苏鲁地体南缘超高压变质带朐山二云花岗片麻岩的地球化学特征及其构造意义

二云花岗片麻岩是组成苏鲁地体南缘超高压变质带朐山杂岩体的重要岩石类型,虽然经历了超高压变质作用,但仍保留了花岗岩的岩石学特征。常量元素和微量元素分析结果表明该片麻岩具有高w(K₂O)、低w(CaO)、高w(TFeO)/w(MgO)比值、铝饱和指数偏高的A型花岗岩的特征,岩石类型为高钾碱性过铝质A型花岗岩。稀土元素中轻稀土富集、分馏程度高、Eu强烈亏损,微量元素中Ba、P、Ti、Sc具有明显的负异常,w(Sr)/ w(Y)、w(La)/ w(Yb)和w(Rb)/ w(Sr)、w(Rb)/ w(Ba)较高,尤其是w(TiO₂)＜0.2％和w(Y)/ w(Nb)＞1.2的特征,以及在w(Rb)-w(Yb+Ta）和w(Rb)-w(Y+Nb）判别图解上样品投点位于板内环境区等,表明该片麻岩的原岩形成于板内与裂谷有关的非造山环境。锆石SHRIMP U-Pb测年结果揭示其侵位时代为新元古代中晚期((722±32）Ma）,与杂岩体中早期侵位的二长花岗片麻岩及杂岩体上覆地层中的变质火山岩同为Rodinia大陆裂解、扬子地块陆内裂谷形成过程中伴随的岩浆活动的产物。     

元阳梯田水稻地方品种与现代水稻品种的农艺性状比较研究

本文对3个元阳县哈尼族人持续种植了上百年的水稻品种和3个现代品种分别种植在元阳梯田6个不同海拔梯度进行主要农艺性状比较研究。研究结果表明：传统品种在不同海拔的株高、穗长、有效穗等农艺性状差异不显著,而现代品种在不同海拔的农艺性状波动较大,这可能是元阳地方水稻品种长期种植与环境相适应的结果。     

论壮族地区的水稻种植与环境适应的关系

水稻种植过程中,常具有浓厚的环境适应的特征。分布在不同地貌区的壮族是典型的稻作民族,已充分意识到所在地区气候、土壤等自然地理环境对水稻种植的深刻影响。为适应自然地理环境,发挥最大的生产效益,山居壮族多选择种植生长期较长、耐寒、耐肥的粳稻为主;在平原丘陵地区的壮族则以种植生长期短的籼稻居多;为适应岩溶山区干旱少水、不利于灌溉的环境,当地壮族则多种陆稻,但由于陆稻口感不佳以及所在地区人地关系由宽趋紧,导致陆稻在壮族种植结构中的地位不断下降。此外,壮族在生活中对水稻用途的定位,也影响到水稻品种的选择与种植。     

粤北连平地区钨锡多金属矿床成矿时代研究

粤北连平地区钨锡多金属矿床类型主要为石英脉型.采用云母Ar-Ar法和石英包裹体Rb-Sr法.分别获得:锯板坑含钨锡石英脉中的云母Ar-Ar坪年龄为(139.2±1.5)Ma(等时线年龄为143.6±3.9 Ma,MSWD:0.30):鸡啼石含钨石英脉中石英包裹体Rb-Sr等时线年龄为(155.4±5.1)Ma(MSWD=2.1).结果表明该区存在燕山早期和燕山早晚过渡期两期钨锡多金属成矿作用,并且认为:(1)鸡啼石钨矿为南岭地区中生代大规模成岩成矿作用高峰期(150～160 Ma)的产物;(2)南岭地区140 Ma左右也有大型钨锡多金属矿的形成.这一成果为研究区域成矿规律,指导区域找矿提供了重要同位素年代学依据.     

