南极涛动异常及其对冬春季北半球大气环流影响的数值模拟试验

利用IAP9L-AGCM模式考察了模式中与南极涛动异常相关的海温敏感区,发现南半球高纬海温异常能够强迫出南极涛动异常,而赤道东太平洋海温异常与太平洋南美型密切相关.研究了南极涛动异常对冬春季北半球大气环流及亚洲北部气温的影响,结果表明,南极涛动加强,能够引起北半球高纬环流异常和欧亚西风加强,以及亚洲北部地表气温和850 hPa气温显著增温.数值模拟支持了已有的诊断结果,也证实了冬春季节南极涛动异常下两半球高纬间的经向遥相关存在.     

武汉市汤逊湖沉积物重金属垂向变化的磁响应特征及环境意义

对武汉汤逊湖湖泊沉积物T06-1样芯进行了磁性测量、重金属分析和粒度分析,探讨了利用磁参数追踪、指示城市湖泊重金属污染的可行性.结果表明,低矫顽力的亚铁磁矿物主导了沉积物的磁性特征.磁参数χ,SIRM和ARM与重金属Cr,Zn,Cu和Pb呈现较为一致的垂向变化特征:55cm之下,磁参数值和重金属的含量均较低且稳定;在50～10 cm之间,两者基本呈现随深度的减小而增加的趋势,其中在20～10 cm区间,出现小范围内波动;而10cm至表层,元素含量和磁参数值随深度减小而急剧增加.选取粘土(＜4μm)对沉积物中Cr,Zn,Cu和Pb进行粒度校正的结果显示:校正后元素的变化趋向于平稳,但在表层的10cm处Cr,Pb,Zn和Cu的含量仍然较高,表明了表层沉积物中金属元素的含量主要受人类活动的影响.相关分析也表明了磁参数χ,SIRM和ARM与重金属Cr,Pb,Zn和Cu之间均呈显著相关关系(0.62≤R≤0.86),表明磁参数可以用于追踪和指示汤逊湖湖泊沉积物重金属污染.     

土壤剖面的磁学特征及其对交通污染的指示意义——以北京首都机场高速公路为例

对北京首都机场高速公路旁采集的土壤柱状T01剖面的磁学参数和金属元素分析,探讨了研究区内现代交通导致的土壤磁学性质的变化及其对环境污染的响应.结果表明,磁参数(χ,ARM和SIRM)与重金属含量呈同步垂向变化趋势.来源于交通运输排放的污染物是土壤剖面上部(0～8 cm)磁性和金属含量增强的主要原因,8cm以下,土壤基本未受到污染,磁性矿物和重金属含量较低,磁性颗粒变化稳定,基本代表了该地区土壤的自然背景.尽管土壤岩石磁学分析表明剖面上下部受污染和未受污染样品的磁载体均是粒度较粗的多畴磁铁矿,但是结合磁参数比值曲线,说明底部样品的磁颗粒的粒度较顶部偏细.磁性矿物的含量变化没有影响磁颗粒的粒度特征.指标聚类等相关分析表明,土壤磁参数(χ,ARM和SIRM)与重金属元素(Pb,Zn和Cu)含量显著相关;结合模糊聚类分析,磁参数可用于追踪、识别交通污染物质在土壤剖面中的富集、迁移状态,揭示不同深度土壤的污染程度.     

灌河口潮滩重金属累积特征及污染评价

河口地区潮滩是重金属重要的"汇"。测定了灌河口(燕尾港)潮滩高中低滩的33个表面样粒度、重金属数据,研究了4根柱状样的重金属和粒度特征,利用地累积指数法、潜在生态危害指数法及富集指数法等评价指标,对灌河口重金属的污染状况进行了评价,并对其结果进行了相互比较和印证。分析结果显示,灌河口潮滩重金属的分布主要受水动力影响,特别是受粘土分布的控制。Cd与粒径Ф值相关性不显著,相关系数只有0.099,而与粘土含量呈明显正相关关系,Hg的变化趋势恰恰相反,其含量随着距离河口距离的加大反而有增加的趋势;其他元素的变化趋势不明显。重金属元素Zn、Pb、Cu、Hg含量变化走势基本相同,用Li作归一化标准元素归一化后,所有重金属元素的归一化值变化波动范围均比重金属含量值明显收窄,波峰和波谷有后延的趋势。灌河口滩涂总体重金属环境尚可,但存在一定程度的Hg、Cu污染富集。柱状样Hg、Cu的地累积污染指数总体上均呈现随深度增加而降低的趋势。     

