A New Reference Material for Tritium Organic Molecules in Sediment: Results of an International Intercomparison Exercise

Solid matrix ³H reference materials are challenging to prepare given the volatile nature of ³H and are often unrepresentative of the range of ³H forms that may be encountered during routine analysis. As a result, few ³H reference materials are currently available, undermining verification of analytical techniques for environmental ³H measurement. To address this, an International Working Group on Organically‐Bound Tritium Analysis determined to produce a tritium natural matrix reference material (NMRM). The reference material comprises marine sediment blended with sewage sludge contaminated with ³H‐organic species arising from authorised discharges from a radiopharmaceutical manufacturing site. Previous studies have demonstrated that the ³H species have persisted in the environment over three decades providing valuable supporting data to underpin the characterisation of the NMRM. The preparation and characterisation of the NMRM are described along with the subsequent application of the reference material in an international intercomparison exercise involving nineteen laboratories from nine countries. A reference value of 168 ± 22 Bq kg^?1 was derived from the data arising from the proficiency test.     

考虑吸力变化的非饱和高液限黏土-土工织物界面剪切特性研究

以高液限土为填料的加筋挡墙广泛在南方地区应用,加筋挡墙土体吸力经常随气候变化而发生变化,直接影响筋土界面强度特性,考虑吸力变化的非饱和高液限黏土-土工织物界面强度特性亟待深入研究。利用ZFY-1A型非饱和土应变控制式直剪仪对非饱和高液限黏土-土工织物界面进行控制吸力的剪切试验,探讨吸力循环变化（干湿循环）对筋-土界面剪切特性的影响。研究表明,高液限黏土-土工织物界面的抗剪强度随着净法向应力的增加而增大;随着循环次数的增加,界面强度呈现先升高而后衰减的变化规律。经历3次干湿循环的界面强度低于未经历干湿循环的强度。随着循环次数的增加,界面强度总体上呈降低趋势。吸力增加的速率 随吸力循环次数的增加先增大后减小,有效界面摩擦角 、界面有效黏聚力 、界面综合摩擦系数 、综合摩擦系数比K与此类似。 含水率变化量的最大值随着净法向应力、循环次数的增加而增大。最大剪胀量 随循环次数的增加先增大后减小,随净法向应力的增大而减小。最后通过对数拟合,得出经历若干次基质吸力循环后的界面强度计算公式。     

上海村镇民房抗震对策分析

本文采用类比法和定量化方法对上海宝山区村镇民房震害损失进行了预测。在此基础上,对上海已有的和新建的民房提出抗震对策和措施。     

SCATTERING PHASE MATRICES OF ICE CRYSTALS WITH HEXAGONAL PRISM AND TRIANGULAR PYRAMID FORM—A VECTOR RAY TRACING METHOD

The work presented previously by the authors(Cai and Liou,1982)has been extended in this paper.By making use of our improved model the calculations on scattering phase matrices of hexagonal prismice crystals(HPIC)have been conducted for monodisperse and polydisperse systems.Compared with themodel of Cai and Liou,the required computational quantity is decreased by about two orders of magni-tude and the errors of results are less for the new model.Meanwhile,the scattering phase matrices of triangularpyramid ice crystals(TPIC)are also computed in the paper,and the comparison between the scatterings of thetwo forms of ice crystals is performed.     

