粤西河台金矿田糜棱岩XRD特征及其地质意义

粤西河台金矿田位于钦州湾—杭州湾（钦—杭）结合带南段的云开地区,是典型的受韧性剪切带控制的金矿。然而,对于剪切带中有利于金成矿的地质环境及其成矿过程仍然存在争议。本文在对河台矿区高村矿床进行详细野外地质调查的基础上,通过X射线衍射（XRD）对含金剪切带中各类糜棱岩系列岩石进行系统研究,建立应力变化—成分变异的对比序列,从而进一步揭示剪切变形与金矿化的关系。结果显示,剪切带中白（绢）云母的含量在9%~40%,并且在初糜棱岩、无矿糜棱岩、含矿糜棱岩、无矿超糜棱岩、含矿超糜棱岩中呈现出逐渐递增的趋势。白（绢）云母主要为2M1型,b0值在 0.55505~0.99002 nm之间,初糜棱岩＜无矿糜棱岩＜ 无矿超糜棱岩,分别指示低压、中压和高压环境。可见,从初糜棱岩到超糜棱岩,随着变形强度的增加,热液活动也随之增强,从而新生成了大量白（绢）云母。然而,在含矿的糜棱岩和超糜棱岩中还存在一些低压白云母,推测其可能是在后期脆性裂隙中由于流体活动所新形成的。因此,成矿可能经历了两个阶段,即早期的韧性剪切变形阶段导致金的初步富集,后期叠加的脆性破裂阶段形成具有工业品位的矿体。另外,无矿超糜棱岩的石英含量（29.8%）明显低于糜棱岩（44.2%）,推测在形成石英脉型矿体过程中,部分热液可能来自于其围岩超糜棱岩。因此,相对于初糜棱岩和糜棱岩,超糜棱岩中更有利于金矿的形成。     

根据碎屑白云母40Ar/39Ar年龄追索喜马拉雅造山带的剥落历史——对青藏高原隆升过程的启示

对喜马拉雅前陆盆地和孟加拉海扇中各地层的碎屑白云母40Ar/39Ar资料的系统分析揭示了喜马拉雅造山带自印度-欧亚板块碰撞开始造山以来的整个剥落历史: 剥落速率开始较为稳定,然后开始上升,在22Ma左右达到峰值,为4~5mm/a,随后急剧下降,最终以2mm/a的速率保持平稳。喜马拉雅造山带与青藏高原周缘剥落历史的对比约束了印度-欧亚板块碰撞造成青藏高原东缘和北缘的不同反应方式。即开始时的挤压主要被青藏高原北缘的大规模左旋走滑吸收, 到30Ma左右,喜马拉雅造山带冷却、剥落速率显著增强,北缘左旋走滑造成的柴达木地块的向东运动被华北板块阻挡而停滞,因此在北缘发生了一些重要的冷却和抬升剥落事件。至18Ma左右,喜马拉雅造山带的冷却、剥落速率继续增高并维持在较高水平,而该时间段内无论是北缘还是东缘,均未发生显著的抬升剥落事件,因此青藏高原的整体隆升和地壳增厚可能发生在此期间。中新世末—上新世初开始至今,青藏高原东缘龙门山地区发生了一些显著的抬升剥落事件,导致了大量的山崩和河流侵蚀,即此时来自喜马拉雅的挤压主要被青藏高原向东方向的地壳逃逸所吸收。     

甘肃北山红尖兵山钨矿床的40Ar-39Ar同位素年代学研究

文章对红尖兵山钨矿云英岩中的白云母进行了40Ar-39Ar同位素年代学研究,获得的坪年龄为(216.6±1.6)Ma(2σ),等时线年龄为(215.2±2.8)Ma,MSWD=0.47,40Ar/36Ar初始比值为333±47。等时线年龄与坪年龄在误差范围内完全一致,可认为该结果近似代表了黑钨矿的形成时代,即红尖兵山的黑钨矿形成于印支期。     

新疆哈密镜儿泉伟晶岩型稀有金属矿床40Ar-39Ar年龄及其地质意义

文章通过对哈密镜儿泉伟晶岩型稀有金属矿床中白云母的40Ar/39Ar同位素定年研究,测得该矿床的同位素年龄数据,其坪年龄为(243±2)Ma。这一结果显示,镜儿泉的含稀有金属伟晶岩脉是在印支期形成的,并且在形成之后没有再受到后期地质事件的影响。与阿尔泰成矿省相似,东天山在印支期也发生了伟晶岩型稀有金属的成矿作用。这表明,东天山地区的成矿演化与阿尔泰地区具有可比性,从而为2个地区的地质找矿指出了新的方向。     

山东胶南地区榴辉岩围岩中白云母的初步研究

山东胶南地区的白云母赋存于榴辉岩及其围岩中。研究表明，白云母的化学成分与温度、压力和原岩成分有关，其阳离子数Ｓｉ一般＞３．３，属多硅白云母。白云母的晶体结构以３Ｔ型为主，ｂ０＝０．９０３０ｎｍ～０．９０５４ｎｍ，其同位素年龄在１５５Ｍａ左右     

