湘南香花岭锡铅锌多金属矿田的云母类型及对成矿的指示

湘南癞子岭花岗质复式岩体是香花岭锡铅锌多金属矿田的主要成矿岩体,其中云母广泛出现在各期次岩（矿）体之中。笔者等在对癞子岭岩体岩相学研究的基础上,开展全岩主微量元素地球化学分析,同时对岩浆成因云母（花岗岩中的云母）、热液成因云母（矿化云英岩、晶洞矿物集合体以及条纹岩中的云母）进行了电子探针分析。结果表明,癞子岭岩体为一套高钾钙碱性—钾玄质、准铝质—过铝质花岗岩,癞子岭岩体中的云母主要为铁锂云母,从早期到晚期,呈现出FeO和Al2O3含量降低,K2O、F、MnO和Rb2O含量升高,且Pb、Zn、Fe等成矿元素含量逐渐增加的特征。热液成因云母分为以下两种： ① 产于矿化云英岩和晶洞矿物集合体中的云母主要形成于流体出溶的早期,无围岩组分参与,云母类型由铁锂云母演化为锂云母,主要沉淀Fe、Zn、Pb、Mo等成矿元素;② 产于条纹岩中的云母晚于矿化云英岩和晶洞矿物集合体中的云母,有围岩组分参与,云母类型由黑鳞云母变为富镁黑云母和富铁黑云母再变为金云母,主要沉淀Fe、Sn和W等成矿元素。随着流体演化,云母呈现SiO2、F、K2O含量逐渐降低,MgO含量逐渐升高,相应的成矿元素从富Fe 、Zn、Pb、Mo逐渐过渡到富Fe 、Sn和W。     

Provenance of Palaeozoic sandstones from the Carnic Alps (Austria): petrographic and geochemical indicators

An integrated approach of petrographic analysis, whole rock geochemistry and microprobe analysis has been applied to obtain information on the geodynamic development and the provenance for Ordovician to Permian siliciclastic successions exposed within the Carnic Alps (Austria). Sandstone detrital mode and geochemical results refine previous geodynamic interpretations. Late Ordovician samples indicate a stable craton and recycled orogenic and, possible, extensional setting. The Early Carboniferous is interpreted to represent a compressional environment, followed by a Late Carboniferous molasse-type foreland basin, and a Permian extensional geodynamic setting. Contrasting geochemical patterns of post-Variscan and Permian sequences suggest a rift setting. Electron microprobe data of detrital white mica also indicate changes in the provenance. Compositional data reflect a shift from low- to medium-grade metamorphic (Ordovician) to high-grade metamorphic (Carboniferous) to low- to medium-grade metamorphic and plutonic source rocks (Permian). Additionally, our data show that various chemical discrimination diagrams do not include all possible ranges of sandstones, and that high contents of detrital mica and ultra-stable heavy minerals may cause misclassification. Consequently, we propose the use of multi-method approach for provenance studies, including the control of geochemical data by modal analysis and heavy mineral investigations.     

Early Mesozoic unroofing pattern of the Dabie Mountains (China): Constraints from the U-Pb detrital zircon geochronology and Si-in-white mica analysis of synorogenic sediments in the Jianghan Basin

This paper presents the results of an integrated U-Pb detrital zircon geochronology and Si-in-white mica analysis for synorogenic sediments in the Jianghan Basin to the south of the Dabie Orogen. The results provide an improved understanding of the provenance of these sediments and the unroofing pattern of the early Mesozoic Dabie Mountain. Si contents of detrital white micas range from 3.09 to 3.34 atoms pfu for the upper Triassic sandstones whereas 3.06 to 3.59 atoms pfu for the lower and middle Jurassic sandstones. The majority of detrital white micas in the lower Jurassic sandstones is phengitic and originated exclusively from the Dabie high- to ultrahigh- pressure rocks. The U-Pb dating results of the detrital zircons for seven samples suggest that these synorogenic sediments have a significant change of provenance from late Triassic to early and middle Jurassic. For the upper Triassic sandstone, the U-Pb age clusters of these zircons are characterized by ~ 420-450 Ma, ~ 750-820 Ma, ~ 1050-1200 Ma and ~ 2500 Ma with minor Luliangian (~ 1700–2000 Ma) components. In contrast, the zircon ages of the Jurassic sandstones are dominated by the Luliangian (~ 1700–2000 Ma) ages with only minor Caledonian (~ 420-450 Ma) and Greenville (~ 1050-1200 Ma) ages. In combination with other available geological data, it can be concluded that the Dabie HP-UHP rocks might initially be exposed to the surface at the beginning of early Jurassic (~ 190 Ma). The Jiangnan terrain (also named “Jiangnan old continental in Chinese) to the south of the Jianghan basin provided the predominant supply of upper Triassic sediments, whereas the Paleoproterozoic Yangtze crustal materials (overlying the present Dabie Complex at the time) were the important provenance of the Jurassic sediments in the Jianghan basin.     

