川西甲基卡烧碳沟地区伟晶岩脉地球化学特征

通过对烧碳沟地区伟晶岩的岩石学特征及地球化学特征进行分析,探讨了其成矿构造背景及物质来源等成矿地质条件.结果表明:烧碳沟一带伟晶岩的SiO2含量为73.46％～75.96％,全碱含量为4.71％～7.36％,里特曼指数为0.70～1.84,反映了伟晶岩的钙碱性特征;铝饱和指数A/CNK 为1.54～2.49,全部大于1...     

Chronology and Geochemistry of Volcanic Rocks in the Cretaceous Suifenhe Formation in Eastern Heilongjiang, China

Zircon U-Pb ages and geochemical data of volcanic rocks in the Suifenhe Formation in eastern Heilongjiang Province are reported, and their petrogenesis is discussed in this paper. The Suifenhe Formation mainly consists of basalt, andesite, and dacite. Zircon from andesite and dacite are euhedral in shape and show typical oscillatory zoning with high Th/U ratios (0.18-0.57), implying its magmatic origin. Zircon U-Pb dating results by laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) indicate that the 206Pb/238U ages of zircons from andesite range within 105-106 Ma, yielding a weighted mean age of 105.5±0.8 Ma (n=14), and that 206Pb/238U ages of zircons from dacite are between 90-96 Ma, yielding a weighted mean age of 93.2±1.3 Ma (n =13). The volcanic rocks from the Suifenhe Formation are subalkaline series and show a calc-alkaline evolutionary trend with SiO2 content of 47.69%-65.47%, MgO contents of 1.42%-6.80% (Mg#= 45-53), and Na2O/K2O ratios of 1.83-3.63. They are characterized by enrichment in large ion lithophile elements (LILE) and light-rare-earth elements (LREE), depletion in heavy rare earth elements (HREE) and high field strength elements (HFSE) (e.g., Nb, Ta, Ti), and low initial 87Sr/86Sr ratios (0.7041-0.7057) and positiveεNd(t) values (039-4.08), implying that they could be derived from a depleted magma source. Taken together, these results suggest that the primary magma of the volcanic rocks might originate from partial melting of the mantle wedge metasomatized by fluids derived from subducted slab under a tectonic setting of active continental margin.     

兴安地块南段晚泥盆世包格德岩体时代的厘定及地质意义

中亚造山带东端兴安地块南段的包格德岩体由石英二长岩、二长花岗岩和花岗斑岩3种岩性组成,岩体锆石LA-ICP-MS U-Pb定年结果分别为368±+1 Ma、364±1 Ma、355±1 Ma,为晚泥盆-早石炭世岩浆活动的产物;岩体的(Na2O+K2O)含量为7.62％～8.82％,K2O/Na2O值为0.93～4.21...     

熔体结构与酸性熔岩的某些特征

在流纹质岩浆中,存在两种不混溶的熔体,一种熔体富SiO_2贫FeO,另一种则相反。从熔体结构的角度看,前一种熔体富桥氧,后者则富自由氧。水的解聚作用可以改变流纹质岩浆的结构,即降低它的聚合程度,因此,含水流纹岩浆的粘度低于玄武岩浆的粘度,从而使流纹岩中流纹构造发育。 实际工作中应避免混淆流纹岩与酸性熔结凝灰岩。     

The Partitioning of Tungsten bwtween Aqueous Fluids and Silicate Melts

An experimental study has been carried out to determine the partition coefficients of tungsten between aqueous fluids and granitic melts at 800 °C and 1.5 kb with natural granite as the starting material. The effects of the solutions on the partition coefficients of tungsten show a sequence of P > CO ₃ ²⁻ > B > H₂O. The effects are limited (generallyK _D < 0.3) and the tungsten shows a preferential trend toward the melt over the aqueous fluid. The value ofK _D increases with increasing concentration of phosphorus; theK _D increases first and then reduces with the concentration of CO ₃ ²⁻ when temperature decreases, theK _D between the solution of CO ₃ ²⁻ and the silicate melt increases, and that between the solution of B₄O ₇ ²⁻ and the silicate melt decreases. The partition coefficients of phosphorus and sodium between fluids and silicate melts have been calculated from the concentrations of the elements in the melts. TheK _D value for phosphorus is 0.38 and that for sodium is 0.56. Evidence shows that the elements tend to become richer and richer in the melts.     

铼－锇同位素体系在基性—超基性岩中应用现状的综述

综述了该同位素体系晚侏罗世以来，尤其是现代地幔岩石的研究成表明，地幔在晚侏罗世以来在１８７Ｏｓ／１８６Ｏｓ比值方面显示出非均一性，其比值从０．９０～１．２６，但此类岩石的１８７Ｏｓ／１８６Ｏｓ比值分别与各个不同研究者所确定的地幔演化线相一致；来自较古老正常地幔或贫化地幔的岩石，在锇同位素方面体现为１８７Ｏｓ／１８６Ｏｓ初始比值接近或低于Ｒｅ－Ｏｓ同位素体系地幔演化线值。在此类岩石中，Ｒｅ－Ｏｓ同位素体系与Ｓｍ－Ｎｄ同位素体系之间存在着三种可能的关系：①正相关关系；②负相关关系；③无相关关系。据认为，第一种关系是由羽状地幔端元和富集亲石元素而且贫铼之次大陆型岩石圈地幔端元混合而成；第二种关系则是由羽状地幔端元与地壳物质混合而成；第三种关系则是锇同位素成分相同但钕同位素成分明显不同的两端元物质混合而成。在第三方面，有古老俯冲大洋壳物质参与之基性－超基性岩石具有高于地幔演化线的初始１８７Ｏｓ／１８６Ｏｓ比值。具有此种锇同位素成分特征的岩石包括大洋岛弧玄武岩（ＯＩＢ）、洋中脊玄武岩（ＭＯＲＢ）以及榴辉岩。①     

