合成锌镁硅云母K_(1.66)Ba_(0.17)(Mg_3Zn_2)(Si_8O_(20))F_4

本文采用高温熔融体热处理结晶的方法合成了含亲硫元素Zn的云母K_(1.66)Ba_(0.17)(Mg_3Zn_2)(Si_8O_20)F_4,其晶胞参数为α=0.525nm,b=0.911nm,c=2.005nm,β=91.28°。这种新型云母的合成在矿物学和地球化学上具有理论意义。     

Phengite K-Ar ages of schists from the Sanbagawa southern marginal belt, central Shikoku, southwest Japan: Influence of detrital mica and deformation on age

Abstract K–Ar age determinations were carried out on phengite separates from pelitic schists collected systematically from the Sanbagawa southern marginal belt and the associated area. The petrography and phengite chemistry by electron probe micro-analyzer (EPMA) revealed the existence of detrital white micas in the schist that have an extremely older age (108 Ma) in comparison with the neighboring schists (88 Ma) without any detrital mica. The ages become gradually older from the north ( ca 78 Ma) to the south ( ca 90 Ma) except for some samples that contain detrital micas and/or have been reactivated thermally by intrusives. The age is interpreted as an exhumation-cooling age that has been controlled by the ductile deformation of the host rocks that have never experienced a culmination temperature higher than 350°C which corresponds to the closure temperature of the K–Ar phengite system. The southward aging of the recorded ages in the extensive chlorite zone of the central Shikoku, from the Dozan river area of the north ( ca 65 Ma) to the study area of the south ( ca 85 Ma) through the Asemi river area ( ca 75 Ma), is explained in terms of increasing exhumation/cooling rates of the host rocks from north to south. The phengite K–Ar ages in the pelitic schists from the Kyomizu tectonic zone, which is classically considered as a remarkable thrusting shear zone, have no significant difference in comparison with that of the neighboring schists. This fact suggests that the latest stage of brittle deformation during exhumation/uplift has not significantly affected the ages of phengite in the schists.     

White mica K-Ar ages of blueschist-facies rocks from the Piemonte 'calc-schists' of the western Italian Alps

Abstract Fifty calc-schists have been systematically collected from the Piemonte zone of the western Italian Alps and examined in terms of petrology, X-ray powder diffractometer (XRD) analysis of carbonaceous materials, and K-Ar ages of white mica separates. The petrological study and XRD analysis of carbonaceous materials have shown that calc-schists have suffered blueschist-facies metamorphism in the subduction zone of the convergent margin between the Apulian (African) continental and Tethyan oceanic plates. The metamorphic sequence is divided into three mineral zones based on increasing metamorphic temperature: chlorite (lower than 300°C), chloritoid, and rutile (higher than 450°C). The chlorite zone has dispersed ages of white mica separates, ranging from 115 to 44 Ma, whereas the rutile zone has a comparatively uniform age distribution from 60 to 40 Ma. The chloritoid zone has an intermediate age variation. The large variation in the chlorite zone is attributed to mixing of variable amounts of detrital mica derived from older high temperature metamorphic rocks in the separates, which have not been completely reset during Alpine metamorphism. The uniform age (average ca 50 Ma) in the rutile zone is the cooling age of blueschist-facies calc-schists, which have been episodically exhumed at the collision event of the European and Apulian continents in the Paleocene-Eocene.     

焦家式金矿中铬铝云母化学成分的标型性

本文系统研究了胶东地区金矿中产出的铬铝云母亚族中３个白云母、１６个绢云母和３２个含Ｃｒ云母种属的化学成分特征。提出了含Ｃｒ云母种属结构层内四面体、八面体及层间离子种类和数量在焦家式金矿成矿过程中的指示作用，阐明了白云母、绢云母及含Ｃｒ云母种属之间的演化特征在与焦家式金矿化有关的成岩成矿作用中的标型意义。     

Fe-Li云母化学成分的解释和分类

用置换矢量概念解释了115个天然 Fe-Li 云母化学成分的变化。Fe-Li 云母是三八面体 Li-Fe-Al 云母,其基本置换是四锂云母置换。由于 Al-Li 白云母置换和白云母置换的影响,其化学组成变化的基本趋势呈明显的非线性,因而 Fe-Li 云母不是真正的二元系。作为 Fe-Li 云母,富铁黑云母和铁叶云母都是最富铁的成员,因而建议称 Fe-Li 云母为黑云母-锂云母系列。根据化学成分,晶胞参数和折光率的异常变化还提出了该系列自然分类的方案。     