Fluid-induced breakdown of white mica controls nitrogen transfer during fluid–rock interaction in subduction zones

ABSTRACT

In order to determine the effects of fluid–rock interaction on nitrogen elemental and isotopic systematics in high-pressure metamorphic rocks, we investigated three different profiles representing three distinct scenarios of metasomatic overprinting. A profile from the Chinese Tianshan (ultra)high-pressure–low-temperature metamorphic belt represents a prograde, fluid-induced blueschist–eclogite transformation. This profile shows a systematic decrease in N concentrations from the host blueschist (~26 μg/g) via a blueschist–eclogite transition zone (19–23 μg/g) and an eclogitic selvage (12–16 μg/g) towards the former fluid pathway. Eclogites and blueschists show only a small variation in δ¹⁵N_air (+2.1 ± 0.3‰), but the systematic trend with distance is consistent with a batch devolatilization process. A second profile from the Tianshan represents a retrograde eclogite–blueschist transition. It shows increasing, but more scattered, N concentrations from the eclogite towards the blueschist and an unsystematic variation in δ¹⁵N values (δ¹⁵N = + 1.0 to +5.4‰). A third profile from the high-P/T metamorphic basement complex of the Southern Armorican Massif (Vendée, France) comprises a sequence from an eclogite lens via retrogressed eclogite and amphibolite into metasedimentary country rock gneisses. Metasedimentary gneisses have high N contents (14–52 μg/g) and positive δ¹⁵N values (+2.9 to +5.8‰), and N concentrations become lower away from the contact with 11–24 μg/g for the amphibolites, 10–14 μg/g for the retrogressed eclogite, and 2.1–3.6 μg/g for the pristine eclogite, which also has the lightest N isotopic compositions (δ¹⁵N = + 2.1 to +3.6‰).

Overall, geochemical correlations demonstrate that phengitic white mica is the major host of N in metamorphosed mafic rocks. During fluid-induced metamorphic overprint, both abundances and isotopic composition of N are controlled by the stability and presence of white mica. Phengite breakdown in high-P/T metamorphic rocks can liberate significant amounts of N into the fluid. Due to the sensitivity of the N isotope system to a sedimentary signature, it can be used to trace the extent of N transport during metasomatic processes. The Vendée profile demonstrates that this process occurs over several tens of metres and affects both N concentrations and N isotopic compositions.     

内蒙古狼山地区晚志留世二云母二长花岗岩体的厘定及其地质意义

内蒙古狼山山脉西侧分布有零星的早古生代岩浆岩,晚志留世二长花岗岩体主要出露于潮格温都尔镇一带,侵位地层为宝音图岩群。该岩体岩性为二云母二长花岗岩,其LA-ICP-MS锆石U-Pb年龄显示,~(206)Pb/~(238)U加权平均年龄为419.6±4.5～416.0±2.0Ma。岩石为块状构造,暗色矿物为黑云母,可见原生白云母,高硅(SiO_2=73.14%～75.76%)、富碱(Na_2O+K_2O=5.85%～8.20%)、强过铝质,未见闪长质包体,显示了S型花岗岩的特点。岩石富集大离子亲石元素Sr、K、Pb,不同程度亏损高场强元素Nb、Ta、P、Ti,轻稀土略富集,重稀土平坦,Eu异常不明显;锆石负的ε_(Hf)(t)值(-8.3～-4.0)及t_(DM2)为1658～1930Ma(平均值为1759Ma),显示了古—中元古代古老地壳熔融的特点。R2-R1判别图显示了岩石具有同碰撞花岗岩的特点,因此,该岩体可能形成于同造山拼贴的构造背景,与南侧善岱庙地区晚志留世花岗岩的构造属性一致。对比白乃庙地区的晚志留世石英闪长岩,两者岩石地球化学特征具有相似性,可能反映了相同的构造背景。     

江西云山岩体的成因：年代学、地球化学及Nd- Hf同位素制约

云山岩体位于赣北的江南造山带东段九岭隆起带东北端,主要由二云母二长花岗岩组成。本文对该岩体进行了详细的锆石U-Pb年代学、主量元素、微量元素以及Nd-Hf同位素研究。LA-ICP-MS锆石U-Pb定年表明云山二云母二长花岗岩的形成年龄为125.6±1.1Ma,为燕山晚期早阶段岩浆活动的产物。岩相学和岩石地球化学研究表明云山岩体属于高分异的S型花岗岩,具高硅、富碱、过铝质,锆饱和温度低、轻重稀土分馏明显、富集Rb、Th、U、K、Pb等元素而亏损Ba、Nb、Sr和Ti等元素、铕负异常显著(Eu/Eu~*=0.13～0.20)的特点。云山岩体的全岩ε_(Nd)(t)值与锆石ε_(Hf)(t)值分别变化于-3.9～-5.1和-1.0～-8.8,两阶段Nd和Hf同位素模式年龄分别为T_(DM2)(Nd)=1.35～1.44 Ga和T_(DM2)(Hf)=1.25～1.75 Ga,Nd同位素的模式年龄重叠于Hf同位素模式年龄。结合其CaO/Na_2O值均小于0.3,本次研究认为云山岩体的源区很可能是来自于双桥山群中的富泥质变质沉积岩及少量火成岩,形成于早白垩世古太平洋板块俯冲之后的弧后伸展的构造环境。     

