壳聚糖/蒙脱土插层复合物对活性红染料的吸附热力学研究

采用溶液插层法,利用壳聚糖和蒙脱土制备了壳聚糖/蒙脱土插层复合物,使用红外光谱和X-射线衍射分析对其结构进行了表征;以此复合物为活性红染料RR136的吸附剂,考察了复合物中壳聚糖与蒙脱土的摩尔比、染料溶液pH值和浓度、吸附温度及吸附剂用量等因素对吸附性能的影响。结果表明,吸附反应的最佳条件是以壳聚糖与蒙脱土摩尔比为5∶1的插层复合物为吸附剂,反应温度20℃,RR136溶液pH为3。壳聚糖/蒙脱土插层复合物对活性红染料的吸附更符合Langmuir模型,吸附热力学参数ΔGo、ΔHo和ΔSo值分别为-3.338kJ·mol-1(30℃),-37.98kJ·mol-1和-114.77J·mol-1·K-1,表明壳聚糖/蒙脱土插层复合物对活性红染料的吸附是自发的、以物理吸附为主的放热反应。     

Geochemical features and origin of natural gas in heavy oil area of the Western Slope,Songliao Basin,China

The Western Slope of the Songliao Basin is rich in heavy oil resources (>70 × 10⁸ bbl), around which there are shallow gas reservoirs (∼1.0 × 10¹² m³). The gas is dominated by methane with a dryness over 0.99, and the non-hydrocarbon component being overwelmingly nitrogen. Carbon isotope composition of methane and its homologs is depleted in ¹³C, with δ¹³C₁ values being in the range of −55‰ to −75‰, δ¹³C₂ being in the range of −40‰ to −53‰ and δ¹³C₃ being in the range of −30‰ to −42‰, respectively. These values differ significantly from those solution gases source in the Daqing oilfield. This study concludes that heavy oils along the Western Slope were derived from mature source rocks in the Qijia-Gulong Depression, that were biodegraded. The low reservoir temperature (30–50 °C) and low salinity of formation water with neutral to alkaline pH (NaHCO₃) appeared ideal for microbial activity and thus biodegradation. Natural gas along the Western Slope appears mainly to have originated from biodegradation and the formation of heavy oil. This origin is suggested by the heavy δ¹³C of CO₂ (−18.78‰ to 0.95‰) which suggests that the methane was produced via fermentation as the terminal decomposition stage of the oil.     

基于探针气体吸附等温线的矿物材料表征技术:Ⅱ.多孔材料的孔隙结构

含纳米孔的天然矿物岩石材料的吸附和催化性能对于表生地球化学过程、材料加工、应用及煤炭开发利用等方面均有着重要意义。本文对比分析了各种纳米孔表征技术,重点介绍了基于吸附等温线的纳米孔研究方法。对三个典型样品等温线数据的模型计算表明,应根据材料中孔的形态(平行板状孔、球形孔和圆柱形孔)选择模型,不同类型孔所对应的计算方法和参数有很大差别。表征材料表面能量均匀的样品可首先考虑采用DFT法;HK法一般只作为定性研究方法,BJH方法受样品本身性质参数的影响较小,且计算简单,可广泛应用于介孔材料的孔径分布的表征。     

准噶尔盆地吉木萨尔凹陷二叠系芦草沟组储层介—宏孔孔隙结构特征及控制因素

吉木萨尔芦草沟组页岩油资源潜力巨大,为探究其储层介—宏孔孔隙结构特征及控制因素,以研究区芦草沟组钻井岩心为对象,利用X射线衍射、铸体薄片、扫描电镜、孔渗测试、高压压汞、氮气吸附、分形理论、相关性分析等方法,对其储层特征、孔隙结构及控制因素进行了讨论。研究发现：1）研究区芦草沟组储层是一套以长英质碳酸盐岩（A岩）、长英质黏土岩（B岩）、灰/云质细粒长英沉积岩（C岩）、混积岩（D岩）为主的低孔—特低孔、特低渗储层,主要孔隙类型为溶孔,此外还发育有剩余粒间孔、晶间孔、微裂缝;2）研究区芦草沟组储层孔隙分布复杂,孔径分布曲线呈现多峰形,介孔提供了大部分孔容和比表面积;高压压汞计算的宏孔分形维数均值和氮气吸附计算的介孔分形维数均值分别为：2.864 7、2.507 5,介孔孔隙结构复杂程度相对较低;3）有机质丰度有利于A岩、B岩和C岩宏孔孔隙结构的发育,会导致C岩介孔和D岩孔容、比表面积减小;有机质演化程度对A岩介孔、B岩和C岩介孔起到建设作用,对C岩宏孔、D岩介—宏孔有破坏做用;4）脆性矿物含量越高C岩介孔和D岩孔容比表面积越大,而A岩、B岩宏孔、C岩宏孔孔容、比表面积减小;黏土矿物对A岩介孔、C岩介孔及D岩的孔隙系统发育起到建设作用,对B岩宏孔和C岩宏孔有破坏作用。孔隙结构的发育主要受有机质（有机质丰度、有机质演化程度）和矿物组份（脆性矿物含量、黏土矿物含量）的影响,不同岩性、不同尺度的孔隙发育影响因素各有差异。

