板块俯冲起始与成熟阶段的差异变质响应

板块俯冲起始是俯冲带最不为人知的关键过程之一,对理解全球板块构造如何启动有重要意义。本文综合了最新的数值模拟、变质岩石学和年代学研究结果,探讨板块俯冲起始到成熟阶段的热结构和变质作用差异。从俯冲起始到成熟阶段,俯冲带热结构由"热"变"冷",初始俯冲更可能形成的是角闪岩或麻粒岩,形成于热俯冲环境,以逆时针p-t轨迹为主,通常伴随板块部分熔融过程;而成熟阶段形成的主要是低温蓝片岩和榴辉岩,形成于冷俯冲环境,具有典型的顺时针p-t轨迹,以板块变质脱水为主。对俯冲带高t/p变质岩(如变质底板)的进变质过程、时间以及构造背景等方面需进一步加强研究,以获取更详实的现代板块俯冲起始阶段的地质过程。     

西藏八宿吉利地区新发现寒武纪变质花岗岩锆石U-Pb年龄、地球化学特征及其地质意义

八宿吉利地区寒武纪变质花岗岩位于曲扎湖-提卡一带,主要由变质二长花岗岩和变质花岗闪长岩组成。这一新发现对于认识和恢复原特提斯构造历史演化具有重要意义。锆石CL图像显示变质花岗岩锆石为岩浆成因。锆石LA-ICP-MS测年得出片理化变质二长花岗岩年龄为503.7±4.7Ma、变质花岗闪长岩年龄为494.7±3.4Ma,表明该岩体形成时代属于寒武纪。通过岩石地球化学分析,变质二长花岗岩SiO2含量介于69.87%~79.89%之间;变质花岗闪长岩SiO2含量介于66.63%~70.15%之间。前者Al2O3含量变化于12.36%~14.82%,Na2O含量为2.54%~7.16%,K2O含量为0.15%~5.95%,K2O/Na2O=0.02~2.34;后者Al2O3含量变化于14.66%~15.41%,Na2O含量为3.60%~5.63%,K2O含量为0.77%~2.78%,K2O/Na2O=0.14~0.77,属于钙碱性-碱性过铝质花岗岩。在侵入岩构造环境Rb-(Y+Nb)判别图解、Rb-(Yb+Ta)判别图解中,样品均落入“火山弧花岗岩”区域中,表明其形成于大陆边缘火山弧环境。结合锆石测年结果及区域地质背景分析,认为吉利地区变质花岗岩形成于冈瓦纳大陆裂离卡穷微陆块阶段,同时表明原特提斯洋形成最早时限可追溯至寒武纪。     

The duration of near‐peak metamorphism from diffusion modelling of garnet zoning

Garnet in a staurolite–kyanite zone sample from central Vermont displays a bell‐shaped Mn growth zoning with diffusional modification over the outer 100 μm. The diffusion is driven by the prograde net transfer reaction garnet + chlorite = kyanite + biotite as is evidenced by a well‐defined resorption zone on the rim. Analysis of the reaction history and resorbed garnet composition suggests that the peak temperature attained was 620–660 °C. Diffusional modelling of the rim diffusion provides an estimate of the duration of the metamorphic episode over which significant garnet diffusion occurs. The duration is a function of the assumed peak temperature and garnet diffusivities and range from a few hundred thousand years to a few million years. Such short durations require rapid tectonic burial and exhumation of relatively thin tectonic slices.     

侵入接触构造的地质力学研究

本文介绍了作者运用地质力学方法、原理并借鉴国际研究动态,涉足侵入接触构造研究获取的部分成果。基本要点包括:(1)侵入接触构造自成系统;(2)可分3种基本型式;(3)是岩体侵位动力和区域构造应力双重作用的结果;(4)控矿构造的多期活动与水压破裂相关;(5)一般所谓外接触带构造,实质为热动力变质构造.      

苏鲁超高压变质带北部地球物理调查(1)─—深反射地震

苏鲁超高压变质带是世界上研究陆一陆碰撞俯冲和壳幔作用的最佳地质场所之一．为了解超高压变质带岩石的形成、折返和相应的动力学过程,必须了解该区的地壳和浅地幔构造．本文介绍了该区北部的地质情况和进行深反射地震调查取得的成果,包括（１）在五莲─青岛断裂南侧超高压变质岩片向北倾斜,呈现叠复组构,反映岩片的折返;（２）根据地震资料推测在１４６Ｍａ前后胶南地块的隆升一伸展构造内幕;（３）超高压变质岩片厚约１２ｋｍ,由于含有大量相辉岩透镜体,地震波速高达６．８─７．３ｋｍ／ｓ;（４）莫霍面附近有许多楔形反射体,反映陆一陆碰撞;（５）石门地区７ｋｍ深处存在高波速的强反射体,可作为在该区进行大陆科学钻探的候选场址．     

Primary Product Distributions from the Reaction of OH with m-, p-Xylene, 1,2,4- and 1,3,5-Trimethylbenzene