湘西沃溪金锑钨矿床中白云母的矿物学研究

白云母广泛存在于矿床的各种赋矿围岩中。作者对各种地质产状及不同时期形成的白云母在矿床中的分布特征、化学成分及元素组合、晶体化学参数、晶胞参数、热分析特征、红外光谱学特征等进行了较详细的研究，找出了有矿化和无矿化及不同类型的矿化之间白云母的主要差别，确定了本矿床的白云母的标型特征，对找矿勘探具有重要的指导意义     

Regional distribution of Al-silicates and metamorphic zonation in the low-grade Verrucano metasediments from the Northern Apennines, Italy

Abstract Mineralogical and petrological studies of Triassic Verrucano metasediments of the Northern Apennines are reported. The widespread occurrence of Al-silicates allows the delineation of four metamorphic zones with increasing metamorphic grade: (1) kaolinite zone (well Perugia 2, Umbria); (2) kaolinite-pyro-phyllite zone (Monte Argentario and part of the Verrucano of the Monticiano-Roccastrada area and Monti Leoni); (3) pyrophyllite zone (Monti Pisani, Iano, Monti Leoni, the Monticiano-Roccastrada area and some wells in the Larderello region); (4) kyanite zone (Massa area and some wells in the Larderello area).
The four metamorphic zones correspond to temperatures ranging from 300°C to about 450°C. On the basis of the Si content of muscovite and geological arguments, pressures of between 3 and 5 kbar are estimated. The metamorphic zones are located more or less parallel to the bent north-west-south-east trending structural zonation of the Northern Apennines, with the concave side towards the Tyhrrenian Sea.
During the Alpine orogeny, the Verrucano metasediments underwent three folding phases each of which has produced an axial plane schistosity (S₁, S₂, S₃). During the first folding phase the Verrucano sediments were buried increasingly deeply within the crust from east to west. The climax of Alpine metamorphism was attained prior to the second folding phase with crystallization of porphyroblasts of kyanite and chloritoid in a central area located between Massa and Larderello. The inferred paleo-temperature distribution pattern resembles an asymmetric thermal high defined by the kyanite zone, and surrounded by the pyrophyllite zone. A similar pattern is still present in the Tuscan crust, as indicated by a series of geothermal anomalies passing through the Northern Apennines.     

副矿物的电子探针化学定年方法原理及应用

化学定年方法是利用电子探针分析副矿物中的U、Th、Pb含量而进行定年的一种新方法。基本原理是，假设可以忽赂矿物韧始铅，封闭体系中矿物的总铅含量代表U—Th衰变形成的放射性成因铅含量，即：Pb总＝^238U(e^λ238r-1) ^235U(e^λ235r—1) ^232Th(e^λ232r—1)，该方法可利用的副矿物包括：锆石、独居石、褐帘石、碘纪矿、铀石、钍石、晶质铀矿等。本文以华南西华山岩体漂塘花岗岩中的锆石为例，对该方法进行了尝试性的研究。分析结果计算表明，两颗锆石的平均年龄分别为143．9Ma和143Ma，与前人通过同位素方法获得的年龄基本相符。结果还显示，锆石颗粒从中心到边缘的年龄呈现从老到新的趋势。     

A crystal-chemical investigation of Cr substitution in muscovite by XANES spectroscopy

 This work introduces a novel procedure to fit the scattering features of XANES spectra. The procedure was applied and validated on a chromium-containing muscovite for which structural and crystal-chemical characterization is available from literature. The simulation, which involved clusters formed by up to 90 atoms, proved to be effective in representing the Cr local environment, even if the system is characterized by a very low metal content, as demonstrated by the extremely good correspondence with experimental data. Received: 23 May 2002 / Accepted: 6 November 2002     

Nitrogen distribution in Lower Palaeozoic slates/phyllites of the Meguma Supergroup, Nova Scotia, Canada: implications for Au and Zn-Pb mineralisation and exploration

Major and trace elements and nitrogen were analysed in 59 Cambrian and Ordovician slates/phyllites of various lithostratigraphic levels within the Meguma Supergroup, 14 Ordovician slates/phyllites of The Ovens gold mineralisation, and 16 Ordovician slates/phyllites of the Eastville Pb-Zn-Cu mineralisation.The fixed nitrogen content and the normative N_fix/K₂O ratio of muscovite separates members of the Goldenville (sandstone-greywacke-quartzite dominated) and Halifax Formation (slate-phyllite dominated). Low fixed nitrogen concentration is related to high manganese concentration. Black slates/phyllites of the saddle-reef-type Au-mineralisation in The Ovens area are characterised by high fixed nitrogen and a high normative N_fix/K₂O ratio of muscovite. The nitrogen is of secondary hydrothermal origin. Therefore, it might be possible to use the fixed nitrogen as an exploration tool for black slates/phyllite hosted gold mineralisation in Nova Scotia. Mineralised slates/phyllites of the Eastville stratabound Pb-Zn mineralisation cannot be distinguished from nonmineralised time equivalent lithologies on the basis of the fixed nitrogen distribution or the N_fix/K₂O ratio of muscovite.