溴素的有机化学──Ⅴ.溴代脂肪酸—2,3,5,6—四溴—1,4—苯二酯的合成

以1，4—苯二酚和不同的短链脂肪酸为基本原料，经溴代、加成、形成酰卤和酰化等反应，合成了六种新的溴化脂肪酸—2，3，5，6—四溴—1，4—苯二酯。通过对产物的碳、氢、溴等元素的定量分析，以及红外吸收光谱和氢核磁共振谱的研究，验证了化合物的结构。     

Relationship between biogeochemical features of biogenic elements and flocculation in the Changjiang Estuary

ＲｅｌａｔｉｏｎｓｈｉｐｂｅｔｗｅｅｎｂｉｏｇｅｏｃｈｅｍｉｃａｌｆｅａｔｕｒｅｓｏｆｂｉｏｇｅｎｉｃｅｌｅｍｅｎｔｓａｎｄｆｌｏｃｃｕｌａｔｉｏｎｉｎｔｈｅＣｈａｎｇｊｉａｎｇＥｓｔｕａｒｙ￥ＬｉｎＹｉ＇ａｎ；ＴａｎｇＲｅｎｙｏｕ；ＬｉＹａｎ；Ｄｏ...     

渤海南部海域年极值波浪和设计波浪的特征研究

本文用统计计算和后报方法，获得了本海域不同海区多年年极值波高（Ｈ１／１０）资料。用Ｐ－Ⅲ型和短期测波资料频率分析方法，估算了各海区的设计波高，并依据文献［３］计算出对应的平均周期。用Ｋｏｌｍｏｇｏｒｏｆｆ适合度方法检验所得的结果表明，依Ｐ－Ⅲ型方法拟配的理论频率曲线与经验点十分吻合，从而确定了本海域不同海区最佳的设计波浪。分析本海域年极值波浪的基本特征表明，本海域除了渤海湾北部海区以外，主浪向一般为ＮＮＥ向，渤海海峡区的年极值波高和设计波高均为最大，而向莱州湾及渤海湾沿岸海区逐渐减小；在沿岸海区，由龙口至黄河口一带的极值波高较大。     

季节内SST和混合层深度变化的模式研究

用Niiler—Kraus类型的混合层积分模式,对TOGA—COARE强化观测期间由《实验3号》科学考察船观测资料得到的混合层深度和SST在季节内时间尺度的变化进行了模式研究。指出:1.混合层耗散参数与较长时间尺度过程风应力的变化存在着比较好的对应关系;2.模式可以较好的对风场和热通量场在季节内时间尺度的变化作出响应,模拟出季节内时间尺度SST的变化;3.Niiler,-Kraus模式在考虑耗散作用后,可用于海洋季节内时间尺度变化的模式研究。     

黄河三角洲沿岸及邻近海区细粒沉积物中的碳酸盐

本文用X-射线衍射法直接计算了来自黄河三角洲沿岸及邻近海区80个沉积样的细粒组分(<2μm)中的碳酸盐含量。计算结果与全样的容量法分析结果基本一致。研究结果表明,本区细粒沉积物中碳酸盐含量变化受沉积物来源、海区水动力作用、海底地貌特征和碳酸盐的地球化学行为等因素所影响。     

Reanalysis of the Atmospheric Flux of Nutrient Elements to the Southern Yellow Sea and the East China Sea

Based on the recent research results on dry and wet deposition of nutrient elements and sulphate,we estimate the atmospheric flux of nutrient elements and sulphate to the southern Yellow Sea and the East China Sea in each season.The results suggest that the concentrations of nutrient elements and sulphate in aerosol and precipitation show an apparent seasonal cycle with the maximum values in winter and the minimum values in summer.Depositions of nitrate and sulphate are dominated by wet deposition,while the deposition for phosphate is mainly dry deposition.Moreover,compared with the riverine inputs,the atmospheric deposition may be the main source of dissolved inorganic nutrients in the southern Yellow Sea and the East China Sea.     

A Computational Model for Velocity Separation in Shallow Sea

Based on the hydrodynamical feature and the theoretical velocity profiles of tidal flow and vvind-induced flow in shal-low sea, a computational model is established for the first time, which can separate observed velocity into tidal velocity and wind-induced velocity by use of the least square method. With the model, not only the surface velocities of tidal flow and vvind-induced flow are obtained, but also the bed roughness height is determined and the wind velocity above the wa-ter surface is estimated. For verification of the model, the observed velocity in the Yellow River Estuary and the laborato-ry test is separated, then it is applied to the Yangtze River Estuary. All the results are satisfactory. The research results show that the model is simple in method, feasible in process and reasonable in result. The model is a valid approach to analysis and computation of field dala, and can be applied to separate the observed velocity in shallow sea; at the same time, reasonable boundary conditions of th     

Sensitivity to stress of the estuarine bivalve Macoma balthica from areas between the Netherlands and its southern limits (Gironde)

Variation in the sensitivity to stress of Macoma balthica was measured in several French and Dutch estuaries. For adult and juvenile Macoma balthica exposed to copper under conditions of starvation, differences in mortality rate, condition, glycogen, burrowing rate and copper content were assessed. No significant differences were observed between adults and juveniles; the influence of treatment and origin was always evident. Animals from the most southern estuaries, Loire and Gironde, near to the species's southern limit of distribution, showed, in the field, the strongest deviations for the ecophysiological traits measured, and were in the experiments the most sensitive to stress.     

沃克环流上升区赤道低空强西风带的分析

采用ＴＯＧＡ／ＣＯＡＲＥ国际合作考察期间（１９９２年１０月─１９９３年２月）获得的２６７次定点（２°Ｓ，１５５°Ｅ）定时高空大气探测资料，进行计算分析，发现１９９２年１２月─１９９３年２月低空存在一支西风急流，有两次分别持续半月之久，而１９９２年１１月的两次赤道西风急流，因无赤道高空急流配合，仅持续２ｄ便消失。本文还指出：（１）赤道低空西风急流是各种海－气指数产生ＥＮＳＯ异常的重要信息；（２）赤道高空急流有滞后赤道低空急流２ｄ左右的响应关系；（３）赤道低空急流是纬向水汽输送的狭窄通道。