Hot contacts of garnet peridotites in middle/upper crustal levels: new constraints on the nature of the late Variscan high-T/low-P event in the Moldanubian (Central Vosges/NE France)

P–T  paths based on parageneses in the immediate vicinity of former high-temperature contact zones between mantle peridotites and granulitic country rocks of the Central Vosges (NE France) were derived by applying several conventional thermometers and thermobarometric calculations with an internally consistent dataset. The results indicate that former garnet peridotites and garnet–spinel peridotites were welded together with crustal rocks at depths corresponding to 1–1.2 GPa. The temperature of the crustal rocks was about 650–700 °C at this stage, whereas values of 1100 °C (garnet peridotites) and 800–900 °C (garnet–spinel peridotites) were calculated for the ultramafic rocks. After emplacement of the mantle rocks, exhumation of the lower crust took place to a depth corresponding to 0.2–0.3 GPa. The temperatures of the incorporated peridotite slices were still high (900–1000 °C) at this stage. This is indicated by the presence of high- T  /low- P parageneses ( c . 800 °C, 0.2–0.3 GPa) in a small (1–10 m) contact aureole around a former garnet peridotite. Crustal rocks distant to the peridotites equilibrated in the same pressure range at lower temperature (650–700 °C). High cooling rates (10²–10³ °C Ma⁻¹) were calculated for a garnet–biotite rock inclusion in the peridotites and for the crustal rocks at the contact by applying garnet–biotite diffusion modelling. Minimum rates of 0.75–7.5 cm a⁻¹ are required for vertical ascent of rock units (30 km vertical distance) derived from the crust–mantle boundary, resulting in a late Variscan (340 Ma) high- T  /low- P event.     

Metamorphism and kinematics of the early deformation in the Variscan suture of SW Iberia

The early (Devonian) collisional stage in SW Iberia has been investigated through the analysis of deformation in the Cubito‐Moura schists, the main lithology of an Allochthonous Complex putatively rooted in the suture between the Ossa‐Morena and South Portuguese zones. The first deformation in these schists (D₁) is recorded as a S₁‐L₁ mylonitic fabric well preserved in early quartz veins. Subsequent D₂ deformation caused the main folds and the main (S₂) foliation. After restoration, the stretching lineation (L₁) trends at a small angle with the Ossa‐Morena/South Portuguese suture. This trend, together with the top‐to‐the‐east kinematics determined from quartz microfabric is indicative of an oblique left‐lateral collisional scenario in SW Iberia. Chlorite–white K‐mica–quartz ± chloritoid multi‐equilibrium calculations yield P–T conditions in the range 0.9–1.2 GPa and 300–400 °C, during the first collisional stage. P–T conditions during D₂ were 0.3–0.8 GPa and 400–450 °C, thus indicating an important stage of exhumation of the Allochthonous Complex during these two collisional events, after subduction of the Ossa‐Morena Zone margin under the South Portuguese Zone continental crust. In the general context of the Variscan orogen, dominated by dextral collision, the left‐lateral convergence in SW Iberia can be explained in terms of the Avalonian salient represented by the South Portuguese Zone, which would impinge between Iberia and Morocco.     

Evolution of the Pan-African Wadi Haimur metamorphic sole, Eastern Desert, Egypt

By comparison with the general features of metamorphic soles (e.g. vertical and lateral extension, metamorphic grade and diagnostic mineral parageneses, deformation and dominant rock types), it is inferred that the amphibolites, metagabbros and hornblendites of the Wadi Um Ghalaga–Wadi Haimur area in the southern part of the Eastern Desert of Egypt represent the metamorphic sole of the Wadi Haimur ophiolite belt. The overlying ultramafic rocks represent overthrusted mantle peridotite. Mineral compositions and thermobarometric studies indicate that the rocks of the metamorphic sole record metamorphic conditions typical of such an environment. The highest P – T conditions ( c . 700 °C and 6.5–8.5 kbar) are preserved in clinopyroxene amphibolites and garnet amphibolites from the top of the metamorphic sole, which is exposed in the southern part of the study area. The massive amphibolites and metagabbros further north (Wadi Haimur) represent the basal parts of the sole and show the lowest P – T  conditions (450–620 °C and 4.7–7.8 kbar). The sole is the product of dynamothermal metamorphism associated with the tectonic displacement of ultramafic rocks. Heat was derived mainly from the hot overlying mantle peridotites, and an inverted P – T  gradient was caused by dynamic shearing during ophiolite emplacement. Sm/Nd dating of whole-rock–metamorphic mineral pairs yields similar ages of c . 630 Ma for clinopyroxene and hornblende, which is interpreted as a lower age limit for ophiolite formation and an upper age limit for metamorphism. A younger Sm/Nd age for a garnet-bearing rock ( c . 590 Ma) is interpreted as reflecting a meaningful cooling age close to the metamorphic peak. Hornblende K/Ar ages in the range 570–550 Ma may reflect thermal events during late orogenic granite magmatism.     

