金刚石界面金属碳化物过渡层强度的研究 (金刚石焊接机理研究之二)

通过对试样进行强度测试后，在高倍电镜和能谱仪上对金刚石界面金属面碳化物的微观结构和含量的观察，分析，测量其表面金属碳化物面积，计算出不同添加剂所生成的金属碳化物在不同浓度和粒度的金刚石中所生成强度的排序，从而确定不同金属碳化物及其物理力学性能的差异，为金刚石制品的生产与开发提供理论依据。     

EXAMINATION OF SILICATE LIMITATION OF PRIMARY PRODUCTION IN JIAOZHOU BAY, CHINA Ⅰ. SILICATE BEING A LIMITING FACTOR OF PHYTOPLANKTON PRIMARY PRODUCTION

Jiaozhou Bay data collected from May 1991 to February 1994, in 12 seasonal investigations, and provided the authors by the Ecological Station of Jiaozhou B ay, were analyzed to determine the spatiotemporal variations in temperature, light, nutrients (NO-3-N, NO-2-N, NH+4-N, SiO2-3-Si, PO3-4-P), phytoplankton, and primary production in Jiaozhou Bay. The results indicated that only silicate correlated well in time and space with, and had important effects on, the characteristics, dynamic cycles and trends of, primary production in Jiaozhou Bay. The authors developed a corresponding dynamic model of primary production and silicate and water temperature. Eq.(1) of the model shows that the primary production variation is controlled by the nutrient Si and affected by water temp erature; that the main factor controlling the primary production is Si; that water temper ature affects the composition of the structure of phytoplankton assemblage; that the different populations of the phytoplankton assemblage occupy different ecologica l niches for C, the apparent ratio of conversion of silicate in seawater into phytoplankton biomas and D, the coefficient of water temperature's effect on phytoplankton biomass. The authors researched the silicon source of Jiaozhou Bay , the biogeochemical sediment process of the silicon, the phytoplankton predominan t species and the phytoplankton structure. The authors considered silicate a limit ing factor of primary production in Jiaozhou Bay, whose decreasing concentration of silicate from terrestrial source is supposedly due to dilution by current and up take by phytoplankton; quantified the silicate assimilated by phytoplankton, the intrins ic ratio of conversion of silicon into phytoplankton biomass, the proportion of silicate uptaken by phytoplankton and diluted by current; and found that the primary production of the phytoplankton is determined by the quantity of the silicate assimilated by them. The phenomenon of apparently high plant-nutrient concentrations but low phytoplankton biomass in some waters is reasonably explained in this paper.     

北祁连山西段同位素测年概况

作者在广泛收集前人资料的基础上,通过课题研究工作,剔除了一些地点、岩性、测试不详及方法不系统的年龄数据,获得了一组有价值的同位素年代学数据。它们可以代表目前北祁连山西段同位素年代学研究的主要成果与认识,对研究本区盆地-构造-岩浆-热事件提供了重要成因信息。综合评价这一成果,方法较全面,数据有一定系统性,从而有力地支持了对本区各类地质体形成与演化的认识,解决在北祁连山西段科研、地质找矿以及区域地质调查中一些长期争议的地层时代问题,对推动本区成矿时代、热历史等问题研究的深入,有重要意义。     

黄色系硅化造礁石珊瑚的结构特征及颜色成因研究

近些年,黄色系硅化造礁石珊瑚以其独特的花纹和美丽的颜色受到了人们的关注和喜爱。为充分认识硅化造礁石珊瑚的结构特征及颜色成因,本文采用X射线粉末衍射仪、偏光显微镜、热场发射扫描电子显微镜、紫外-可见光分光光度计和拉曼光谱仪对3块天然黄色系硅化造礁石珊瑚进行了研究。结果表明: 所研究的硅化造礁石珊瑚空腔区与隔片区石英颗粒的形态、种类及分布特征不同。当隔片和体壁所围成的空腔或是共骨之间的空腔足够大时,沿空腔内壁到中心,石英颗粒的种类和形态从不规则的细粒→他形的中粒→他形-半自形粗粒;当空腔受到挤压时,石英颗粒主要为他形或似纤维状的细粒石英。隔片区的石英颗粒主要为细粒石英。在偏光显微镜下观察到的黄色-褐红色的矿物经证实为针铁矿和赤铁矿,其中赤铁矿是黄色系硅化造礁石珊瑚的主要致色矿物。受造礁石珊瑚骨骼结构的影响,微观上针铁矿和赤铁矿总是以色素点的方式存在于极细粒或细粒石英颗粒的间隙,宏观上富集于隔片区和空腔边缘。     

