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131.
Sapphirine-bearing granulites and related high-temperature metamorphic rocks from the Higo metamorphic terrane, west-central Kyushu, Japan 总被引:7,自引:0,他引:7
The Higo metamorphic unit in west-central Kyushu island, southwest Japan is an imbricated crustal section in which a sequence of units with increasing metamorphic grade from high (northern part) to low (southern part) structural levels is exposed. The basal part of the metamorphic sequence representing an original depth of 23–24 km consists mainly of garnet–cordierite–biotite gneiss, garnet–orthopyroxene gneiss, orthopyroxene-bearing amphibolite and orthopyroxene-bearing S-type tonalite. These metamorphic rocks underwent high amphibolite-facies up to granulite facies metamorphism with peak P – T conditions of 720 MPa, 870 °C. In addition sapphirine-bearing granulites and related high-temperature metamorphic rocks also occur as tectonic blocks in a metamorphosed peridotite intrusion. The sapphirine-bearing granulites and their related high-temperature metamorphic rocks can be subdivided into five types of mineral assemblages reflecting their bulk chemical compositions as follows: (1) sapphirine–corundum–spinel–cordierite (2) corundum–spinel–cordierite (3) garnet–corundum–spinel–cordierite (4) garnet–spinel–gedrite–corundum, and (5) orthopyroxene–spinel–gedrite. These metamorphic rocks are characterized by unusually high Al2 O3 and low SiO2 contents, which could represent a restitic nature remaining after partial melting of pelitic granulite under the ultra high-temperature contact metamorphism at the peak metamorphic event of the Higo metamorphic unit. The metamorphic conditions are estimated to be about 800 MPa and above 950 °C which took place at about 250 Ma as a result of the thermal effect of the regional gabbroic rock intrusions. 相似文献
132.
Autoclaves are closed vessels in which liquids can be heated above their ‘normal' boiling points. As a consequence the pressure will rise. This equipment has permitted a variety of processes like the syntheses of organics and the leaching of metal ores. Pressure technologies can be used for accelerating reactions, for specific syntheses or they offer an environmental or economical alternative for existing processes. Wet pressure oxidation of sewage sludge, an organic waste product, has become a proven technology. If less oxygen is added than stoichiometrically required for a complete oxidation, cellulose will break down by a different reaction mechanism, releasing electrons. Under these circumstances reduction of inorganic compounds is possible. 相似文献
133.
浙江景宁鹤溪群斜长角闪岩变质新生锆石特征、离子探针(SHRIMP)U-Pb年龄及地质意义 总被引:10,自引:0,他引:10
景宁鹤溪群斜长角闪岩变质新生锆石特征是粒度均匀(约70μm),晶体结晶和透明度极好,色调一致的淡粉红色,呈金刚光泽.未见裂隙、表面熔蚀、环带和核心构造。离子探针质谱GHRIMPⅡ)的206Pb/238U、207Pb/235U两组年龄在误差范围内基本谐和,206Pb/238U年龄的加权平均值(252±5Ma)为变质新生铁石的结晶年龄。锆石的精确定年(252±5Ma)为丽水—余姚断裂以东地区呈“天窗式”零星出露于中生代火山岩系中的鹤溪群提供了一个变质作用的确切年龄,也为印支运动在丽水—余姚断裂以东地区的存在提供了重要的年代学佐证。 相似文献
134.
The high-temperature and pressure experimental data of garnet, sillimantite and biotite-bearing potash feldspar gneiss (SGBG,
natural block rock) has shown that metamorphic reactions between garnet and melt, and mineral assemblage evolutional features
are not only controlled byP-T condition, but also genetically correlate with dehydration-melting of biotite and partial melting of felsic minerals. Combining
experimental data with theoretical analyses, the genetic mechanism of metamorphic reaction and its dynamic significance have
been demonstrated in the process of metamorphic evolution of khondalite series on the border of Jin (Shanxi Province)-Inner
Mongolia.
Project supported by the Youth Geologist Foundation of Ministry of Geology and Mineral Resources of China, the Post-docter
Foundation and the National Natural Science Foundation of China (Grant No. 49572138). 相似文献
135.