Inverted metamorphism and the Main Central Thrust: field relations and thermobarometric constraints from the Kishtwar Window, NW Indian Himalaya

Following the early Eocene collision of the Indian and Asian plates, intracontinental subduction occurred along the Main Central Thrust (MCT) zone in the High Himalaya. In the Kishtwar–Zanskar Himalaya, the MCT is a 2 km thick shear zone of high strain, distributed ductile deformation which emplaces the amphibolite facies High Himalayan Crystalline (HHC) unit south‐westwards over the lower greenschist facies Lesser Himalaya. An inverted metamorphic field gradient, mapped from the first appearance of garnet, staurolite and kyanite index minerals, is coincident with the high strain zone. Petrography and garnet zoning profiles indicate that rocks in the lower MCT zone preserve a prograde assemblage, whereas rocks in the HHC unit show retrograde equilibration. Thermobarometric results derived using THERMOCALC indicate a P–T increase of c. 180 °C and c. 400 MPa across the base of the MCT zone, which is a consequence of the syn‐ to postmetamorphic juxtaposition of M1 kyanite grade rocks of the HHC unit on a cooling path over biotite grade footwall rocks, which subsequently attain their peak (M2) during thrusting. Inclusion thermobarometry from the lower MCT zone reveals that M2 was accompanied by loading, and peak conditions of 537±38 °C and 860±120 MPa were attained. M1 kyanite assemblages in the HHC unit, which have not been overprinted by M2 fibrolitic sillimanite, were not significantly affected by M2, and conditions of equilibration are estimated as 742±53 °C and 960±180 MPa. There is no evidence for dissipative or downward conductive heating in the MCT zone. Instead, the primary control on the distribution of peak assemblages, represented by the index minerals, is postmetamorphic ductile thrusting in a downward propagating shear zone. Polymetamorphism and diachroneity of equilibration are also important controls on the thermal profile through the MCT zone and HHC unit.     

High-precision relative thermobarometry: theory and a worked example

A number of sources of uncertainty are involved in thermobarometric calculations, the most important of which are associated with analytical precision, activity–composition ( a – x ) relationships, and thermodynamic data. Statistical treatment of these uncertainties results in relatively large uncertainties on the calculated values of pressure and temperature. Little can be done, at least in the short term, about the magnitude of such uncertainties, and any thermobarometric calculations in which they are not taken into account should be treated with caution. Given that uncertainties associated with a–x models and thermodynamic data are systematic when applied to multiple samples with the same mineral assemblage, a solution to the problem of imprecise absolute thermobarometry can be obtained via a relative thermobarometric technique referred to as the Δ PT  approach. The Δ PT  approach offers a major improvement in the precision of thermobarometry if the calculations can be presented in a Δ PT  context.     

Cretaceous high-P granulites at Milford Sound, New Zealand: metamorphic history and emplacement in a convergent margin setting

Granulite facies orthogneiss of the Arthur River Complex (ARC) at Milford Sound, western Fiordland records a complex Early Cretaceous magmatic and orogenic history for the Pacific Gondwana margin that culminated in the emplacement and burial of a dioritic batholith, the Western Fiordland Orthogneiss (WFO). Enstatite-bearing mafic to intermediate protoliths of the ARC and WFO intruded the middle to upper crust. The early deformation history of the ARC is preserved in the Pembroke Granulite, where two-pyroxene S1 assemblages that reflect P <8 kbar and T  >750 °C were only patchily recrystallized during later deformation. S1 is cut by garnet-bearing, leucogabbroic to dioritic veins, which are cut by distinctive D2 fractures involving anorthositic veins and garnet–diopside–plagioclase-bearing reaction zones. These zones are widespread in the ARC and WFO and record conditions of P ≈14 kbar and T  >750 °C. Garnet–clinopyroxene-bearing corona reaction textures that mantle enstatite in both the ARC and WFO reflect Early Cretaceous burial by approximately 25 km of continental crust. Most of the ARC is formed from the Milford and Harrison Gneisses, which contain steeply dipping S4 assemblages that envelop the Pembroke Granulite and involve garnet, hornblende, diopside, clinozoisite, rutile and plagioclase, with or without kyanite. The P–T history of rocks in western Fiordland reflects pronounced Early Cretaceous convergence-related tectonism and burial, possibly related to the collision and accretion of island arc material onto the Pacific Gondwana margin.     

