In Situ Determination of First‐Row Transition Metal,Ga and Ge Abundances in Geological Materials via Medium‐Resolution LA‐ICP‐MS

An in situ, medium‐resolution LA‐ICP‐MS method was developed to measure the abundances of the first‐row transition metals, Ga and Ge in a suite of geological materials, namely the MPI‐DING reference glasses. The analytical protocol established here hinged on maximising the ablation rate of the ultraviolet (UV) laser system and the sensitivity of the ICP‐MS, as well minimising the production of diatomic oxides and argides, which serve as the dominant sources of isobaric interferences. Non‐spectral matrix effects were accounted for by using multiple external calibrators, including NIST SRM 610 and the USGS basaltic glasses BHVO‐2G, BIR‐1G and BCR‐2G, and utilising ⁴³Ca as an internal standard. Analyses of the MPI‐DING reference glasses, which represent geological matrices ranging from basaltic to rhyolitic in composition, included measurements of concentrations as low as < 10⁰ μg g^?1 and as high as > 10⁴ μg g^?1. The new data reported here were found to statistically correlate with the ‘preferred’ reference values for these materials at the 95% confidence level, though with significantly better precision, typically on the order of ≤ 3% (2s_m). This analytical method may be extended to any matrix‐matched geological sample, particularly oceanic basalts, silicate minerals and meteoritic materials.     

Vulnerability assessment in a volcanic risk evaluation in Central Mexico through a multi-criteria-GIS approach

The Valley of Toluca is a major industrial and agricultural area in Central Mexico, especially the City of Toluca, the capital of The State of Mexico. The Nevado de Toluca volcano is located to the southwest of The Toluca Basin. Results obtained from the vulnerability assessment phase of the study area (5,040 km² and 42 municipalities) are presented here as a part of a comprehensive volcanic risk assessment of The Toluca Basin. Information has been gathered and processed at a municipal level including thematic maps at 1:250,000 scale. A database has been built, classified and analyzed within a GIS environment; additionally, a Multi-Criteria Evaluation (MCE) approach was applied as an aid for the decision-making process. Cartographic results were five vulnerability maps: (1) Total Population, (2) Land Use/Cover, (3) Infrastructure, (4) Economic Units and (5) Total Vulnerability. Our main results suggest that the Toluca and Tianguistenco urban and industrial areas, to the north and northeast of The Valley of Toluca, are the most vulnerable areas, for their high concentration of population, infrastructure, economic activity, and exposure to volcanic events.     

阿尔泰造山带玛因鄂博蛇绿混杂岩俯冲-折返拼贴式就位的特征

阿尔泰山南缘原划下石炭统姜巴斯套组实为一套具有洋壳性质的变质岩组成, 由玄武岩、辉长岩和少量硅质岩组成, 并混杂岩了前寒武纪基底残残块。该洋壳组分位于增生岩楔之中, 构造楔形体的形成是俯冲作用一次次“脉冲式”推进的产物, 大体可以分为7个岩片, 在增生楔下部(南部)见有滑混岩出露。角闪岩相变质的洋壳又经历了退变质作用的影响, 显微镜下可见到辉石转变为阳起石、绿帘石交代斜长石的现象。显示折返过程中经历了由角闪岩相绿片岩相的退变质作用演化过程, 俯冲的洋壳残片又被仰冲盘携带上升, 发生俯冲-折返拼贴式就位, 与弧火山岩共同形成了SSZ型蛇绿混杂岩。蛇绿混杂增生岩楔的特征表明洋壳由南向北俯冲, 记录了古亚洲洋中支早古生代晚期的演化特点。     

A Common Reference Material for Cadmium Isotope Studies – NIST SRM 3108

Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio ¹¹⁴Cd/¹¹⁰Cd for NIST SRM 3108 lies within ～ 10 ppm Da^?1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use.     

Événements panafricains dans l'Adrar Souttouf (Sahara marocain)

The Adrar Souttouf belt (Western Sahara) lies in the northern part of the Mauritanide belt and was considered as a part of the Hercynian Mauritanian-Appalachian belt. Recently the presence of a Panafrican protolith (595 Ma) was evidenced by the age of inherited zircons from an eclogitic unit and led to consider complex Panafrican events included in the Hercynian belt, as in the central and southern Mauritanide belt. Our new field survey completed by ten KAr dating (whole rocks and separate minerals) confirmed that multiphased Panafrican formations outcrop within the center of the Adrar Souttouf massif. Diverse events ranged from ca. 1000 to 500 Ma, some of them being indicative of an oceanic type environment and metamorphism. The 1000 Ma metamorphic event is recorded for the first time in the West African craton. A large Hercynian remobilisation is also evidenced. To cite this article: M. Villeneuve et al., C. R. Geoscience 338 (2006).     

Définition et datation de la Formation de Venaco (Corse) : dépôt d’origine gravitaire d’âge Priabonien

Priabonian age is highlighted for the first time in Corsica in the Venaco Formation using the presence of specific microfauna (in particular some representatives of Turborotalia cerroazulensis lineage). This silicoclastic formation is mainly represented by coarse facies. It is composed of three members from south to north and from oldest towards youngest: member of Uboli, Cardo and Orsu. The sedimentologic analysis reveals a gravity depositional environment, involving different type of currents. Sedimentologic and chronologic characteristics make the Venaco Formation and the Annot Formation (p.p.) equivalent. Dating the Venaco Fm. brings confirmation that the green schist metamorphism of the Variscan batholith and the related deformation are from the pre-Priabonian period.     

科学家的人文关怀--读80年前德日进第一次来华时的书信

文章通过读德日进1923～1924年第一次来华工作期间的书信，介绍了德日进思想中的几个重要侧面：其宗教思想中的“上帝”及“现世”；学术研究应跨学科综合进行；精神生活的首要地位以及如何看待东西方文化的异同。     

A spectrophotometric measurement of soil cation exchange capacity based on cobaltihexamine chloride absorbance

Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH₃)₆³⁺ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation.     

Chemical Analysis of Iron Meteorites Using a Hand‐Held X‐Ray Fluorescence Spectrometer

We evaluate the performance of a hand‐held XRF (HHXRF) spectrometer for the bulk analysis of iron meteorites. Analytical precision and accuracy were tested on metal alloy certified reference materials and iron meteorites of known chemical composition. With minimal sample preparation (i.e., flat or roughly polished surfaces) HHXRF allowed the precise and accurate determination of most elements heavier than Mg, with concentrations > 0.01% m/m in metal alloy CRMs, and of major elements Fe and Ni and minor elements Co, P and S (generally ranging from 0.1 to 1% m/m) in iron meteorites. In addition, multiple HHXRF spot analyses could be used to determine the bulk chemical composition of iron meteorites, which are often characterised by sulfide and phosphide accessory minerals. In particular, it was possible to estimate the P and S bulk contents, which are of critical importance for the petrogenesis and evolution of Fe‐Ni‐rich liquids and iron meteorites. This study thus validates HHXRF as a valuable tool for use in meteoritics, allowing the rapid, non‐destructive (a) identification of the extraterrestrial origin of metallic objects (i.e., archaeological artefacts); (b) preliminary chemical classification of iron meteorites; (c) identification of mislabelled/unlabelled specimens in museums and private collections and (d) bulk analysis of iron meteorites.     

Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification

Ilmenite (FeTiO₃) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised ⁵⁷Fe and ⁴⁹Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm^?2 and fs‐LA‐ICP‐MS.