Parameter analysis for gate metal—oxide—semiconductor structures of ion-implanted 4H silicon carbide metal—semiconductor field-effect transistors

From the theoretical analysis of the thermionic emission model of current--voltage characteristics, this paper extracts the parameters for the gate Schottky contact of two ion-implanted 4H-SiC metal--semiconductor field-effect transistors (sample A and sample B for three and four times multiple ion-implantation channel region respectively) fabricated in the experiment, including the ideality factor, the series resistance, the zero-field barrier height, the interface oxide capacitance, the interface state density distribution, the neutral level of interface states and the fixed space charge density. The methods to improve the interface of the ion-implanted Schottky contact are given at last.     

河南省金属矿产资源现状及勘查战略探讨

本文在全面论述河南省金属矿产资源特点,90年代以来金属矿产勘查开发的主要成果及存在问题,以及在主要金属矿产勘查开发前景的基础上,提出了找矿勘查四大战略:即在项目安排上,要以市场对矿产品和矿权地的需求为立项的主要依据;在矿种选择上,要重点勘查金、银,注意找寻铜、铅锌,择优勘查富钼、富铝,有条件地探索富铁、富锰;在勘查选区上,要以老区扩展为主,新区开拓为辅;在技术方法上,要大力研究和应用找矿新理论、新技术、新方法,力求深部找矿有重要突破。     

铜陵地区不同景观区金属态地球化学特征

通过铜陵地区已知矿集区和覆盖区多金属态测量,不仅确定了深穿透测量在矿集区的有效指示作用,同时,根据不同景观区、不同金属态地球化学特征的对比,指出了覆盖区具指示意义的元素金属态,为长江中下游平原区寻找隐伏矿床提出了新的化探方法。     

微波消解-等离子体发射光谱法同时测定水中硅铁钠

讨论使用电感耦合等离子体发射光谱法测定水样中si、Fe、Na时，四种水样前处理方法对测试结果的影响。提出采用HNO3^-HF体系微波消解、H3BO3掩蔽HF的方法前处理水样，用等离子体发射光谱法可同时准确快速地测定水中Si、Fe、Na三种元素的含量。5次测定的相对标准偏差小于4％，加标回收率为89．2％-106％。     

硅肥对水稻镉吸收影响初探

试验表明：用炼铁水淬渣为主要原料生产的硅肥,能够抑制水稻对镉吸收。在本试验条件下,施硅肥后糙米镉含量相对下降９２％以上,稻草镉含量下降９４％。随着硅肥施用量的增加,抑制作用有增强的趋势,作者认为在镉污染不太严重的地区,施用硅肥可以防止重金属污染。     

二次熔矿方式电感耦合等离子体发射光谱法测定棕刚玉中硅铁钛钙镁锆

根据棕刚玉难熔的特点,采用二次熔矿方式对样品进行分解,经盐酸酸化的浸提液用电感耦合等离子体发射光谱法测定硅、铁、钛、钙、镁、锆的含量。第一次加入硼酸-碳酸钠(质量比2∶1)熔矿,熔剂中大量硼酸的存在可以确保棕刚玉样品无需研磨而分解完全;但所得熔融物极难提取,通过提高熔剂中碳酸钠的比例后进行第二次熔矿,使熔融物酸化浸取变得快速简单。对硼酸-碳酸钠混合溶剂的比例、熔矿温度和时间、称样量和样品粒度等实验条件进行优化,分析结果表明方法检出限为0.0003%~0.0051%,精密度(RSD,n=11)为0.88%~4.78%。用标准物质验证,测定值与标准值相符;与国标法对比验证,测定结果相符。该方法样品分解充分,对样品的粒度适应范围宽,可满足生产控制快速检测的要求。