扩展SSH Hubbard模型的晶格振动矩阵

在计及最近邻电子相互作用的扩展ＳＳＨＨｕｂｂａｒｄ模型时，得到了晶格振动矩阵，它对电子的正负自旋态对称和非对称的各类非线性元激发情形均适用。     

泥质杂基含量对柴达木盆地昆2井孔隙演化模式影响的压实模拟实验研究

随着勘探程度的提高,油气勘探必然向深层延伸。弄清深部储层的孔隙演化规律,提高预测精度,是深入勘探的重要基础。通过对柴达木盆地昆2井岩屑和岩芯样品的系统采集,运用铸体薄片、扫描电镜和测井解释等手段,系统分析了古近系与新近系地层的岩石学、矿物学和储层物性特征,发现泥质杂基含量与砂岩的孔隙演化密切相关。为了正演孔隙的演化过程,运用分选很好的风成石英砂和粒度细小的红色粘土为材料,按照粘土杂基含量为5%、10%、15%、20%,制作了四类石英砂开展模拟实验。松散沉积物的压实模拟,从1.4MPa试验加压到210.4MPa,分别进行了21个循环实验。将实验模拟的结果,与昆2井的岩芯资料进行了对比分析。研究表明,碎屑岩泥质杂基含量越高,初始孔隙度越小,孔隙度衰减越快;泥质含量较低的净砂岩,当上覆压力达到76.5MPa时,颗粒大量破碎并重新排列,导致粒间体积减缩以及少量直线型粒内裂缝出现,储层物性明显变差。压实模拟的实验数据,能够为快速沉降区砂岩的储层质量预测提供依据。     

New insights into geochemical behaviour in ancient marine carbonates (Upper Jurassic Ammonitico Rosso): Novel proxies for interpreting sea‐level dynamics and palaeoceanography

Elemental concentrations in Phanerozoic sea water are known to fluctuate both in time and space. With regard to carbonates precipitated from marine fluids, elemental concentrations in the carbonate crystal lattice are affected by a complex array of equilibrium and non‐equilibrium as well as post‐depositional alteration processes. To assess the potential of carbonate elemental chemostratigraphy, seven Upper Jurassic sections were investigated along a proximal to distal transect across the south‐east Iberian palaeomargin. The aim was to explore stratigraphic and spatial variations in calcium, strontium, magnesium, iron and manganese elemental abundances. The epicontinental geochemical record is influenced by the combination of continental runoff and a significant diagenetic overprint. In contrast, the epioceanic geochemical record agrees with reconstructed open marine sea water values, reflecting a moderate degree of syn‐depositional to early marine pore water diagenesis. Establishing a fair degree of preservation of matrix micrite, a thorough statistical approach was applied and elemental associations tested for their environmental significance. Principal component and hierarchical cluster analyses revealed a persistent relation between carbonate magnesium, iron and strontium abundances. Processes related to early diagenetic nodulation in Ammonitico Rosso facies most probably account for the incorporation of these elements in the calcium carbonate lattice. The clear decoupling of carbonate manganese abundance with respect to the remaining elements is documented and related to high sea floor spreading rates and hydrothermal activity during the Late Jurassic. The investigation of potential time‐fluctuation of geochemical patterns was approached through variogram computation. The observed temporal behaviour is most likely to be forced by relative sea‐level dynamics, reflecting Late Jurassic palaeoceanographic conditions and potential planetary interactions. The data obtained in this study highlight the utility of elemental data from carbonate matrix micrites as geochemical proxies for studying the influence of remote trigger factors.     

半参数回归与模型精化

就一般情况给出了半参数平差的算法,并结合一种特定的情况,讨论了正规化矩阵半正定时的计算方法,给出了相应的公式。最后构造了一个模拟的平差问题,对半参数法和最小二乘法的计算结果进行了比较。计算表明,半参数法能够发现并识别模型误差或观测值中的系统误差     

动载作用下混凝土细观损伤的CT图像分割和灰度共生矩阵特征值研究

动载作用下混凝土随应力变化的系列CT图像完整地记录了混凝土内部破损过程,在CT图像中能直接观察到细观裂纹时混凝土往往已发生宏观破坏,挖掘混凝土材料损伤的细观信息是混凝土细观力学分析的核心。本文基于混凝土单轴动态压缩CT试验,获得不同应力阶段的横断面CT图像,分别应用图像分割技术和灰度共生矩阵法提取孔隙率和4个特征值,研究孔隙率和4个特征值随应力的变化规律。结果表明孔隙率随应力的增加显示出单调增加的总趋势,个别部位在应力水平较小时孔隙率随应力增加变化不大,反映出混凝土的压密效应。受压密效应影响,对比度在低应力水平时随应力增加有升有降,能量对应力变化不够敏感,相关性和同质性随应力的增加单调增加,对应力变化较为敏感,能反映混凝土整体损伤过程。对混凝土CT图像进行分区后再研究孔隙率、同质性和相关性随应力的变化,可以更好地反映动载作用下混凝土的细观损伤过程。     

适用于大旋转角的三维基准转换的一种简便模型

基于大角度的空间直角坐标转换,提出了以方向余弦为参数、适用于任何角度旋转的空间直角坐标转换的简明计算方法。