广西芒场锡多金属矿田稳定同位素组成对矿床成因探讨

笔者曾对广西芒场锡多金属矿田的稳定同位素进行研究。本文根据硫、铅、氢、氧、碳等稳定同位素组成和锶的初始值提供的信息.探讨了矿床成因。并结合矿田矿床地质特征、控矿条件及有关统计参数,参考前人对矿床认识的基础上,修正提出了该矿田混合热液成矿模式,可供类似矿床研究和找矿的参考。     

金矿床的热液流体特征研究

通过对中国东部金成矿区域地质特征的分析,根据氢氧同位素及流体包裹体数据特征,表明中国东部金矿床成矿流体主要来自大气降水,其次为变质作用过程释放的水和岩浆分异水;成矿金属组分主要来自太古宙变质岩系。     

40Ar/39Ar and oxygen isotope studies of polymetamorphism from Tinos Island, Cycladic blueschist belt, Greece

Abstract Petrological, oxygen isotope and ⁴⁰Ar/³⁹Ar studies were used to constrain the Tertiary metamorphic evolution of the lower tectonic unit of the Cyclades on Tinos. Polyphase high-pressure metamorphism reached pressures in excess of 15 kbar, based on measurements of the Si content in potassic white mica. Temperatures of 450–500° C at the thermal peak of high-pressure metamorphism were estimated from critical metamorphic assemblages, the validity of which is confirmed by a quartz–magnetite oxygen isotope temperature of 470° C. Some ⁴⁰Ar/³⁹Ar spectra of white mica give plateau ages of 44–40 Ma that are considered to represent dynamic recrystallization under peak or slightly post-peak high-pressure metamorphic conditions. Early stages in the prograde high-pressure evolution may be documented by older apparent ages in the high-temperature steps of some spectra. Eclogite to epidote blueschist facies mineralogies were partially or totally replaced by retrograde greenschist facies assemblages during exhumation. Oxygen isotope thermometry of four quartz–magnetite pairs from greenschist samples gives temperatures of 440–470° C which cannot be distinguished from those deduced for the high-pressure event. The exhumation and overprint is documented by decreasing ages of 32–28 Ma in some greenschists and late-stage blueschist rocks, and ages of 30–20 Ma in the lower temperature steps of the Ar release patterns of blueschist micas. Almost flat parts of Ar–Ar release spectra of some greenschist micas gave ages of 23–21 Ma which are assumed to represent incomplete resetting caused by a renewed prograde phase of greenschist metamorphism. Oxygen isotope compositions of blueschist and greenschist facies minerals show no evidence for the infiltration of a δ¹⁸O-enriched fluid. Rather, the compositions indicate that fluid to rock ratios were very low, the isotopic compositions being primarily controlled by those of the protolith rocks. We assume that the fundamental control catalysing the transformation of blueschists into greenschists and the associated resetting of their isotopic systems was the selective infiltration of metamorphic fluid. A quartz–magnetite sample from a contact metamorphic skarn, taken near the Miocene monzogranite of Tinos, gave an oxygen isotope temperature of 555° C and calculated water composition of 9.1%. The value of δ¹⁸O obtained from this water is consistent with a primary magmatic fluid, but is lower than that of fluids associated with the greenschist overprint, which indicates that the latter event cannot be directly related to the monozogranite intrusion.     

案例推理的地学应用背景和方法

案例推理 (CBR)研究 ,是人类认知的一种合理性模型 ,接近于人类认识、解决问题最原始的思维方式 ,具有在无法获取机理模型、确定规则或统计模型时 ,采用简单的历史相似性推理实现问题的定量求解和预测 ,成为人工智能领域近年来的研究热点。     

20颗依巴谷碳星的近红外测光

对20颗依巴谷(Hipparcos)卫星所观测的碳星作了近红外JHK测光，由近红外观测结果估算了其在K波段的热改正BCK和视热星等mbpl以及有效温度Te，结合依巴谷卫星所得视差，得到其中一些星的绝对热星等Mbol。     

长江三峡工程地壳形变监测网络

长江三峡工程地壳形变监测网络，采用了当今高精度GPS、INSAR空间大地测量技术，并与精密水准测量，精密重力测量，精密激光测距和峒体连续形变监测等技术相结合，构成一个空间上点、线、面结合，时间上长、中、短兼顾的高精度，高时空分辨率的地壳形变监测网络。该网络既可获取三峡库区特别是库首区区域形变场和区域应变场的动态变化，监测库区主要断层活动，为水库诱发地震预测及研究服务，又可用于气象、滑坡地质灾害监测等，该监测网络于1997年底开始建设，2001年6月建成，到目前为止，已获得大量宝贵的观测资料，必将产生显著的经济效益和社会效益。     

Dissolved organic carbon dynamics in two streams draining forested catchments at loch ard,Scotland

Dissolved organic carbon (DOC) was measured at four or eight hour intervals between mid-1989 and mid-1991 in two catchments in west central Scotland. The experimental catchment had been recently clear-felled and the control remained under forest. The amount of DOC varied during individual storm events following the stream hydro-graph. Maximum variations were found in the summer half-year and in the clear-felled catchment. There was also evidence of the exhaustion of DOC in the later events of a sequence. Differences between the catchments were related to catchment characteristics and to land-use change. The reduced magnitude of variation in DOC with discharge in the control stream was due to the influence of a wetland area through which the stream flowed. The mean DOC concentrations were similar in the two streams and annual exports were 15 g m^?2 from the control and 16g m^?2 from the felled catchment. The stream draining the clear-felled catchment had greater high flow DOC concentrations in the summer half-year, probably due to the effect of greater mean summer temperatures on DOC release and of the greater supply of organic debris in the stream channel.     