1992—2012年东北水稻生育期变化分析

生产实践中水稻生育期变化是气候条件和品种更新等因素共同作用的结果。利用东北地区13个农业气象站点1992—2012年水稻试验观测资料,分析水稻生育期的变化及其与东北变暖趋势、水稻品种调整的关系。结果表明：水稻生长季平均气温和≥10℃积温在1992—2001年呈显著增加趋势,水稻生长季积温的差别最大可达500℃?d,从2002年开始升温趋势减缓,并略有下降。相应地,2002—2012年与1992—2001年的物候期基本上呈现相反的变化特征,其中抽穗期、乳熟期、成熟期在1992—2001年明显提前,分别提前了3.1、2.9、4.5 d/10a,移栽期、分蘖期、成熟期则在2002—2012年呈现出明显的推迟趋势,分别推迟了4.6、4.7、2.0 d/10a;生育期的变化受多种因素影响,但播种-移栽期、乳熟-成熟期在1992—2001年分别缩短了0.7、1.6 d/10a,而在2002—2012年则分别延长了2.9、2.8 d/10a;总的来说,1992—2012年水稻全生育期整体延长了3.7 d/10a,其主要归因于营养生长期的延长。在试验资料比较完整的12个站点所做的分析表明,在东北水稻种植的生产实践中,不断地通过品种调整适应气候条件的改变,多数站点水稻实际生育期与品种审定生育日数差别较小,说明其品种的选择能够与当年的气候条件较好地匹配,充分利用了当地的气候资源。延吉站、梅河口站、通化站随着气候的持续波动又显示出水稻实际生育期与品种审定生育日数偏差增大的趋势,宁安站和前郭尔罗斯站的水稻种植品种的审定生育日数几乎没有改变。因此,迫切需要对东北气候变化的科学事实和水稻种植适应气候变化的生产实践进行系统的总结,为东北水稻生产适应气候变化提供科学支撑。     

A new combination and two varieties of polystigmate Gomphonema (gomphonemaceae bacillariophyta) from Heilongjiang Province, China

The authors discribed a new polystigmate combination,Gomphonema turris Ehr. var.okamurae (Skv.) Fan et Bao. comb. nov., and two new varieties,Gomphonema turris Ehr. var.latum Fan et Wang. var. nov. andGomphonema acuminatum var.obtusum Fan et Bao, var. nov., that were distinguished by frustule morphology under LM. The samples were collected from freshwater of Heilongjiang Province, China. Project No. 39899400 supported by the NSFC.     

The initiation and development of metamorphic foliation in the Otago Schist, Part 1: competitive oriented growth of white mica

The 3D shape, size and orientation data for white mica grains sampled along two transects of increasing metamorphic grade in the Otago Schist, New Zealand, reveal that metamorphic foliation, as defined by mica shape‐preferred orientation (SPO), developed rapidly at sub‐greenschist facies conditions early in the deformation history. The onset of penetrative strain metamorphism is marked by the rapid elimination of poorly oriented large clastic mica in favour of numerous new smaller grains of contrasting composition, higher aspect ratios and a strong preferred orientation. The metamorphic mica is blade shaped with long axes defining the linear aspect of the foliation and intermediate axes a partial girdle about the lineation. Once initiated, foliation progressively intensified by an increase in the aspect ratio, size and alignment of grains, although highest grade samples within the chlorite zone record a decrease in aspect ratio and reduction in SPO strength despite continued increase in grain size. These trends are interpreted in terms of progressive competitive anisotropic growth of blade‐shaped grains so that the fastest growth directions and blade lengths tend to parallel the extension direction during deformation. The competitive nature of mica growth is indicated by the progressive increase in size and resultant decrease in number of metamorphic mica with increasing grade, from c. 1000 relatively small mica grains per square millimetre of thin section at lower grades, to c. 100 relatively large grains per square millimetre in higher grade samples. Reversal of SPO intensity and grain aspect ratio trends in higher grade samples may reflect a reduction in the strain rate or reduction in the deviatoric component of the stress field.     

The Location of Creativity and U.S. Companies in Germany

This article analyzes how far U.S. companies locate subsidiaries in need of highly skilled staff in state locations in Germany that have a high ranking of creativity. Such locations should provide an especially attractive location for certain “creative” staff, which should be of special interest to U.S. companies in need of highly skilled staff. Analyzing U.S. companies that were established since the year 2000 and with more than fifty staff, we find support for our propositions that nonmanufacturing and organizationally higher rank subsidiaries with a need for urban infrastructure and connectedness are located in creative states in Germany.     

多尺度知识溢出研究——以进出口互动效应为例

知识溢出是地理学探究的重点话题。知识可以在不同的地理尺度上溢出,其效应具有差异化的表现。本文选择进出口互动效应作为知识溢出成果的表征,并基于2002—2015年中国海关进出口贸易数据,实证测度了企业从进口侧所导入的知识在企业内部、区域内部以及区域之间三个地理尺度上的溢出对企业出口所造成的影响。研究发现,在全国范围内,企业自身和企业所在的区域进口新品种的产品,能显著促进企业出口新品种的产品,且前者的促进效应更强。同时,企业邻近区域进口新产品,对本地企业出口新产品存在负向影响。然而,该影响在发达地区中表现为负,在欠发达地区表现为正。文章结果反映了不同地理尺度上的知识溢出具有差异化的表现,溢出效应存在距离衰减特征。本文丰富了地理学对于知识溢出话题的认知,具有一定的理论和现实指导意义。