     

珠江三角洲及珠江口海区的空气微生物含量

１９９４年６，７月，调查了广州、深圳、珠海及珠江口海区的空气微生物粒子沉降量状况。发现空气微生物粒子总量、真菌粒子量、真菌粒子数／总菌粒子数百分比在三市中不一致。这三种数据一般是陆上的高于海上。随着距陆的增加，都市影响的减弱和海面的开阔，空气微生物含量呈减少之势，显示出海洋新鲜空气对陆上污染空气的调节、净化作用。文中还分析了空气微生物有关参数与气温、风力或相对湿度间的相关关系。     

三峡库区消落区表层沉积物磷吸附特征

以三峡库区消落区表层沉积物为研究对象,通过对干湿交替沉积物中磷的赋存形式、吸附等温曲线的分析,揭示了干湿交替过程中沉积物磷的分布规律、吸附特征以及磷的源汇变化。结果表明:上覆水总磷变化呈现11月总磷<5月总磷<8月总磷。消落区覆水到出露沉积物最大磷吸附量、土壤最大缓冲能力在增加,磷零吸持平衡浓度、易解吸磷在降低,表明沉积物在夏季出露落干的过程中,固磷能力增强,释磷能力减弱;消落区土壤首次覆水过程中土壤磷呈现出由源到汇的转变。成库初期,覆水时沉积物主要表现为磷的积累,次年水库开闸放水排沙时,消落区表层富磷沉积物被冲刷排出。     

淡水中丝状绿藻对重金属Pb2+的吸附

通过淡水中绿藻门的一些丝状种类,如毛枝藻(Stigeoclonium)、刚毛藻(Cladophora)、水绵(Spirogyra)对铅的吸附实验,研究淡水藻类与铅的吸附关系及影响因素。结果表明,淡水中丝状绿藻对铅有较强的吸附能力, 当pH值和温度以及包埋藻类的量控制在一定条件下,即pH值约为4,温度为28℃左右,按照2 g藻类处理20 mL 质量浓度为100 mg/L Pb²⁺溶液原则包埋藻类,就可以使单位藻类吸附效率达到40％。     

Evaporitic sedimentation and microbial mats in a salina system (Port Fouad,Egypt)

A salina system along the Mediterranean coast of Egypt was investigated. Five sedimentary facies are described. For each facies, the evaporitic sedimentation and the biological conditions are considered. Comparisons of evaporite precipitates in the salina with ancient deposits are made.     

天然胶体的水环境行为

胶体是一种分散相粒子具有特定粒径(通常为1 nm~1μm)的混合物,天然水体中的胶体通常是指水环境中普遍存在,而又符合“胶体”形态定义的物质的总和.因为具有特殊的表面性质以及独特的水动力学特点,天然水体中的胶体被认为是一种重要的污染物载体,尤其在促进重金属类的污染物迁移以及性质转化的过程中具有重要作用.本文归纳总结了水环境研究领域中胶体概念的提出与发展,讨论了现有研究中对胶体的定义与理解,比较了当前几种主要的胶体提取手段的特点.同时,针对胶体在水环境中的环境行为,详细归纳了河湖水体中胶体的物质组成、特征以及相应的检测手段,重点总结了胶体在水环境中对污染物的结合作用、胶体污染物的生物效应、胶体自身的团聚规律以及胶体对污染物迁移的影响机制.本文提出了胶体在水环境中复杂的组成成分与动态变化在胶体研究中的重要性,并对进一步揭示胶体环境效应的研究思路以及方法手段进行了展望.     

Biodegradation and transport of benzene,toluene, and xylenes in a simulated aquifer: comparison of modelled and experimental results

Both laboratory experiments and numerical modelling were conducted to study the biodegradation and transport of benzene–toluene–xylenes (BTX) in a simulated semi‐confined aquifer. The factors incorporated into the numerical model include advection, hydrodynamic dispersion, adsorption, and biodegradation. The various physico‐chemical parameters required by the numerical model were measured experimentally. In the experimental portion of the study, BTX compounds were introduced into the aquifer sand. After the contaminants had been transported through the system, BTX concentrations were measured at 12 equally spaced wells. Subsequently, microorganisms obtained from the activated sludge of a sewage treatment plant and cultured in BTX mixtures were introduced into the aquifer through the 12 sampling wells. The distribution data for BTX adsorption by the aquifer sand form a nonlinear isotherm. The degree of adsorption by the sand varies, depending on the composition of the solute. The degradation time, measured from the time since the bacteria were added to the aquifer until a specific contaminant was no longer detectable, was 35–42 h for BTX. The dissolved oxygen, after degradation by BTX compounds and bacteria, was consumed by about 40–60% in the entire simulated aquifer; thus the aerobic conditions were maintained. This study provides insights for the biodegradation and transport of BTX in aquifers by numerical modelling and laboratory experiments. Experimental and numerical comparisons indicate that the results by Monod degradation kinetics are more accurate than those by the first‐order degradation kinetics. Copyright © 2002 John Wiley & Sons, Ltd.