长江水下三角洲沉积物柱状样重金属垂向分布特征

对长江水下三角洲3个沉积物柱状样进行粒度分析、²¹⁰Pb测年,并测定其中Cr、Cu、Pb、Zn等重金属元素和Al等常量元素的含量,得到了沉积物粒度、粘土含量、重金属含量的垂向分布曲线和沉积物测年数据。通过相关分析来研究沉积物中的Cr、Cu、Pb、Zn等重金属、粒度、Al相互之间的关系;以Al为参照元素对这4种重金属进行归一化处理,分析其归一化前后的垂向分布特征。结果表明,Cr、Cu、Pb、Zn 4种重金属元素在此区域的地球化学行为相似,其分布受细颗粒沉积物的吸附和胶体的絮凝作用共同控制;近一二十年来,该区域的Cr、Cu、Pb含量并没有显著增加,Zn有轻微污染。此外,CJ19柱中Cu存在异常峰值,可能是特大风暴潮事件对研究区浅水区底质沉积物中重金属的分布造成的影响。     

重力异常垂直梯度中央区效应的精密计算

为提高利用重力异常计算重力异常垂直梯度中央区效应的精度,视中央区为矩形域,将重力异常表示成双三次多项式插值形式,引入非奇异变换,推导出了重力异常垂直梯度中央区效应的精密计算公式。以低纬度区域分辨率为2＇×2＇的重力异常数据为背景场进行了仿真分析,结果表明在解算计算点所在的1个网格的中央区效应时,传统公式与本文导出公式计算结果差值的最大值达数E。该导出公式可为重力异常垂直梯度中央区效应的精密计算提供理论依据。     

垂向悬沙扩散与近岸挟沙力理论研究

根据垂向二维悬沙扩散方程和谢才公式,假定泥沙垂向扩散系数为常数或为水深和摩阻流速的函数时,从理论上推导得到一个新的不仅适用一般水域,也适用于高含沙水域的挟沙力公式。公式一阶近似形式上与近岸海域常用的刘家驹公式相一致也不显含泥沙沉速,从理论上证明了刘家驹公式的合理性,说明其经验公式在理论上也成立。对更高阶近似,公式显含泥沙沉速,与维利卡诺夫以及张瑞瑾等挟沙力公式相一致,说明了张瑞瑾公式的合理性。分析了导出的公式的物理意义以及与刘家驹公式和张瑞瑾公式的异同。新的挟沙力公式也表明挟沙力公式的近似应是流速平方的多项式,选择低阶项作为近似会有一定的误差。     

利用海水平均声速进行海洋分布式垂直缆姿态校正

垂直缆地震采集方法能够获得高信噪比、宽频带、宽方位角的地下结构的反射资料,进而实现目标区域的高精度成像。垂直缆姿态的准确获得是高质量地震资料解编的必要前提。利用初至采样点差值与震源激发采样点差值的相关匹配方法,得到共检波点道集。依据超短基线测得的位置参数,得到垂直缆的初始姿态模型,结合海水平均声速的估算值,校正垂直缆的姿态以及确定倾斜角度范围,为垂直缆地震数据的后续处理工作提供支持。     

Numerical study of sand scour with a modified Eulerian model based on incipient motion theory

Application of the standard Eulerian model to simulations of sand scour results in unrealistic phenomena. Therefore, the present work develops a modified Eulerian model based on sand incipient motion theory. The modified model is applied for simulating a two-dimensional single vertical jet and a moving planar jet. The simulation results generally demonstrate fairly good agreement with published results of scour profiles and the velocity contours of the water and sand phases. In addition, equations to describe self-similar scour profiles for the moving planar jet cases are given. The results demonstrate that the modified model efficiently and accurately simulates the two-dimensional sand scour produced by jets, particularly for the moving jet cases.     

南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.     