贵州梵净山前寒武系甚低级变质作用研究

本文运用伊利石结晶度、绿泥石结晶度、云母b0值和绿泥石地质温度计研究了梵净山前寒武系甚低级变质作用。结果表明经Kisch伊利石结晶度标样校正的伊利石结晶度Kübler指数为0.20~0.99°Δ2θ,绿泥石结晶度árkai指数为0.22~0.63°Δ2θ。由此阐明梵净山前寒武系经历了成岩作用到浅变质作用的影响,迄今依然保留了成岩带、近变质带和浅变质带的岩石记录。成岩岩石具有伊蒙混层特征成岩指示矿物,浅变质带具有钠云母特征变质指示矿物。钾云母(伊利石)b0值范围为:0.9000~0.9045nm;平均0.9018nm,b0值累积频率曲线分布介于典型中压—中低压系列之间,估算的压力为366MPa。峰期变质温度为293~364℃,平均342℃,古变质温压梯度为27℃/km。近变质带界线穿越地层和梵净山背斜轴线,表明甚低级变质作用为成岩-构造运动同期或后期构造增厚引起下部和底部岩石随温压的升高而产生的。     

一株产铁载体细菌的筛选及其与云母的相互作用

        产铁载体细菌与云母类矿物相互作用的研究有助于了解矿物生物风化和土壤形成的演化规律和机理。采用纯培养法 自南京龙山废钾矿区酸模根际土壤分离筛选到一株高产荧光铁载体的细菌Z6,通过16S rDNA 序列分析和生理生化反应将其 鉴定为假单胞菌属（Pseudomonas sp.）;通过室温静置培养试验研究Z6 菌株与云母的相互作用结果表明,细菌生长代谢前期 （8~15 d）快速产生大量铁载体,菌株与矿物共培养75 d 后,产铁载体细菌对云母类矿物确实产生了风化作用,黑云母组发 酵液中Fe 含量增加了211 倍,Si 含量增加了约27.8 倍,SEM 显示云母表面出现溶蚀坑,细菌可以在矿物表面形成生物膜或 矿物- 细菌复合物。不同矿物对共培养体系中细菌数量、荧光铁载体含量、溶液pH 的影响不同。     

内蒙古中西部宝音图群云母片岩的变质P- T轨迹与锆石年代学研究

位于内蒙古中西部地区的宝音图群,主要由云母片岩、斜长角闪岩、石英岩和大理岩等组成。其中云母片岩中发育典型的巴罗式递增变质带,目前对于该递增变质带的研究非常薄弱。本文对宝音图群的云母片岩开展了系统的岩相学、矿物化学、相平衡模拟以及锆石U-Pb年代学的研究。岩相学研究结果显示,三个云母片岩样品具有不同的峰期矿物组合,分别为石榴子石+白云母+黑云母+斜长石+石英,十字石+白云母+黑云母+斜长石+钛铁矿+石英,石榴子石+蓝晶石+白云母+黑云母+斜长石+钛铁矿+石英。此外,样品LS93和LS07存在晚期红柱石的叠加。相平衡模拟研究限定三个云母片岩的峰期温度压力分别为：577℃、0.73 GPa, 620℃、0.78 GPa和670℃、0.8 GPa,具有递增型特征,其峰期温度压力指示的地热梯度为18～20℃/km,为典型的中压相系;此外,三个样品的P-T轨迹均显示早期升温升压直至峰期阶段,随后降温降压的顺时针型,反映地壳加厚和后期抬升的演化过程。云母片岩中的锆石发育典型的变质边结构,变质边的Th/U=0.004～0.02,锆石U-Pb年代学结果显示该变质年龄为398±6 Ma,代表峰期或近峰期阶...     