刘福来 《吉林大学学报(地球科学版)》1998,(1)
蔓箐沟地区石榴基性麻粒岩发育多期变质反应结构。矿物组合演化可划分三个阶段:①峰期阶段(M1),以包裹于石榴石中的Opx+Cpx±Hb+Pl±Qz和由Gt+Opx+Cpx±Hb+Pl±Qz组成基质矿物组合为代表;②退变早期近等温减压阶段(M2),形成蠕虫状后成合晶Opx+Hb+Pl±Mt;③退变晚期阶段(M3),则形成细粒、黄绿色Hb+中酸性Pl的较低温组合。并揭示该区石榴基性麻粒岩从中下部地壳的麻粒岩相变质,到快速抬升至中浅部地壳发生的近等温减压及晚期降温退变的复杂pT演化历史。 相似文献
136.
We employ spectra of resolution 20–35000 of seven SC stars, four S stars, two Ba stars and two K–M stars to derive abundances of a variety of elements from Sr to Eu relative to iron. Special attention is paid to Rb and Tc, and to the ratio of the heavy s-process species to the light s-process elements. Abundances are derived in LTE, both by using model atmospheres in which the carbon and oxygen abundances are nearly equal and by using curves of growth. Spectrum synthesis is used for critical lines such as the 5924-Å line of Tc and the 7800-Å line of Rb. For most of the heavy-element stars the enhancement of the s-process elements is about a factor of 10. The ratio of the heavy to light s-process species is not far from solar, except for RR Her for which the same ratio is +0.45 dex. For Tc the blending by other lines is severe. While we have probably detected the 5924-Å line, we can only present abundances in the less-than-or-equal-to category. For Rb, whose abundance is sensitive to the 85 Rb/87 Rb ratio and hence to the neutron density during s-process production, we find a considerable range of abundances, indicating a neutron density from 106 to ≳108 cm−3 for the SC stars. For the four S stars the range is from 107 to ≳108 cm−3 . Recent calculations by Gallino et al. show that neutron densities near 107 cm−3 favour the 13 C source for neutrons, while densities greater than 108 cm−3 may be associated with neutrons from the 22 Ne source. 相似文献
137.
138.
139.
The reaction coefficients of nitrogen dioxide and nitrous acid with monodisperse sodium chloride and ammonium sulphate aerosols have been measured in a flow reactor at atmospheric pressure. These experiments were performed at relative humidities above and below the deliquescence points of both aerosols (r.h. 50 and 85%) at 279 K. The results for NO2 afford a reaction coefficient in the range (2.8–10) × 10-4 and for HONO, (2.8–4.6) × 10-3. For both species, there appears to be an enhancement of the reaction coefficient on sodium chloride aerosol at 50% r.h. The results are compared with reaction coefficients determined by other experimental methods. A good agreement is found for both gases between this method and the coated denuder method previously developed in our research laboratories (Msibi et al., 1993) and with the majority of other published data for NO2. In the case of HONO, our estimate of reaction coefficient is smaller than, or at the lower limits of the ranges reported by other published studies. 相似文献
140.
In the Proterozoic Mary Kathleen Fold Belt, northern Australia, infiltration of large volumes of externally derived fluid occurred synchronously with regional amphibolite-facies metamorphism and deformation. This paper develops a model of structurally controlled fluid migration by comparing the distribution of fossil fluid pathways with the inferred stress and strain patterns during the deformation. Intense fluid flow was localized within strong, relatively brittle meta-intrusive bodies, and in discrete, veined, brecciated and altered zones around their margins. In metasediments folded in a ductile manner outside these areas, fluid infiltration was negligible. The direct correlation between structural styles and the magnitude of veining and metasomatism suggests control of permeability enhancement, and hence fluid flow, by deformation. Finite difference modelling of a strong body in a weaker matrix has been used to evaluate the variation of stresses during the deformation, from which it is clear that stress and strain heterogeneities have systematically influenced the development and maintenance of metamorphic fluid pathways. Particular regions in which mean stress may be significantly lower than the average lithostatic pressures include the ‘strain shadow’zones adjacent to the strong bodies, other dilatant zones around the bodies, and the bodies themselves. This geometry is favourable not only for localized brittle deformation under amphilobite facies conditions, but also for focused fluid flow in the low mean stress regions, as evidenced by the abundance of veins. Fluid access through these metamorphic aquifers occurred during tensile failure episodes, with particularly large dilations and decimetre-scale veining in areas of strain incompatibility. It appears likely that fluid circulated many times through the Fold Belt, with flow concentrated in the metamorphic aquifers. A model is developed that explains both the structurally focused fluid flow and the postulated multi-pass recirculation by dilatancy pumping, the ‘pump engines’comprising the low mean stress zones. 相似文献