Distribution of nitrate over sea-salt and soil derived particles — Implications from a field study

A method for determining the distribution of supermicrometer nitrate between size-segregated sea-salt and soil derived particles is presented. The analysis is based on field data from six measurements at a coastal site in southern Finland, and on a theoretical treatment taking into account the transfer of gaseous species onto particle surfaces and their subsequent reaction. Significant amounts of nitrate were found in both the particle types, with the fraction of nitrate associated with soil particles varying from 20–50% in the 1–2 m size to near 90% in particles larger than 10 m. Overall, the nitrate accumulation followed closely the relative abundances of these two particle types. Two overlapping modes in supermicron nitrate mass size distributions could be identified. The lower mode, associated with sea-salt, was located between the surface-area and volume distribution of sodium peaking at about 2–3 m of EAD. The upper mode peaked at 3–5 m and followed more closely the surface-area distribution of calcium in all samples. At our site, the accumulation of nitrate into both particle types was shown to be limited by an effective surface reaction rate rather than by gas-phase diffusion. This rate was estimated to be considerably larger for sea-salt particles. Strong evidence in support of the saturation of nitrate in sea-salt particles were obtained.     

A jadeite–quartz–glaucophane rock from Karangsambung, central Java, Indonesia

High-pressure metamorphic rocks are exposed in Karangsambung area of central Java, Indonesia. They form part of a Cretaceous subduction complex (Luk–Ulo Complex) with fault-bounded slices of shale, sandstone, chert, basalt, limestone, conglomerate and ultrabasic rocks. The most abundant metamorphic rock type are pelitic schists, which have yielded late Early Cretaceous K–Ar ages. Small amounts of eclogite, glaucophane rock, garnet–amphibolite and jadeite–quartz–glaucophane rock occur as tectonic blocks in sheared serpentinite. Using the jadeite–garnet–glaucophane–phengite–quartz equilibrium, peak pressure and temperature of the jadeite–quartz–glaucophane rock are P  = 22 ± 2 kbar and T  = 530 ± 40 °C. The estimated P–T conditions indicate that the rock was subducted to ca 80 km depth, and that the overall geothermal gradient was ∼ 7.0 °C/km. This rock type is interpreted to have been generated by the metamorphism of cold oceanic lithosphere subducted to upper mantle depths. The exhumation from the upper mantle to lower or middle crustal depths can be explained by buoyancy forces. The tectonic block is interpreted to be combined with the quartz–mica schists at lower or middle crustal depths.     

A petrogenetic grid for eclogite and related facies under high-pressure metamorphism

The petrogenetic grid between the eclogite and other high-pressure/temperature (P/T) metamorphic facies in a basaltic system is constructed by considering barroisite as one of the important phases in high-P/T metamorphism and by using previous petrological data combined with Schreinemakers' analysis and slope calculation. In the constructed petrogenetic grid, the eclogite facies is bounded by the blueschist and epidote–amphibolite facies with negative-slope reactions at lower temperatures (450–550 °C) and by the epidote–amphibolite, amphibolite and granulite facies with positive-slope reactions at higher temperatures (> 550–600 °C). The eclogite facies does not contact the greenschist facies, and the lowest P condition for the eclogite facies exists at the boundary between the eclogite and epidote–amphibolite facies. The temperature range of the epidote–amphibolite facies increases with increasing pressure until 8–11 kbar and then decreases up to 13–15 kbar. Compared to boundaries of other facies, boundaries of the eclogite facies may have wider P–T ranges. The boundary between the blueschist and eclogite facies occurs over a large temperature range from 450 to 620 ± 30 °C, and the transitions between the eclogite and amphibolite or high-pressure granulite facies occur over a pressure range in excess of 6–10 kbar.     

Phase relations and P–T conditions of the Ryoke pelitic and psammitic metamorphic rocks in the Ina district, Central Japan

The Ina district of the Ryoke Belt is divided into two mineral zones, based on the mineral parageneses of the pelitic and psammitic rocks at the peak metamorphism. A biotite–muscovite zone (quartz + plagioclase + biotite + muscovite with or without K-feldspar) constitutes the northwestern part, and a biotite–cordierite–K-feldspar zone (quartz + plagioclase + biotite + cordierite + K-feldspar) comprises the central to southern and eastern parts. The isograd reaction between two mineral zones is defined by a divariant reaction: Mg-rich biotite + muscovite + quartz = Fe-rich biotite + cordierite + K-feldspar + H₂O (1), which, in the K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (KFMASH) system, occurs at ∼ 590 °C at 0.2 GPa and 660 °C at 0.4 GPa. Fibrolite accompanied by andalusite porphyroblasts in aluminous pelitic rocks of the biotite–muscovite zone and the low-grade part of the biotite–cordierite–K-feldspar zone, suggests that sillimanite was the stable aluminosilicate at the peak metamorphic condition throughout the area. In the high-grade part of the biotite–cordierite–K-feldspar zone, fibrolite mostly occurs as inclusions in cordierite or in plagioclase. The phase relations and the compositional zoning of plagioclase in relation to fibrolite inclusions suggest that fibrolite was formed under relatively high-pressure conditions, and that partial melting took place.     