Compositional variation of phlogopite in a marble sample: implications for geological thermobarometry

Abstract The textural and compositional features of phlogopites in a contact-metamorphic dolomite marble inclusion in the Bergell intrusion (central Alps) and in a metasomatic reaction vein cutting through this marble suggest different origins for vein phlogopites:
(a) High-Al vein phlogopite represents former marble phlogopite which has been compositionally modified by reaction with the vein forming fluid.
(b) Low-Al vein phlogopite represents phlogopite precipitated from the vein forming fluid.
As both types of vein phlogopite were in contact with the same vein forming fluid at the same time, low-Al phlogopite most likely represents an equilibrium phlogopite composition, whereas high-Al phlogopite does not. High-Al vein phlogopite retained its Al-content from the contact-metamorphic marble parent phlogopite and only underwent Fe-Mg exchange with the metasomatic fluid.
All the vein phlogopites studied are strongly enriched in Fe relative to marble phlogopite. The data may suggest in general that phlogopite Al/Si ratios may be retained from the conditions under which the phlogopites first formed, whereas the Mg/Fe-ratios may be substantially modified by exchange with other ferromagnesian solid phases and/or a metamorphic fluid at later stages in their metamorphic history. This may have significant effects on calculated pressures and temperatures from thermobarometers involving biotite.     

The (Na–Ca)amphibole–albite–chlorite–epidote–quartz geothermobarometer in the system S–A–F–M–C–N–H2O. 2. Applications to metabasic rocks in different metamorphic settings

In order to illustrate different applications of the amphibole-albite-chlorite-epidote-quartz geothermobarometer, pressure-temperature-time ( P–T–t ) ± space ( P–T–t–s ) ± deformation ( P–T–t–d ) paths have been established from literature data. They are discussed as a function of the chemical, equilibrium and microstructural data available in each case, and compared with the conclusions already established by other methods. It is clear that it is necessary to know the relative chronology of the events (directions of zoning of minerals in successive microstructural positions) to establish precise P–T paths; this enables reconstruction of complex geodynamic histories. From this point of view, it is necessary to analyse the maximum possible number of minerals in a few well-chosen metabasic rocks showing different generations of blastesis. The rocks should belong to different tectonic units to obtain the best overall picture of a metamorphic complex.     

High-pressure,low-temperature metamorphism in Alpujarride Units of southeastern Betics (Spain)Métamorphisme de haute pression et basse température dans les unités Alpujarrides du Sud-Est de la cordillère Bétique (Espagne)

We present the first occurrences of high-pressure, low-temperature ferro-magnesiocarpholite-bearing mineral assemblages associated to quartz segregations in the Alpujarride units of southeastern Betics (Sierra de Almagro, Sierra de los Pinos and Sierra Cabrera). Thermobarometric results show that the carpholite-bearing rocks underwent the same P–T conditions in the three outcrops, i.e. 8–10 kbar, 350–400 °C. Metamorphic and structural data allow us to conclude that these rocks belong to the same Alpujarride unit. In the Sierra de Almagro, tectonic units with carpholite-bearing rocks overlie low-pressure, low-temperature Alpujarride units, then forming a stack with an inverted tectono-metamorphic sequence, as observed in the central and western part of the Alpujarride complex. The preservation of carpholite-bearing assemblages in these rocks implies that no significant temperature increase occurred during the exhumation history. To cite this article: G. Booth-Rea et al., C. R. Geoscience 334 (2002) 857–865.     

Petrological and geochronological constraints on regional metamorphism along the northern border of the Bitterroot batholith

Quantitative thermobarometry in pelites and garnet amphibolites from the Bitterroot metamorphic core complex, combined with U–Pb dating of metamorphic monazite and zircon from footwall rocks, provide new constraints on the P – T  – t evolution of footwall rocks. The thermobarometric and geochronological results, when correlated with observations from other regions bordering the Bitterroot batholith, define a regional metamorphic history for the northern margin of the Bitterroot batholith consisting of three distinct events beginning with early prograde metamorphism (M1) coincident with arc-related magmatism and crustal shortening at c .  100–80 Ma. Magmatism and crustal thickening led to regional upper-amphibolite facies metamorphism (M2) and anatectic melting between 64 and 56 Ma. Mineral textures related to high-temperature isothermal decompression (M3), coincident with late stages of magmatism in the Bitterroot complex footwall (56–48 Ma), are only preserved in areas adjacent to extensional structures. The close temporal relationship between peak metamorphism and the onset of footwall decompression indicates that thermal weakening was an important factor in the initiation of Early Eocene regional extension and tectonic denudation of the Bitterroot complex and possibly the Boehls Butte metamorphic terrane. The morphology of the decompressional P – T  – t path derived for Bitterroot footwall rocks is similar to other trajectories reported for Cordilleran core complexes and may represent a transition in the deformational style of core-bunding detachments responsible for exhumation.