层状硅酸盐矿物填料在聚合物中的应用及发展

高岭土、云母、滑石三种常见的层状硅酸盐矿物在聚合物中作为填料对聚合物的刚性，尺寸稳定性及其它物理化学性能如抗压，抗冲击，耐腐蚀，绝缘性有显著的影响。滑石粉可以提高填充材料的刚度冲击强度，硬度和降低线膨胀系数等；高岭土可增大材料的体积，提高塑料的绝缘强度，电阻，增强对红外线阻隔效果等；白云母有利于提高聚丙烯的刚性和屈服强度，冲击强度和断裂伸长率等。聚合物／层状矿物纳米材料的制备作为新兴的技术有着广阔的应用前景。     

A Quaternary Solution Model for White Micas Based on Natural Coexisting Phengite-Paragonite Pairs

A thermodynamic model for the quaternary white mica solid solutionwith end-members muscovite–Mg-celadonite–paragonite–Fe-celadonite(Ms–MgCel–Pg–FeCel) is presented. The interactionenergies for the MgCel–Pg join, the FeCel–Pg joinand the ternary interactions were obtained from natural coexistingphengite–paragonite pairs. Phengite–paragonite pairswere selected based on the criteria that their chemical compositionsmay be represented as a linear combination of the model end-membercompositions and that the respective formation conditions (350–650°C,4–21 kbar) are accurately known. Previously publishedexcess free energy expressions were used for the Ms–Pg,Ms–MgCel and Ms–FeCel binaries. The suggested mixingmodel was tested by calculating multicomponent equilibrium phasediagrams. This proved to be particularly well suited to reproducecompositional variations of white micas from amphibolite-faciesmetapelites. KEY WORDS: white mica; solution model; equilibrium phase diagrams     

Phase Relations and Chemical Composition of Phengite and Paragonite in Pelitic Schists During Decompression: a Case Study from the Monte Rosa Nappe and Camughera-Moncucco Unit, Western Alps

The metamorphic evolution of metapelites from the eastern partof the Monte Rosa nappe and the Camughera–Moncucco unit,both situated in the upper Penninic units SW of the Simplonline, were investigated using microstructural relationshipsand equilibrium phase diagrams. The units under considerationexperienced pre-Alpine amphibolite-facies conditions and underwenta complex metamorphic evolution during the Alpine orogeny. Peakpressures during an early Alpine high-pressure stage of 12·5–16kbar were similar in the Monte Rosa nappe and Camughera–Moncuccounit. A pronounced thermal gradient is indicated during decompressionleading to an amphibolite-facies overprint, as the decompressionpaths went through the chlorite, biotite and plagioclase stabilityfields in most of the Monte Rosa nappe, through the staurolitefield in the easternmost Monte Rosa nappe and in the Camughera–Moncuccounit, and through the sillimanite field in the easternmost Camughera–Moncuccounit. In high-Al metapelites the initial formation of stauroliteis related to continuous paragonite breakdown and associatedformation of biotite. In the course of this reaction phengitebecomes successively sodium enriched. In low-Al metapelites,in contrast, the initial staurolite formation occurs via thecontinuous breakdown of sodium-rich phengite. In both low- andhigh-Al metapelites the largest volume of staurolite is formedduring the continuous breakdown of sodium-rich phengite belowP–T conditions of about 9·5 kbar at 600–650°C.During this reaction phengite becomes successively potassiumenriched as sodium from phengite is used to form the albitecomponent in plagioclase. For ‘normal’ pelitic chemistries,phengite becomes Na enriched during decompression through thebreakdown of paragonite along a near-isothermal decompressionpath. The Na content in phengite reaches its maximum when paragoniteis entirely consumed. During further decompression the paragonitecomponent in phengite decreases again because Na is preferentiallyincorporated into the albite component of plagioclase. KEY WORDS: metapelites; white mica; high pressure; equilibrium diagrams; Western Alps