内蒙古巴特敖包地区早古生代洋壳消减的岩石证据

内蒙古白云鄂博北部巴特敖包、查干呼绍一带分布着一系列岛弧型侵入岩,其岩石地球化学特征与典型的埃达克岩(adakite)一致:SiO2多≥56 %,Al2O3>15 %,MgO<3 %(很少大于6 %),Yb(0.726 ~ 2.789)×10-6,La/Yb>10 ~ 20,Y(6.842 ~ 28.734)×10-6,Sr>400×10-6,Sr/Y≥20 ~ 40;Mg#值在0.51 ~ 0.58之间,多大于0.40;稀土元素分析,显示为轻稀土富集、重稀土亏损型,具正铕异常或微弱负铕异常;微量元素蛛网图中具明显的Sr峰和Nb、Ti低谷.9组锆石U-Pb同位素年龄值(206 Pb/238 U)范围在345.06 ~ 552.671 Ma间,反映了本区大洋板块消减事件的年龄.构造环境判别证明它们是在岛弧环境下形成,为早古生代期间南蒙古洋板块向宝音图微陆块发生强烈斜向俯冲(oblique subduction),古洋壳板块发生部分熔融、消减而形成的产物.     

北祁连山西段金属矿床时空分布和生成演化

北祁连山西段以产镜铁山式铁矿而著称,近几年找金和找铜又有新突破。本文从地质构造历史演化角度探讨了区内金属矿床分布的规律,提出从古元代到印支期已经历了９期成矿作用,迄今划分出四个矿床成矿系列及两个矿床成矿亚系列。区内铁呈现出多期成矿,而大多数金属在加里东期“爆炸式”堆积,金的富集成矿与大型剪切一走滑,深部流体上升卸载有关。     

孔兹岩系——山西吕梁地区界河口群的年代学和地球化学

吕梁地区界河口群主要由变泥砂质岩石和一定数量的大理岩及少量斜长角闪岩等类岩石组成。7个变泥砂质岩石样品分析,ΣREE=152～322μg/g,Eu/Eu     

Regional and temporal changes in bivalve diversity off the south coast of Portugal

From 2000 to 2006, a total of 75 bivalve species were identified, varying from 29 (spring 2001) to 54 species (spring 2005) per year. Seasonal tendencies in diversity varied according the year, thus the interpretation of long-term and regional scales is essential before drawing any conclusions in other studies. Richness and diversity consistently decreased with depth and increased with sediment grain size (from low in very coarse sand to high in coarse silt). Diversity decreased progressively from 3 to 16 m depth, thus the harsher shallower environments (due to waves and tidal air exposure) showed greater diversity than the most stable areas. Communities in finer sediments were more diverse than those in coarser sand. Evenness showed patterns opposite to diversity, overall.Diversity and evenness maps (produced with multivariate universal kriging), showed that most geographic areas with greater diversity were farer from river outflows and wastewater treatment plants. Two types of geographic pattern were observed: areas with persistently greater bivalve diversity through time and areas that changed locally from year to year. This spatial analysis can be used to establish priority conservation areas for management purposes, and to analyse the persistency of regional diversity patterns. The area with most habitat heterogeneity (Sotavento) corresponded to greatest diversity.There was a positive relationship between Spisula solida and Chamelea gallina landings and bivalve diversity 2 years and 1 year later, respectively. Possibly, local fisheries, by selectively withdrawing the commercial numerically dominant species from the ecosystem, increased diversity 1 to 2 years later, as the ecological niches of the dominants are quickly filled by several other species thereby creating a more even community. On regional scales, no significant impact was found on long-term bivalve diversity in local fisheries,     

