries and become ＂stay mine＂. Features of refi＇actory gold ores are： gold in micro-particles or a microscopic state that is wrapped in pyrite, presence of arsenopyrite and other sulfide minerals or disseminated in the crystal lattice of sulfide minerals; harmful impurity elements such as arsenic, carbon, mercury, antimony, copper with high content are closely related with the gold, and these elements affect the contact reaction between the gold and solvent extraction, making the recovery of the gold extraction process low. In the past 20 years, overseas countries have developed the application of the roasting oxidation method, hot acid （alkali） oxidation, bacterial oxidation and flash chlorination oxidation technology to solve this problem.Among these, biological oxidation has developed rapidly in the domestic market and gold enterprises abroad because of its low investment in infrastructure, low production costs, less environmental pollution, simple process and easy control, etc.     

陇西黄土三轴剪切过程微观变化研究

为了解黄土三轴剪切过程中的微观变化,采用PFC3D建立黄土三轴试验模型,模拟围压分别为0、50、150、300 kPa的三轴剪切试验,并与室内试验进行对比分析。分析结果表明：PFC3D能够较好地模拟出不同围压下从开始到破坏到残余变形整个过程中应力-应变的变化规律,且位移场及接触应力场的变化规律与室内三轴试验宏观现象较一致;发现弹性模量、泊松比及峰值强度与数值模型中微观参数有着密切的联系,如法向刚度kn控制试样宏观弹性模量,kn /ks值控制泊松比,摩擦系数控制峰值强度;通过体应变-轴向应变曲线发现,随着围压的增加应变能增大,试样呈现出由体积膨胀到体积减缩的变化规律。其研究结果为进一步探究黄土的应力-应变性状及抗剪强度特性提供参考。     

黄海浒苔绿潮及其溯源研究进展

2007-2012年,黄海连续6a暴发了大规模绿潮。分析了过去5a国内外对黄海绿潮以及绿潮形成种浒苔的研究进展,并总结了对黄海绿潮浒苔溯源的主要观点。结合国内外对绿潮浒苔生物学研究结果,深入分析了大规模黄海绿潮暴发的关键要素(绿潮形成种、近海海水富营养化和其它海洋环境因子)以及生物生态学机制,根据已知的结果推演黄海绿潮全年发生发展过程。据此,认为黄海绿潮大暴发与江苏省近岸海域海水富营养化密切相关,辐射沙洲的浒苔微观繁殖体(孢子、配子及其不同发育程度的显微个体)在绿潮暴发过程中扮演重要角色。     

新疆北天山泥火山固体喷出物特征及成因机制初探

北天山泥火山位于新疆天山北麓山前拗陷带内,均处在背斜褶皱的轴部。在了解泥火山的地质背景、活动现状的基础上,对该区泥火山进行了详细的野外考察,对所采样品进行粒度、显微形貌及成分分析。研究发现:该区域的泥火山样品粒径主要集中在0.3~100μm,平均值相近,分选较差,分布对称性呈极正偏。矿物颗粒以石英、长石为主,基质为黏土矿物,白杨沟和艾其沟样品中均含有铁矿物质。根据上述分析结果对北天山泥火山成因机制进行了初步探讨,认为该区域的泥火山物源相同,泥浆最深来源于下中侏罗统,地层压力以构造活动为主。目前泥火山处于弱活动期,短期内造成较大灾害的可能性很小。     

低温氮、磁化综合处理钻头使用性能提高的X射线 和电子显微技术分析研究

在地质钻探和石油钻井中,钻头都是非常重要的钻进工具。其技术特性,特别是硬度和耐磨性与钻探的技术经济指标,即与机械钻速、钻头进尺和每米钻探成本直接相关。为了提高钻头的工作性能,俄罗斯南方国立技术大学提出了综合低温淬火、磁化回火处理钻头的方法。经过综合处理后,钻头体、复合片底座和钎焊层的硬度分别提高了30%、3%和22%。野外钻进试验结果表明,经过低温液态氮和磁化综合处理的与未经综合处理的钻头相比,每次试验钻头进尺都有提高,总体上钻头进尺提高了222%,取得了很好的钻进效果。并对取得的效果进行了X射线和显微技术分析。