湖南仁里稀有金属矿床岩相学和矿物学特征及其地质意义——以5号脉ZK708号钻孔为例

仁里矿床是中国近年新发现的超大型花岗伟晶岩型稀有金属矿床,文章针对其稀有金属矿化富集规律、成岩成矿演化特征及找矿标志等问题,以5号主矿脉钻孔ZK708全孔岩芯及岩体内、外伟晶岩为研究对象,采用了电子探针、能谱仪分析和全岩地球化学分析等方法,开展了伟晶岩岩相学、矿物学及地球化学等方面的研究工作.研究结果表明:①仁里矿床伟...     

特征变量选择结合SVM的耕地土壤Hg含量高光谱反演

为探讨应用高光谱数据反演耕地土壤重金属汞(Hg)含量,对原始光谱进行10 nm重采样和SG平滑处理,用不同光谱变换数据与土壤重金属Hg含量进行相关性分析,采用IRIV、Random Frog和PCC提取光谱特征波段,分别建立SVM与GWO-SVM土壤Hg含量高光谱反演模型,获取Hg含量最优反演路径。研究表明,一阶微分变换光谱后土壤光谱特征更明显;上述特征提取方法在不同程度上减少光谱数据冗余,保留有效变量信息;经灰狼算法优化后支持向量机模型反演精度提高,IRIV结合GWO-SVM预测精度更高,其验证集R²为0.894,RMSE为0.082,MAE为0.016。研究成果可为类似土壤重金属含量的反演提供借鉴。     

Parallelization of the distinct lattice spring model

The distinct lattice spring model (DLSM) is a newly developed numerical tool for modeling rock dynamics problems, i.e. dynamic failure and wave propagation. In this paper, parallelization of DLSM is presented. With the development of parallel computing technologies in both hardware and software, parallelization of a code is becoming easier than before. There are many available choices now. In this paper, Open Multi‐Processing (OpenMP) with multicore personal computer (PC) and message passing interface (MPI) with cluster are selected as the environments to parallelize DLSM. Performances of these parallel DLSM codes are tested on different computers. It is found that the parallel DLSM code with OpenMP can reach a maximum speed‐up of 4.68× on a quad‐core PC. The parallel DLSM code with MPI can achieve a speed‐up of 40.886× when 256 CPUs are used on a cluster. At the end of this paper, a high‐resolution model with four million particles, which is too big to handle by the serial code, is simulated by using the parallel DLSM code on a cluster. It is concluded that the parallelization of DLSM is successful. Copyright © 2011 John Wiley & Sons, Ltd.     

Correlation between geochemical environments and controlling factors in the metallation of porphyrins

Experimental study on metallation of tetrapyrroles in biphasic systems showed that complexation with metal cations of the first transition series is a feasible under chemical environments similar to the naturally occurring ones. The metal transport from the aqueous media to the organic, which is a novel approach using naturally occurring fatty acids hydroxy aromatic compounds and thiols, is demonstrated. Selectivity between Ni²⁺ and VO²⁺ complexation is achieved under sulfurous rich conditions. The kinetic implications are discussed in view of their geoenvironmental applicability.     

H~+对Cu~(2+)—Me~(2+)二元体系吸附的影响规律研究

土壤对重金属离子的吸附容量严格受H~+浓度的控制。本文通过试验探讨了H~+ 对Cu~(2+)——Pb~(2+),Cn~(2+)——Zu~(2+),Cu~(2+)——Hg~(2+)系统中Cu~(2+)吸附量的影响规律。当pHpH时,Cu~(2+)吸附量随pH值增大而减小。对于酸性土,pH=6.5(初始值)或7.0(平衡值),对碱性土,pH=5.5(初始值)或7.8(平衡值)。在pHpH_(ZPC)时,吸附模式具有完全不同的形式。     

Computational methods for fitting statistical distribution models of multi-site binding equilibria

Statistical distribution models of multi-site binding equilibria have potential applicability in the study of acid-base and metal complexation chemistry of humic substances in soils, sediments, and natural waters. A mathematical derivation is presented for the general continuous model for the case of proton binding; computational methods are described for fitting numerically the parameters in such models. Among models considered are those based on nontruncated, truncated, and bimodal (mixed) distributions. Specific emphasis is placed on Gaussian distribution models.