Fluorine and chlorine in apatites,micas, and amphiboles of layered trap intrusions of the Siberian Platform

Geochemistry of chlorine and fluorine in apatites, micas, and amphiboles in rocks from eight intrusive complexes of the Siberian Platform has been first studied on the basis of new factual and analytical data (more than 1000 analyses). The main attention is focused on minerals from layered intrusions. Most apatites show F > Cl; the maximum contents of halogens are specific to chlorapatite (6.97 wt.% Cl) and fluorapatite (6.04 wt.% F). The total f value (f = Fe/(Fe + Mg), at.%) of femic minerals varies from 2 to 98 at.% in micas and from 22 to 95 at.% in amphiboles. The Cl-f and F-f trends show an increase in the Cl content and a decrease in the F content in the minerals with increasing f. Chlorine clearly exhibits ferrophilic properties, and fluorine has magnesiophilic properties. The halogen-richest minerals are fluorophlogopite (F = 7.06 wt.%, f = 7 at.%), chlorannite (Cl = 6.30 wt.%, f = 89 at.%), and chloroferrihastingsite (Cl = 5.22 wt.%, f = 90 at.%). Coexisting micas and amphiboles in the rocks are close in f value, but the micas are richer in Cl than the amphiboles. We assume that the halogen-containing minerals crystallized at the high pressure of halogen-hydrocarbon fluids at the levels of the MW, IW, and QIF buffers. The reducing conditions of the magmatism process are also evidenced by the presence of graphite and native metals in the rocks. The similarity of the Cl-f and F-f trends of micas and amphiboles from different intrusive complexes indicates the same mechanisms of the melt differentiation and mineral crystallization.     

江汉盆地东部早中生代沉积地层碎屑云母成分:对大别高压-超高压岩石暴露作用的约束

碎屑白云母是碎屑岩中常见的、来自源区的稳定成分,可以用来指示源区性质,多硅白云母是碰撞造山高压-超高压变质岩石的特征矿物。对大别造山带同造山期沉积而成的江汉盆地东部上三叠统-中侏罗统砂岩碎屑白云母化学成分研究表明:上三叠统该区地层砂岩中碎屑白云母多以低硅白云母(Si<3.2)为特征,暗示此时大别造山带高压-超高压岩石很可能没有出露地表;自下侏罗统开始,砂岩中碎屑白云母中多硅白云母(Si>3.3)大量出现,中侏罗统砂岩多硅和低硅白云母发育,表明大别高压-超高压岩石在早侏罗世即已出露地表并经剥蚀搬运至盆地。这一结果从沉积学角度为约束高压-超高压岩石的折返时序和大别造山带演化提供了新的资料。     

长白山区热量资源立体分布模式及其应用

采用二次趋势势面函数模拟长白山区热量资料的地理分布，用地理细网格分析方法推算山区各地的热量资源状况，并以此为基本依据，分析山区主要农作物品种的合理布局，指出不同品种在各地的适宜种植高度带，该项分析了已长白山区气候及农业资源立体开发中的发挥作用。     

右江盆地三叠纪岩层极低级变质作用及地球动力学意义

 右江盆地三叠纪槽盆相浊流沉积岩系遭受过区域极低级变质作用。依据地质观察和伊利石结晶度、绿泥石-云母堆垛集合体、标志性粘土矿物及白云母(伊利石)b0参数测定资料,阐述了泥质岩石的成岩变质作用经浅层(近)变质作用到浅变质作用的转换特征。变质温度区间为150-350℃,低压类型,具高地温梯度(40-43℃/km).变质级及亚带总体与地层时代及岩层在地层柱中的位置有耦合关系,而与区域变形强度无关。最后指出区域极低级变质作用是印支-燕山构造旋回早期及区域变形前的地质事件,属于地壳伸展构造背景下右江边缘型盆地内部的埋藏型变质作用。