The impact of human activities in the Malia coastal area (Crete) on groundwater quality

The evaluation of the long-term effects of seawater intrusion into the aquifers due to negative water balance and nitrate pollution of drinking-water quality due to human activities requires detailed knowledge of both the transport of the chemical constituents and the geochemical processes within aquifers. Hydrogeological and hydrochemical studies in the unconfined aquifer of Malia have provided the necessary data to define the areas at increased risk from these phenomena. The solution of the second Fick's low under given boundary conditions gave an estimate of the propagation of groundwater pollution by NO₃ ^–. Additionally, in order to simulate the ion concentration changes during a period, for example a period of positive water balance or refreshening, groundwater transport and cation exchange reactions were modelled using the code PHREEQM. Received: 25 July 1997 · Accepted: 4 November 1997     

辽东-吉南地区早元古代变质地体的组成及主要特征

在辽东－吉南地区存在两个性质不同的变质地体：辽北地体和辽南地体,二者之间以断裂带或韧性剪切带相接。辽北地体包括北辽河群和老岭群,辽南地体包括南辽河群和集安群。不同变质地体内的早元古代变质岩系在地层系统及岩石组合、原岩建造及沉积环境、变质作用类型及ｐＴｔ轨迹、区域构造和岩浆活动等方面都存在明显的差别。它们在早元古代时期形成于不同的大陆边缘,具有完全不同的形成条件和演化历史。两个变质地体最晚在早元古代晚期经构造作用拼贴在一起。     

REE Geochemistry of Some Metamorphic Rock Types of the Late Archean Fuping Group and Their Anatectic Derivatives in Pingshan,Hebei Province,China—A Preliminary Study

The Late Archean Fuping Group of the Xiaojiao area in Pingshan Couty,Hebei Province consists mainly of three metamorphic rock types of supracrustal affinity,i.e.,Kfeldspar leucoleptite,biotite leptite-gneiss and hornblendic rocks.Their anatectic derivatives formed in the initial stage of anatexis are petrochemically of K-feldspar granitic trondhjemitic and granodioritic compositions respectively,and in general have inherted the main petrochemical featurews from their parent rock types,Probably due to the fact that they contain less REE rich accessory minerals as compared with their parent rocks,the anatectic derivatives are in general lower in EREE content,But both the derivatives and their parent rocks have similar REE patterns,which serves as an additional indication of the genetic relationship between them.     

陕西略阳铜厂铜矿床成矿机制分析

从铜厂铜矿床矿石的稀土元素,铅同位素特征及示踪结果,结合岩体形成的构造环境与成矿年代资料,指出铜厂铜矿床为岩浆期后热液与动力变质热液叠加复合型矿床。成矿物质既有来自火山岩围岩的,又有源于岩体本身的,是多源复因矿床。     

Transformations of Benzene Photoinduced by Nitrate Salts and Iron Oxide

This paper reports the results of a study on the transformation of benzene in the presence of solid nitrate salts (NaNO₃, NH₄NO₃) under irradiation in a gas-solid photoreactor. Sodium and ammonium nitrate have been chosen as representative of the composition of atmospheric particulate, benzene as a model aromatic molecule. The purpose is to simulate the transformations that aromatic compounds undergo on the surface of dispersed particles in the atmosphere. Irradiation of sodium nitrate causes hydroxylation and nitration of benzene, yielding phenol and nitrobenzene. This is most likely due to the generation of ^•OH and ^•NO₂ radicals upon nitrate photolysis, with ^•OH + O₂ leading to the formation of phenol and ^•OH + ^•NO₂ yielding nitrobenzene. The percentage of oxygen in the reaction environment influences the transformation pathways, with phenol formation being favoured and nitrobenzene formation depressed by high O₂ concentration. In the presence of hematite (α-Fe₂O₃, another component of atmospheric particulate) very relevant formation of nitrobenzene takes place even with 21% oxygen (simulated air), indicating that the interaction between hematite and nitrate can lead to the formation of aromatic nitroderivatives on the surface of atmospheric particulate. The effect of hematite is possibly due to protonation of peroxynitrite, formed upon nitrate photoisomerisation, to peroxynitrous acid, a powerful nitrating agent. A similar effect leads to relevant formation of nitrobenzene under atmospheric conditions upon irradiation of the acid salt ammonium nitrate.