90年代世界贸易发展及空间格局变化的新特点

在世界贸易组织、日趋强烈的开放的区域主义倾向、跨国公司强劲的直接投资影响下，世界贸易正在经历着巨大变化，处在一个新的转换时期。本文从影响当今世界贸易发展的多重因素分析，揭示90年代世界贸易增长、内容结构以及空间格局发展变化的新特征，并展望世界贸易的未来发展。     

The Silurian of Gotland (Sweden): facies interpretation based on stable isotopes in brachiopod shells

The Silurian of Gotland, Sweden, consists of 440 m of carbonate deposits. Repeatedly, uniform sequences of micritic limestones and marls are interrupted by complex-structured reefs and by adjacent platform sediments. Generally, the alteration of facies is interpreted as the result of sea-level fluctuations caused by a gradual regression with superimposed minor transgressive pulses. The purpose of this study is a facies interpretation based on both field observations and stable isotope measurements of brachiopod shells. Approximately 700 samples from stratigraphically arranged localities in different facies areas have been investigated. The carbon and oxygen isotopes show principally parallel curves and a close relationship to the stratigraphic sequence. Lower values occur in periods dominated by deposition of marly sequences. Higher values are observed in periods dominated by reefs and extended carbonate platforms. The oxygen isotope ratios are interpreted to reflect paleosalinity changes due to varying freshwater input, rather than to paleotemperature. Carbon isotope ratios are believed to have been connected to global changes in the burial of organic carbon in black shales during periods of euxinic deep water conditions. Consequently, the facies succession on Gotland results from global paleoclimatic conditions. Changes in terrigenous input due to different rates of weathering and freshwater runoff, rather than sea-level fluctuations, control the carbonate formation of the Silurian on Gotland.     

铜陵地区老鸦岭层状钼矿床铅同位素组成研究

安徽铜陵老鸦岭矿床中二叠系大隆组(P2d)顶部的含矿(钼矿化)黑色页岩以及附近(立新煤矿)同一层位不含矿黑色页岩的实测铅同位素组成分别为：^206Pb/^204Pb20.20～22.37,^207Pb/^204Pb15.67～15.82,^208Pb/^204Pb38.47～38.60和^206Pb/204Pb18.83～20.80,^207Pb/^204Pb15.65～15.76,^208Pb/^204Pb38．84～39．22。对137Ma的放射成因Pb进行校正后的铅同位素组成表明，含矿黑色页岩和不含矿黑色页岩均与燕山晚期火成岩无关，老鸦岭含矿黑色页岩可能具沉积成因。对沉积(约250Ma)以来的放射成因Pb进行校正后的铅同位素组成表明：不含矿黑色页岩的Pb源自上地壳，而含矿黑色页岩的Pb(因而推测其他成矿金属)可能源于上地壳物质(与不含矿黑色页岩的Pb源相似)与下地壳物质的混合。     

南秦岭十里坪锑矿床成矿时代及成因的初步研究

十里坪锑矿床受赵川陆缘隆_滑构造的主滑脱拆离带的控制。矿体呈脉状赋存于韧_脆性主滑脱带上部的脆性次级断层_节理中,矿石类型主要为萤石石英辉锑矿型。围岩为太古宙_元古宙变质岩系,围岩蚀变弱。成矿流体属H2O_CO2_NaCl体系,流体包裹体盐度w(NaCleq)为3.6%～11.3%,均一温度为109～232℃,形成压力大致为800×105Pa。硫、铅同位素研究表明,矿质主要来源于变火山岩围岩;氢、氧同位素显示,成矿流体以大气降水为主,初步将该矿床定为变质岩源就地式大气降水热液矿床。矿石中萤石Sm_Nd等时线年龄为(392±24)Ma,与南秦岭北部晚古生代拗陷区热水喷流_沉积成矿时代相一致,它们都形成于秦岭微板块泥盆纪非造山裂解阶段。     

双剪统一强度准则改进及其在岩土工程中的应用

在分析Mohr-Coulomb强度准则和双剪统一强度准则的基础上,提出了主剪面应力对和主剪面应力对的作用这2个新概念,并以此为出发点,通过考虑十二面体单元主剪面上所有3个主剪面应力对的共同作用,在双剪强度准则的基础上提出了一个新准则,并对其作了极限线分析.应用该新强度准则研究了静水压力条件下圆形巷道围岩弹塑性分析和土压力计算问题.研究表明,该准则不仅能较好地非线性反映岩土的3个基本强度特征,还解决了双剪统一准则中存在的双重破坏角问题.     