A study was conducted to examine the OH-initiated degradation products of the four title compounds in the presence of sub-part-per-million levels of NO_x. The oxidation was conducted in a dynamic reactor to minimize the conversion of the aromatic compounds. The experiments were designed to represent reaction pathways that occur in the atmosphere at ambient NO₂ concentrations. A wide range of ring-retaining and ring-cleavage products having widely varying yields were measured during the study. For m-xylene, the major primary products observed (with molar yields) were methyl glyoxal (0.40), 4-oxo-2-pentenal (0.12), glyoxal (0.079), and m-tolualdehyde (0.049). For p-xylene, the major primary products were p-tolualdehyde (0.103), 2,5-dimethylphenol (0.13), cis-3-hexene-2,5-dione (0.176), trans-3-hexene-2,5-dione (0.045), 2-methyl-butenedial (0.071), glyoxal (0.394), and methylglyoxal (0.217). Several other reaction products were measured at yields less than 3%. The primary products for OH + 1,2,4-trimethylbenzene were found as follows: methylglyoxal (0.44), glyoxal (0.066), cis-3-hexene-2,5-dione (0.13), trans-3-hexene-2,5-dione (0.031), biacetyl (0.114), 3-methyl-3-hexene-2,5-dione (0.079), and 2-methyl-butenedial (0.045). Six other (ring retaining) products were measured at yields less than 3%. The primary products for OH + 1,3,5-trimethylbenzene were methylglyoxal (0.90), 3-methyl-5-methylidene-5(2H)-furanone (0.1), 3,5-dimethyl-3(2H)-2-furanone (0.1), 3,5-dimethyl-5(2H)-2-furanone biacetyl (0.08), and 2-methyl-4-oxo-2- pentenal (0.05). Three other products were detected at molar yields less than 5%. In some cases, the yields for the ring fragmentation products could only be based on calibrations from surrogate compounds. Yields for several of the unsaturated dicarbonyl compounds have not been reported previously while yields for methylglyoxal, glyoxal, and biacetyl are largely consistent with previous reports. Some of the primary furanone products are the identical to those reported as secondary products in aromatic systems.     

低温高压微地质体中微米纳米级矿物相研究——以大冶葡萄石中绿纤石和多硅白云母为例

低温高压地质体因与地壳碰撞、俯冲等构造活动密切相关,长期以来一直是国内外地学界关注的研究对象。但由于受研究手段、分辨能力所限,对于呈微米纳米级微粒形式存在于低温高压微地质体（即矿物）中的成分、物相及其成因等问题的研究,至今仍是地学研究中的薄弱环节。随...     

四川石棉地区前震旦纪“康定杂岩”的时代探讨

四川石棉地区的前震旦纪基底变质杂岩（“康定杂岩”） 呈断块产出,由中浅（深） 变质岩、变质侵入岩及混合岩组成。在片岩中获蓟县纪—青白口纪球藻类化石;采用锆石ＵＰｂ 法和ＰｂＰｂ 法获得变粒岩的原岩年龄为１０６７Ｍａ,变质砂岩的成岩年龄小于８５３Ｍａ,变质侵入岩的成岩年龄为８７６ ～８２８Ｍａ,混合岩的变成年龄为７１１Ｍａ,结合早震旦世岩体侵蚀混合岩,故将基底变质杂岩的时代确定为蓟县纪—青白口纪。     

Multi-stage pseudomorphic replacement of garnet during polymetamorphism: 2. Algebraic analysis of mineral assemblages

Chemical relationships among four metapelites have been studied by investigation of mineral and bulk chemistry data and by singular value decomposition analysis of single and composite assemblage matrices. Bulk rock compositions cluster close together in an AFM diagram, all within the intersection space defined by the four sample assemblages. The similarity of bulk compositions normalized on a silica-free, anhydrous basis indicates that sample chemistries differ mainly as a result of inhomogeneous distribution of quartz layers. The existence of mass balance relationships among samples indicates that assemblages also overlap in the Si–Ti–Al–Fe–Mg–Mn–Ca–Na–K multisystem. Analysis of single and composite matrices helps in defining possible mass balances linking sample mineral facies to one another during progressive contact metamorphism. The assemblage in sample A can form as the result of the model reaction 5.000  Ky+0.269 Grt+0.965 Bt+0.314 Pl=0.049 Ilm+1.115 Ms+0.849 Chl+0.306 St and react to assemblage B via reaction 0.97 Chl+0.52 Grt+0.66 Ms+0.14 Ilm+1.26  Ky=0.42 St+0.63 Bt+0.22 Pl coupled with the Ky→And transition. Assemblage B can transform into C by initial progress of Ky+Ilm+Chl+Grt+Ms=And+St+Bt+Pl followed by 0.142 Ilm+0.175 St+1.089 Chl+1.533 Ms+0.003 Grt=5.000 And+1.266 Bt+0.551 Pl Matrix analysis cannot satisfactorily model the C–D transition, because it predicts a net production of staurolite, which is in disagreement with petrographic evidence. All mass balances in the C–D composite matrix indicate net consumption of muscovite; this is integrated with the contrasting evidence of prograde pseudomorphs of muscovite after staurolite, observed in the nodules of sample D, within a model involving the progress of ionic reaction cycles.     

赣中变质岩带的Sm—Nd,Rb—Sr同位素年代研究

赣中变质岩带主要由斜长(云母)变粒岩、十字石榴云母片岩、云母石英片岩夹斜长角闪岩组成。斜长角闪岩Sm-Nd全岩等时线年龄为1113±19Ma,相当于该变质岩带的原岩形成年龄。ε_(Nd)(t)值为2.4±0.1,说明岩浆起源于亏损程度较低的地幔源区:726.6±1.1Ma、403.1±6.4Ma的Rb-Sr等时线年龄表明赣中地区在新元古代末期、加里东期经历了一次强烈的构造变质热作用,其地质、地球化学特征及时代可与浙闽地区陈蔡群、建瓯群进行对比。因此赣中变质岩带并非长期公认的华南加里东褶皱带,应是华夏地块的一部分,这一事实对华南大地构造单元的划分及构造演化具有重要意义。