青岛城市规划区不同岩性氡浓度差异及其控制因素

青岛是典型的花岗岩地区,通过分析青岛不同岩性的氡浓度探讨其差异和控制因素。结果表明：青岛不同岩芯的氡浓度变化范围为0.05～19.51 KBq/m3,平均值为2.56 KBq/m3（n=210）,花岗岩氡浓度均值为1.54 KBq/m3,同其他岩性相比氡浓度较低。不同岩性样品氡浓度释放量平均值表现为粉质黏土＞泥岩＞砂质泥岩＞泥质砂岩＞闪长岩＞粉土/填土＞砂岩＞正长花岗岩＞粗砂＞花岗岩＞二长花岗质片麻岩。综合来看,土壤层中氡浓度最高,其次是沉积岩和岩浆岩,变质岩中氡浓度最低。不同岩性氡浓度与其铀含量和孔隙率有关,除花岗岩外,沉积岩和变质岩中铀含量越高所含氡浓度越高,沉积岩、岩浆岩以及变质岩的氡浓度和孔隙率大小呈正相关,沉积岩中氡浓度高于岩浆岩,推测与其所含的富水砂层有关;土壤的土质均匀疏松,孔隙度最高,氡在土壤中有大量的存储空间,故在所有岩性中所含的氡浓度最大。     

Characteristics and origin of carbon isotopes of n-alkanes in crude oils from the western Pearl River Mouth Basin,South China sea

The quantitative characterization of carbon isotopes of n-alkanes is commonly carried out in organic geochemical studies. Possible controls on carbon isotopes include source organic matter, maturity, fractionation during oil expulsion and migration, and the mixing of different oils. In this study of the origin of crude oils in the western Pearl River Mouth Basin, the influences of all of these factors have been considered in reaching a conclusion. Carbon isotopes of n-alkanes in the crude oils, and the extracts of the two effective source rocks (the Wenchang and Enping formations) in the basin, exhibit clear differences. The Wenchang source rocks have heavy δ¹³C values that remain almost constant or become slightly heavier with increasing carbon number. The Enping source rocks have light δ¹³C values that become lighter with increasing carbon number. Two groups of oils in this area were identified based on the carbon isotopes of the n-alkanes; groupIoils are similar to extracts of the Wenchang source rocks. However, the groupIIoils are different from both the Wenchang and Enping source rocks and the carbon isotopic profiles of their n-alkanes exhibit a “V” feature with increasing carbon number. The results of artificial thermal maturation experiments indicate that, from the early stage to the peak stage of oil generation (with EasyRo between 0.64% and 1.02%), the δ¹³C values of n-alkanes in the pyrolysis oils become heavier by about 3‰ with increasing thermal maturity, but the shape of the carbon isotopic profiles are not significantly changed. Calculated δ¹³C values of n-alkanes in “mixed” artificial pyrolysis oils indicate that the mixture of oils generated from the same source rocks with different maturities could not change the carbon isotopic profile of the n-alkanes, however, a mixing of the Wenchang and Enping oils could give the “V” feature in the profiles, similar to the groupIIoils in this area. The groupIIoils appear to be mixed Wenchang and Enping oils, the latter being the dominant component in the mixture. We conclude that the source organic matter and the degree of mixing are the main factors controlling the carbon isotopic characteristics of n-alkanes in crude oils in the western Pearl River Mouth Basin.     

南海北部表层颗粒有机碳的季节和年际变化遥感分析

海洋颗粒有机碳（POC）是海洋固碳的一个关键参数。为了研究南海北部陆架及海盆表层POC浓度的时空分布特征以及变化趋势,本文利用2009-2011年4个季节的实测数据,对NASA发布的MODIS/AQUA卫星月平均POC遥感产品,进行了验证和校正;并利用校正后的遥感数据分析了2003-2014年POC的时空分布特征和变化趋势。发现POC遥感产品与南海北部实测数据具有较好的线性关系（R2=0.72）,但存在系统性偏高,需利用实测数据对遥感数据进行区域性校正。分析校正后的遥感数据发现,南海北部陆架POC浓度较高,平均为（33.34±8.02）mg/m3;吕宋海峡西南海域浓度较低,平均为（29.25±6.20）mg/m3;中央海盆区浓度最低,平均为（27.02±4.84）mg/m3。春夏季POC浓度较低,最低值一般出现在5月,冬季（12月至翌年1月）POC浓度达到最高。利用2003-2014年的长时间序列遥感叶绿素（Chl a）和海表温度（SST）、混合层深度（MLD）模式数据,以及实测数据对南海北部POC浓度的影响机制进行了分析。发现POC与Chl a在秋冬呈现较好的相关关系（R2=0.51）,但在春夏季较离散,表明秋冬季生物作用对POC影响较大。2003-2014年期间,POC与Chl a、MLD及SST存在明显的年际变化,但并没有显著的上升或下降趋势。     