钨、锡流-熔分配实验结果及其矿床成因意义

本文用实验确定了钨、锡在成分不同的花岗质熔体相与共存水热流体相的流-熔分配系数(D_(Me)~(V/L))及其与介质溶液(NaF,KF,HF,NaCl等水溶液)摩尔浓度间的函数关系。实验结果表明,钨、锡的分配行为明显不同。在相同条件下,随体系的不同,D_W~(V/L)比D_(Sn)~(V/L)大几倍至二十倍。钠和钾对钨、锡的流-熔分配行为的影响基本相同,而氟和氯对钨、锡的分配行为的影响相差甚远,花岗质熔体的主成分对D_W~(V/L)和D_(Sn)~(V/L)有复杂的影响。利用这些结果探讨与花岗岩有关的钨、锡矿床的成矿机理,得出了一些与前人不同的新认识。     

核爆炸玻璃、撞击玻璃和玻璃陨石源岩

本文根据核爆炸岩石熔融玻璃的地球化学研究结果,与超速陨石撞击坑的熔岩进行比较,获得在远离热力学平衡条件下,各种玻璃和熔岩在化学成分上分布十分均匀的重要结论。岩石玻璃和熔岩是由基岩各组成岩石按一定比例混合熔融形成的。它们的主量元素和痕量元素丰度受基岩元素背景值制约。文中根据熔体和靶岩的化学成分,计算了熔岩各组成岩石的百分比。玻璃陨石是地壳岩石受撞击熔融形成的。同一撒布区的玻璃陨石化学成分相近,说明起源于同一源坑;而玻璃陨石化学成分的不同,则说明母岩组成分量的差异。因此,文中通过模拟计算,得出各玻璃陨石的组成源岩。澳大利亚撒布区的玻璃陨石,Al₂O₃,K₂O 和Na₂O 与 SiO₂及 K₂O/Na₂O 比值不完全相同,说明澳大利亚撒布区存在着几个不同的源岩和源坑,至少有印支、爪哇、菲律宾和澳大利亚四个相应撞击坑。     

Gold-bearing rocks of Mangalur greenstone belt,Gulbarga District,Karnataka

The Mangalur greenstone belt of Dharwar Craton, South India, is an Archaean schist belt dominated by metavolcanic rocks. The gold mineralization occurs within the metavolcanics and the fabric, mineralogy and geochemistry of these host rocks indicate that they were tholeiitic basalts regionally metamorphosed under medium to low-grade greenschist facies. The basic metavolcanic rocks occur as tholeiitic metabasalts and amphibolites. The rocks have undergone some fractionation and appear to be derived from melts generated by 10 to 25% melting of the mantle at depths 30 to 35 km around temperature 1200°C and pressure 12 kb. The source of gold is mainly in the basalts and not in the surrounding granites.     

Three mechanisms of ore re-mobilisation during amphibolite facies metamorphism at the Montauban Zn–Pb–Au–Ag deposit

The relative importance of mechanical re-mobilisation, hydrothermal dissolution and re-precipitation, and sulphide melting in controlling redistribution of metals during concurrent metamorphism and deformation is evaluated at the middle amphibolite facies Montauban deposit in Canada. As at many other deposits, ductile deformation was important in driving mechanical re-mobilisation of massive sulphides from limb regions into hinge regions of large-scale folds and is thus the most important for controlling the economics of Pb and Zn distribution. Two possible stages of hydrothermally driven re-mobilisation are discussed, each of which produces characteristically different alteration assemblages. Prograde hydrothermal re-mobilisation is driven by pyrite de-sulphidation and concurrent chlorite dehydration and is thus an internally driven process. At Montauban, the H₂S-rich fluid generated through this process allowed re-mobilisation of gold into the wall rock, where it was deposited in response to sulphidation of Fe Mg silicates. Retrograde hydrothermal re-mobilisation is an externally driven process, whereby large volumes of fluids from outside the deposit may dissolve and re-precipitate metals, and cause hydration of silicate minerals. This second hydrothermally driven process is not recognised at Montauban. Sulphide melting occurred as temperatures neared the peak metamorphic conditions. Melting initiated in the massive sulphides through arsenopyrite breakdown, and a small volume of melt was subsequently re-mobilised into the wall rock. Trace element partitioning and fractional crystallisation of this melt generated a precious metal-rich fractionate, which remained mobile until well after peak metamorphism. Thus, prograde hydrothermal re-mobilisation and sulphide melting were the most important mechanisms for controlling the distribution of Au and Ag.