Extreme value theory based on the r largest annual events: a robust approach

In Smith (1986, J. Hydrol. 86, 27–43), a family of statistical distributions and estimators for extreme values based on a fixed number r > = 1 of the largest annual events are presented. The method of estimation was numerical maximum likelihood. In this paper, we consider the robust estimation of parameters in such families of distributions. The estimation technique, which is based on optimal B-robust estimates, will assign weights to each observation and give estimates of the parameters based on the data which are well modeled by the distribution. Thus, observations which are not consistent with the proposed distribution can be identified and the validity of the model can be assessed. The method is illustrated on Venice sea level data.     

国内外PMP/PMF的发展和实践

对20世纪80年代以来PMP／PMF在国内外的发展和实践情况作了简要的介绍和评论。内容包括PMP／PMF定义、估算方法、成果合理性检查和概率。PMP估算方法包括概化估算法、当地暴雨放大、暴雨移置、暴雨组合、推理模式和统计估算法。PMF估算着重介绍了由PMP转化为PMF的产流和汇流特点，以及目前在南非和法语非洲国家广泛应用的经验公式。     

Space-time mapping of soil salinity using probabilistic bayesian maximum entropy

The mapping of saline soils is the first task before any reclamation effort. Reclamation is based on the knowledge of soil salinity in space and how it evolves with time. Soil salinity is traditionally determined by soil sampling and laboratory analysis. Recently, it became possible to complement these hard data with soft secondary data made available using field sensors like electrode probes. In this study, we had two data sets. The first includes measurements of field salinity (EC_a) at 413 locations and 19 time instants. The second, which is a subset of the first (13 to 20 locations), contains, in addition to EC_a, salinity determined in the laboratory (EC_2.5). Based on a procedure of cross-validation, we compared the prediction performance in the space-time domain of 3 methods: kriging using either only hard data (HK) or hard and mid interval soft data (HMIK), and Bayesian maximum entropy (BME) using probabilistic soft data. We found that BME was less biased, more accurate and giving estimates, which were better correlated with the observed values than the two kriging techniques. In addition, BME allowed one to delineate with better detail saline from non-saline areas.     

沈阳近百年的温度变化特征及其环流形势分析

沈阳地处全球温度变化的敏感带，在近百年的温度观测记录中，沈阳的温度变化呈逐渐上升之势，近百年增高约1．7℃，这种上升趋势在冬季远比夏季明显。沈阳的年平均温度变化有一个12a的周期，各周期温度基本呈阶梯状上升，20世纪末的周期冬季平均温度比世纪初的周期升温2．8℃左右。从近50a的极端温度的变化趋势来看，极端最低温度明显升高，而极端最高温度并没有上升，变化趋势甚至略下降，以致冬、夏两季温差缩小。从沈阳的最低平均温度和最高平均温度变化来看，两者均随时间逐渐升高，说明沈阳市的增温不仅是最低温度升高造成的，最高温度的增温作用亦十分重要。从冬季环流形势分析来看，东亚大槽及其后弱脊和地面蒙古高压在上世纪80年代、90年代明显减弱，使得冷空气向南侵袭的径向气流减弱，是导致位于冷空气通道中的沈阳冬季增温明显的原因之一。     

河流调整中的熵、熵产生和能耗率的变化

河流是一个真正的开放系统,而不是孤立系统或封闭系统。运用经典热力学和非平衡态热力学基本原理,分析研究了河流调整中的熵、熵产生和能耗率的变化。指出:熵和熵产生是两个不同的概念;最小熵产生原理等价于最小能耗率原理;冲积河流在调整过程中遵循最小熵产生原理或最小能耗率原理,而不是最大熵原理。     

The structural role of Ti in aluminosilicate liquids in the glass transition range: insights from heat capacity and shear viscosity measurements

The shear viscosities and 1 bar heat capacities of glasses and melts along the 67mol% silica isopleth in the system SiO₂-Al₂O₃-Na₂O-TiO₂ have been determined in the temperature ranges 780-1140 K and 305-1090 K respectively. Anomalous behaviour of both these properties is observed for compositions rich in TiO₂ and/or Al₂O₃, an observation attributed to liquid-liquid phase separation followed by anatase crystallization. For samples which do not show anomalous behaviour, it is found that the partial molar heat capacity of the TiO₂ component previously determined in Al-free compositions reproduces our heat capacities to within 1.3%. Viscosity data show that addition of TiO₂ tends to increase viscosity and melt fragility at constant temperature. Furthermore, heat capacity and viscosity data may be combined within the framework of the Adam-Gibbs theory to extract values of the configurational entropy of the liquids and qualitative estimates of the variation of the average energy barrier to viscous flow. Configurational entropy at 900K is inferred to decrease upon addition of TiO₂, in contrast to previous results from Al-free systems. The compositional limit separating normal from anomalous behaviour, as well as the data for homogenous melts have been used to constrain the structural role of Ti in these samples. Our data are consistent with a majority of Ti in five-fold coordination associated with a titanyl bond, in agreement with previous spectroscopic studies. Furthermore, we find no evidence for a Ti-Al interaction in our samples, and we are led to the conclusion that Al and Ti are incompletely mixed, a hypothesis consistent with the observed reduction of configurational entropy upon addition of TiO₂, suggesting an important role of medium range order in controlling the variations in thermodynamic properties.     