墨西哥湾南部晚侏罗纪主力烃源岩的形成条件

通过对墨西哥湾不同时代可采储量的分布特征和油源对比资料的分析认为,晚侏罗纪烃源岩是墨西哥湾南部最主要的烃源岩。资料显示,晚侏罗纪优质烃源岩形成的主控因素是稳定的构造和沉积条件以及超咸的还原环境,其中,"世界顶级"的晚侏罗纪提塘阶烃源岩主要形成于超咸的碳酸盐岩和/或蒸发岩沉积环境,属半深海还原环境,有机质以藻类为主,推测烃源岩中的有机质可能与极端干旱气候条件下的藻类勃发有关。     

Stochastic bivariate time series models of waves in the North Sea and their application in simulation-based design

In this paper, we present and evaluate three long-term wave models for application in simulation-based design of ships and marine structures. Designers and researchers often rely on historical weather data as a source for ocean area characteristics based on hindcast datasets or in-situ measurements. The limited access and size of historical datasets reduces repeatability of simulations and analyses, making it difficult to assess the sampling variability of performance and loads on marine vessels and structures. Markov, VAR and VARMA wave models, producing independent long-term time series of significant wave height (H_s) and spectral peak period (T_p), is presented as possible solutions to this problem. The models are tested and compared by addressing how the models affect interpretation of design concepts and the ability to replicate statistical and physical characteristics of the wave process. Our results show that the VAR and VARMA models perform sufficiently in describing design performance, but does not capture the physical process fully. The Markov model is found to perform worst of the tested models in the applied tests, especially for measures covering several consecutive sea states.     

Marine hydrocarbon source rocks of the Upper Permian Longtan Formation and their contribution to gas accumulation in the northeastern Sichuan Basin,southwest China

Identification of the main hydrocarbon source rocks of the large Puguang gas field (northeastern Sichuan Basin, southwest China) has been the subject of much discussion in recent years. A key aspect has been the lack of a comprehensive understanding of the development of hydrocarbon source rocks of the Upper Permian Longtan Formation, which had been thought to contain mainly coal seams and thick carbonate layers. In this paper, based on geological data from more than ten wells and outcrops and their related mineralogy and geochemistry, we investigated the depositional environment and main factors controlling organic matter enrichment in the Longtan Formation. We propose a model which combines information on the geological environment and biological changes over time. In the model, organic matter from prolific phytoplankton blooms was deposited in quiescent platform interior sags with rising sea-levels. During the Longtan period, the area from Bazhong to Dazhou was a platform interior sag with relatively deep water and a closed environment, which was controlled by multiple factors including syngenetic fault settling, isolation of submarine uplifts and rising sea-levels leading to water column stratification. Although the bottom water was anoxic, the phytoplankton were able to bloom in the well-lit upper euphotic zone thus giving rise to a set of sapropelic black shales and marlstones containing mostly algal organic matter with minor terrestrial contributions. As a consequence, these rocks have a high hydrocarbon generation potentials and can be classified as high-quality source rocks. The area from Bazhong to Dazhou is a center of hydrocarbon generation, being the main source of reservoired paleo-oils and presently discovered as pyrobitumen in the Puguang gas field. The identification of these source rocks is very important to guide future petroleum exploration in the northeastern Sichuan Basin.