Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins

The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log α_M(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 10²⁰ M^− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log α_M(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.     

南沙海区中生界岩相分布及构造特征

为了了解南中国海南部南沙群岛陆架-陆坡区中生代地层发育情况,作者通过综合分析该海区钻井、拖网及1987年以来采集的20000多公里的多道反射地震勘探等资料,得到了对该区中生界基本特征的如下新认识:空间分布上,南沙的中生界具有从北部的郑和-礼乐隆起南缘向南增厚的趋势;沉积岩相方面,东部三叠纪时为深海相,侏罗纪为浅海与三角洲相,白垩纪为浅海-内浅海相,而往西南部中生代的海水深度有变深的趋势;中-新生代变形上,在南沙西部的曾母盆地,中生界褶皱为复式的、非协调性的,南沙中部多为舒缓褶皱,东部仅在近巴拉望海槽地带出现小幅度的褶皱。结合围区中生界及特提斯构造域的发育特征,作者提出南沙地块上的海相中生界在大地构造上归属于残留在中特提斯洋北部减薄陆缘地壳上的中特提斯期海相沉积地层,是该海域油气资源勘探不可忽视的对象。     

Bioenhancement of cadmium transfer along a multi-level food chain

Previous studies have shown that metal partitioned to a subcellular compartment containing trophically available metal (TAM) is readily available to predators and may be enhanced by increased binding of metal to heat-stable proteins (HSP - e.g., metallothioneins). The aim of the current investigation was to determine the influence of TAM on the trophic transfer of Cd along an experimental, three-level food chain: Artemia franciscana (brine shrimp)-->Palaemonetes pugio (grass shrimp)-->Fundulus heteroclitus (mummichog). P. pugio were fed for 7 days on A. franciscana exposed to Cd in solution (including (109)Cd as radiotracer) and subjected to subcellular fractionation or fed to F. heteroclitus. An HSP-driven increase in the percentage of Cd associated with TAM (TAM-Cd%) in A. franciscana exposed to 1 muM Cd resulted in a bioenhancement (i.e., a greater than linear increase with respect to A. franciscana exposure) of Cd trophic transfer to P. pugio. Increased dietary Cd exposure did not affect TAM-Cd% in P. pugio nor trophic transfer to F. heteroclitus.     

广东红海湾、珠江口及电白—阳江近海第四纪沉积

根据物探和钻探资料，研究区内第四纪沉积物可分为两部分，下部地震反射结构复杂，斜层理发育，粒度较粗，为晚更新世产物；上部的地震反射结构简单，呈水平状或近水平状结构，粒度较细，为全新世沉积。     

SYF1-1型海洋金属防腐装置

SYFl—1型海洋金属防腐装置是一种用于潮汐发电设备、海洋石油平台、输送海水管道、船舶等海洋金属防腐的装置。文中对该装置的工作原理、组成、主要技术性能、特点以及实现方法作了概要描述。     

近1300年来古胶州港位置的变迁

本文主要依据有关方志、文史资料，着重考证了近１３００年来古胶州港位置的变迁，研究发现，古胶州港的位置自唐代至清末近１３００年间，沿胶州湾西、北岸大致经历了７次变更，特别自明代开始，港口位置变迁尤为频繁，作者初步分析认为这与历史时期胶州湾内西、北岸的不断淤涨和胶莱南河、大沽河口的冲淤作用有关。     

救荒野豌豆对污染土壤中Cd的富集特征

研究了Cd单一和Cd、Zn复合污染对救荒野豌豆(Vicia Sativa L)生长及吸收富集重金属元素Cd的影响.以武汉市郊某蔬菜基地的农田土为试验土壤,分别加入5种质量分数的Cd(5,20,50,100,200 mg/kg),Zn的添加质量分数为150 mg/kg,模拟污染土壤进行盆栽试验,每盆移栽生长一致、数量相同的植株幼苗.结果表明:植株根、茎、叶、豆中的w(Cd)随着土壤中w(Cd)的增加而增加,且根＞茎＞叶＞豆.当土壤中的w(Cd)=5 mg/kg时,根部的富集系数达到了17.18.但是,随着w(Cd)的增加,富集系数逐渐减小.在Cd、Zn复合污染的情况下,植物对Cd、Zn的吸收存在着协同效应,尤其是根部对镉的吸收有显著的提高.救荒野豌豆不仅能在高含量的镉污染土壤中正常生长,而且其根部的w(Cd)要远远大于地上部分,说明它是一种镉的排异植物.     

应用于砂岩型铀矿找矿的遥感-航测信息集成模型构建

应用遥感-航测(航放和航磁)信息集成技术,针对砂岩型铀矿找矿的几个重要条件:如盆地内部构造、含矿目的层、水文条件和矿化条件,构建了构造、岩性、水文和矿化4种信息集成模型.将这4种信息集成模型应用于示范区,在已知的矿化地段得到的结果与实际勘探的成果符合较好,提高了预测的准确性.     

外生铀矿成矿系统研究与古水动力分析

分析了砂岩型铀矿的国内外研究现状和发展趋势,尝试从成矿系统演化论的角度提出新的研究思路：即,以系统观为指导,以物质迁移的动力学为主线,从区域地质背景演化,特别是构造动力演化、岩相古地理等方面入手,恢复矿前期、成矿期、矿后期的区域古地形格局。运用融入了地下水流动系统理论的古水文地质分析方法,重建区域演化进程中各地质时期的古流场。着重从区域尺度上研究矿质的源-迁移-汇（成矿）-保存的动力学过程。