用L-曲线法确定岭估计中的岭参数

运用L 曲线法来确定岭估计中的岭参数 ,推导了用L 曲线法确定岭参数的基本公式 ,在此基础上实现了其算法 ,并用两个算例 ,比较了新方法和以往方法。结果表明 ,L 曲线法不仅容易收敛 ,而且其计算结果的精度较高     

Establishment of apparent quantum yield and maximum ecosystem assimilation on Tibetan Plateau alpine meadow ecosystem

The alpine meadow is widely distributed on the Tibetan Plateau with an area of about 1.2×106kn2. Damxung County, located in the hinterland of the Tibetan Plateau, is the place covered with this typical vegetation. An open-path eddy covariance system was set up in Damxung rangeland station to measure the carbon flux of alpine meadow from July to October,2003. The continuous carbon flux data were used to analyze the relationship between net ecosystem carbon dioxide exchange (NEE) and photosynthetically active radiation (PAR), as well as the seasonal patterns of apparent quantum yield (α) and maximum ecosystem assimilation (Pmax).Results showed that the daytime NEE fitted fairly well with the PAR in a rectangular hyperbola function, with α declining in the order of peak growth period (0.0244 μmolCO2 · μmol-1pAR) ＞early growth period ＞ seed maturing period ＞ withering period (0.0098 μmolCO2 · μmol-1pAR).The Pmax did not change greatly during the first three periods, with an average of 0.433mgCO2· m-2· s-1, i.e. 9.829 μmolCO2· m-2· s-1. However, during the withering period, Pmax was only 0.35 mgCO2 · m-2 · s-1, i.e. 7.945 μmolCO2 · m-2 · s-1. Compared with other grassland ecosystems, the α of the Tibetan Plateau alpine meadow ecosystem was much lower.     

Entropy Analysis of Multiple Scale Causality and Qualitative Causal Shifts in Spatial Systems*

Spatial systems are typically characterized by multiple controlling factors and processes operating at different spatial and temporal scales (multiple scale causality [MSC]). An entropy decomposition‐based approach to MSC is presented here in two contexts. First, given maps or distributions of an observed phenomenon at two or more scales, the contribution at more local or global (relative to the primary scale of observation) controls to the observed entropy can be estimated. Second, a theoretical treatment of the entropy decomposition equations shows that as the range of scale is increased by broadening or narrowing resolutions or by incorporating more controls, the influence of larger or smaller‐scale influences not only changes, but may change qualitatively, e.g., in terms of having positive (entropy‐increasing) or negative (information‐increasing) effects. Such qualitative causal shifts have implications for efforts to use any single causal explanation across the molecular to planetary spatial and instantaneous to geological range of scales relevant to physical geography. The entropy decomposition method is illustrated with an application to soil landscapes in the Ouachita Mountains, Arkansas.     

Modeling the influence of settling velocity on cohesive sediment transport in Tanshui River estuary

Settling velocities of suspended cohesive sediment in estuaries vary over a range of several orders in magnitude. Variations in the suspended sediment concentration are often considered as the principal cause. Turbulence and the suspended sediment concentration, as well as other factors such as salinity, dissolved organic substances, flocculation ability, and the rate of floc growth affect setting velocities. A laterally–averaged finite difference model for hydrodynamics and cohesive sediment transport is developed and applied in the Tanshui River estuary, Taiwan. The model has been calibrated and verified with water surface elevation, longitudinal velocity, salinity, and cohesive sediment measured. The overall performance of the model is in qualitative agreement with the available data. The model is used to investigate the influence of settling velocity on cohesive sediment transport dynamics. The simulation indicates that the turbidity maximum zone is near Kuan–Du. When settling velocities increase the surface cohesive sediment concentration at Kuan–Du station trends to decrease and bottom cohesive sediment concentration increases. Both surface and bottom cohesive sediment concentrations decrease at Taipei Bridge and Pa–Ling Bridge. This implies that suspended sediment advected seaward and deposited. There is consequently a net seaward flux of suspended sediment near surface, and a net landward flux near the bed.