Local Oceanic Vertical Deflection Determination with Gravity Data Along a Profile

Deflections of the vertical (DOVs) over oceans cannot be directly measured, which restricts their applications. A local covariance function of anomalous potential is put forward in this paper in conjunction with the least-squares collocation (LSC) method to compute the oceanic DOVs utilization of oceanic gravity data along a profile. The covariance functions of gravity field quantities have been derived directly as functions of x, y and z without the need to introduce coordinate transformations corresponding to along- or cross-profile components. In the proposed methodology, gravity data along a profile were used to calculate the residual gravity anomaly using the remove-compute-restore technique. The residual gravity anomaly was used to calculate the parameters of the proposed covariance function of the local anomalous gravity field, which was used in the LSC to compute the residual DOVs along the profile. The residual DOVs added model DOVs to recover the DOVs along the profile. The results of a simulation experiment prove that the proposed methodology is feasible and effective.     

Numerical modeling study of mineralization induced by methane cold seep at the sea bottom

In order to investigate the response of authigenic minerals to gas hydrate geo-systems, the biogeochemical processes and its induced mineralization were predicted by employing the comprehensive reactive transport modeling approach. Based on the available data extracted from the northern continental slope area of the South China Sea, a 1-D vertical column model was developed. Three cases with different upward methane flux rates and three cases with different mineral compositions, i.e., a total of six cases were designed to investigate the effects of variations in the depth of sulfate methane transition zone (SMTZ) and in the mineral composition on the formation of authigenic minerals. The simulation results indicate that the SMTZ depth influenced by both the upward methane flux rate and the initial composition played an important role in the formation of authigenic minerals. The AOM reaction is intensive at the interface, and the precipitation amount of calcite is large, which is mainly controlled by AOM. When the methane leakage rate is 20 times higher than the base case, aragonite starts to precipitate. During the simulation, oligoclase, k-feldspar, smectite-Na, smectite-Ca, chlorite dissolved. Our study specific to this area as a starting point may provide a quantitative approach for investigating carbonate and pyrite formation in hydrate-bearing sediments accounting for methane oxidation and sulfate reduction. The method presented here and the model built in this study can be used for other sites with similar conditions. In addition, this study may serve as an indication for the potential natural gas hydrate reservoir in depth, and is also significant for marine carbon and sulfur cycle.     

长山群岛海区春季水温垂直结构分析

利用海军大连舰艇学院2006年4月长山群岛海区的CTD调查资料,系统分析了该季节长山群岛海区的温度垂直结构,并探讨了其形成机理。分析指出:4月上、中旬是长山群岛海区季节性温跃层的生成期,群岛东侧和南侧边缘受黄海冷水团形成过程的影响,温跃层的出现概率和跃层强度都远远高于群岛内部;在生成时机上,群岛东侧和南侧边缘海域早于群岛内部水域。中间层和底层海水温度的垂直结构与海流有着很好的相关性,在海洋平流的作用下,海区会产生正跃层、逆跃层、冷中间层、暖中间层等复杂的温度垂直结构。上层海水温度结构主要受海面风场和气温的影响,较强的热辐射和充分的风力搅拌能够加速温跃层的生成。     

南海东沙东北部甲烷缺氧氧化作用的生物标志化合物及其碳同位素组成

南海东沙东北部碳酸盐岩和泥质沉积物中的生物标志化合物组合及其碳同位素组成分析表明,研究区内甲烷缺氧氧化作用(anaerobic oxidation of methane-AOM)发育.研究区内碳酸盐岩中含丰富的AOM标志化合物,2,6,11,15-四甲基十六烷(Crocetane-Cr.)、2,6,10,15,19-五甲基番茄烷(Pentamethylicosane-PMI)和2,6,10,15,19,23-六甲基二十四烷(Squalane-Sq角鲨烷)的13C亏损强烈(δ13C值介于-74.2‰~-119.0‰PDB之间),表明碳酸盐岩形成于AOM,同时反映该研究区曾发生过强烈、持续的富CH₄流体释放活动.柱状泥质沉积物中,AOM生物标志化合物在硫酸岩-甲烷过渡带(SMI-Sulfate-Methane Interface)边界附近相对丰度高,SMI之上样品中含量低,或未检出,表明现代环境在SMI附近有大量嗜甲烷微生物生长,使得深部上升的甲烷被大量消耗,很少有甲烷逸出海底.AOM生物标志化合物可用来指示SMI边界.不同站位、不同岩性AOM生物标志化合物组成(包括碳同位素组成)的差异反映了嗜甲烷古细菌组成的不同.