A warped m= 2 water maser disc in V778 Cyg?

The silicate carbon star V778 Cyg is a source of 22-GHz water maser emission which was recently resolved by MERLIN. Observations revealed an elongated     -like structure along which the velocities of the maser features show a linear dependence on the impact parameter. This is consistent with a doubly warped   m = 2  disc observed edge-on. Water masers and silicate dust emission (detected by the Infrared Astronomical Satellite and Infrared Space Observatory ) have a common origin in O-rich material and are likely to be co-located in the disc. We propose a detailed self-consistent model of a masing gas–dust disc around a companion to the carbon star in a binary system, which allows us to estimate the companion mass of  1.7 ± 0.1 M_⊙  , the disc radius of  40 ± 3  au and the distance between companions of ∼80 au. Using a dust–gas coupling model for water masing, we calculate the maser power self-consistently, accounting for both the gas and the dust energy balances. Comparing the simulation results with the observational data, we deduce the main physical parameters of the masing disc, such as the gas and dust temperatures and their densities. We also present an analysis of the stability of the disc.     

Methane‐related microbial gypsum calcitization in stromatolites of a marine evaporative setting (Münder Formation,Upper Jurassic,Hils Syncline,north Germany)

Fossil stromatolites may reveal information about their hydrochemical palaeoenvironment, provided that assignment to a specific microbial community and a corresponding biogeochemical mechanism of formation can be made. Tithonian stromatolites of the Münder Formation at Thüste, north Germany, have traditionally been considered as formed by intertidal cyanobacterial communities. However, thin sections of the stromatolites show elongated angular traces of former gypsum crystals in a dense arrangement, but no algal or cyanobacterial filament traces. Moreover, high Fe²⁺ and Mn²⁺ contents, oxygen‐isotope and sulphur‐isotope ratios of carbonate‐bound sulphates, and sulphurized hydrocarbon biomarkers of the stromatolitic carbonate indicate that CaCO₃ precipitation occurred near the oxic–anoxic interface as a result of intensive bacterial sulphur cycling rather than photosynthetic activity. Furthermore, anaerobic oxidation of methane by Archaea may have driven CaCO₃ precipitation in deeper parts of the biofilm community, as reflected by high concentrations of squalane with a strongly negative δ¹³C in conjunction with evaporite pseudomorphs showing extremely low δ¹³C_Carb ratios. Consequently, the Thüste stromatolites are now interpreted as having initially formed by gypsum impregnation of biofilms. Subsequently, early Mg‐calcitic calcitization within the biofilms occurred because of combined bacterial iron, manganese and sulphate reduction, with an increasing contribution of anaerobic oxidation of methane with depth. This model plausibly explains the prominent preservation of signals derived from oxygen‐independent metabolic pathways, whereas virtually no geochemical record exists for an aerobic community that may, nevertheless, have prevailed at the stromatolite surface. Photic‐zone stromatolites with a prominent signal of anaerobic oxidation of methane may be common in, and indicative of, oxygen‐depleted sulphate‐bearing environments with high rates of methane production, conditions that possibly were fulfilled at the Archaean to Proterozoic transition.     

Relationship between footwall composition,crustal contamination,and fluid–rock interaction in the Platreef,Bushveld Complex,South Africa

In the northern limb of the 2.06-Ga Bushveld Complex, the Platreef is a platinum group elements (PGE)-, Cu-, and Ni-mineralized zone of pyroxenite that developed at the intrusion margin. From north to south, the footwall rocks of the Platreef change from Archaean granite to dolomite, hornfels, and quartzite. Where the footwall is granite, the Sr-isotope system is more strongly perturbed than where the footwall is Sr-poor dolomite, in which samples show an approximate isochron relationship. The Nd-isotope system for samples of pyroxenite and hanging wall norite shows an approximate isochron relationship with an implied age of 2.17 ± 0.2 Ga and initial Nd-isotope ratio of 0.5095. Assuming an age of 2.06 Ga, the ɛNd values range from −6.2 to −9.6 (ave. −7.8, n = 17) and on average are slightly more negative than the Main Zone of the Bushveld. These data are consistent with local contamination of an already contaminated magma of Main Zone composition. The similarity in isotope composition between the Platreef pyroxenites and the hanging wall norites suggests a common origin. Where the country rock is dolomite, the Platreef has generally higher plagioclase and pyroxene δ ¹⁸O values, and this indicates assimilation of the immediate footwall. Throughout the Platreef, there is considerable petrographic evidence for sub-solidus interaction with fluids, and the Δ _{plagioclase–pyroxene} values range from −2 to +6, which indicates interaction at both high and low temperatures. Whole-rock and mineral δD values suggest that the Platreef interacted with both magmatic and meteoric water, and the lack of disturbance to the Sr-isotope system suggests that fluid–rock interaction took place soon after emplacement. Where the footwall is granite, less negative δD values suggest a greater involvement of meteoric water. Consistently higher values of Δ _{plagioclase–pyroxene} in the Platreef pyroxenites and hanging wall norites in contact with dolomite suggest prolonged interaction with CO₂-rich fluid derived from decarbonation of the footwall rocks. The overprint of post crystallization fluid–rock interaction is the probable cause of the previously documented lack of correlation between PGE and sulfide content on the small scale. The Platreef in contact with dolomite is the focus of the highest PGE grades, and this suggests that dolomite contamination played a role in PGE concentration and deposition, but the exact link remains obscure. It is a possibility that the CO₂ produced by decarbonation of assimilated dolomite enhanced the process of PGE scavenging by sulfide precipitation.