A Reflection on Mg, Cd, Ca, Li and Si Isotopic Measurements and Related Reference Materials

This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis.     

Vegetation dynamics during the late Pleistocene in the Barreirinhas region, Maranhão State, northeastern Brazil, based on carbon isotopes in soil organic matter

The study place is in the Barreirinhas region, Maranhão State, northeastern Brazil. A vegetation transect of 78 km was studied among four vegetation types: Restinga (coastal vegetation), Cerrado (woody savanna), Cerradão (dense woody savanna), and Forest, as well as three forested sites around Lagoa do Caçó, located approximately 10 km of the transect. Soil profiles in this transect were sampled for δ¹³C analysis, as well as buried charcoal fragments were used for ¹⁴C dating. The data interpretation indicated that approximately between 15,000 and ∼9000 ¹⁴C yr B.P., arboreal vegetation prevailed in the whole transect, probably due to the presence of a humid climate. Approximately between ∼9000 and 4000-3000 ¹⁴C yr B.P., there was the expansion of the savanna, probably related to the presence of drier climate. From ∼4000-3000 ¹⁴C yr B.P. to the present, the results indicated an increase in the arboreal density in the area, due to the return to a more humid and probably similar climate to the present. The presence of buried charcoal fragments in several soil depths suggested the occurrence of palaeofires during the Holocene. The vegetation dynamic inferred in this study for northeastern Brazil is in agreement with the results obtained in areas of Amazon region, based on pollen analysis of lake sediments and carbon isotope analysis of soil organic matter (SOM), implying than similar climatic conditions have affected these areas during the late Pleistocene until the present.     

基于GPS掩星技术反演大气参数模型的优化

准确掌握地球大气中的水气分布，了解水气变化趋势对天气现象、全球气候变化、数值预报具有理论研究及实用价值。以无线电掩星技术为基础，利用掩星数据反演大气参数剖面。对原反演模型的不足进行了论证，并给出了反演个例。详细地论述了通过引入MM5先验温度T再通过线性迭代的方法反演对流层下部水汽廓线原理，给出了优化后模型反演个例。并对模型优化后反演廓线中存在的问题进行了分析，提出了下一步优化方向。     

Changes in soil organic carbon and other physical soil properties along adjacent Mediterranean forest, grassland, and cropland ecosystems in Turkey

Cultivation, overgrazing, and overharvesting are seriously degrading forest and grassland ecosystems in the Taurus Mountains of the southern Mediterranean region of Turkey. This study investigated the effects of changes on soil organic carbon (SOC) content and other physical soil properties over a 12-year period in three adjacent ecosystems in a Mediterranean plateau. The ecosystems were cropland (converted from grasslands in 1990), open forest, and grassland. Soil samples from two depths, 0–10 and 10–20 cm, were collected for chemical and physical analyses at each of cropland, open forest, and grassland ecosystems. SOC pools at the 0–20 cm depth of cropland, forest, and grassland ecosystems were estimated at 32,636, 56,480, and 57,317 kg ha⁻¹, respectively. Conversion of grassland into cropland during the 12-year period increased the bulk density by 10.5% and soil erodibility by 46.2%; it decreased SOM by 48.8%, SOC content by 43%, available water capacity (AWC) by 30.5%, and total porosity by 9.1% for the 0–20 cm soil depth (p<0.001). The correlation matrix revealed that SOC content was positively correlated with AWC, total porosity, mean weight diameter (MWD), forest, and grassland, and negatively with bulk density, pH, soil erodibility factor, and cropland. The multiple regression (MLR) models indicated that any two of the three ecosystems and one of the two soil depths accounted for 86.5% of variation in mean SOC values ((p<0.001).     

Internet‐Based GIS Mapping in Support of K‐12 Education

Internet‐based mapping provides a powerful alternative for successfully establishing GIS technology in the K‐12 education community, while simultaneously avoiding the traditional barriers associated with desktop GIS. Internet‐based GIS can support standards‐based inquiry methods of teaching and learning while providing basic analysis tools for studying and exploring geographic or scientific data in the classroom.