N同位素质谱分析及其数据处理

本文论述了N同位素质谱分析原理和钢瓶高纯氮标定方法。同时对影响N同位素分析分馏因素作了相应讨论，指出钢瓶子高纯氮同位素标定，要用纯化后的大气氮定值。     

冀北张麻井铀钼矿床黄铁矿化蚀变岩地球化学迁移特征及与成矿关系亲缘性的讨论

张麻井铀钼矿床是中国北方最大的与火山岩有关的热液铀矿床，围岩蚀变广泛发育，其中黄铁矿化在该矿床分布虽 较为局限，但是与铀钼成矿关系密切。为了研究黄铁矿化蚀变与铀、钼成矿的亲缘关系，文章对张麻井的黄铁矿化蚀变岩 进行主、微量元素分析，并选择Yb作为不活动组分，使用质量平衡迁移计算方法， 利用Grant公式对其组分迁移进行定量 计算。岩石地球化学特征显示，黄铁矿化蚀变岩的TFeO含量极高，介于11.24%~24.57%之间(平均18.45%)，其中Fe2O3含量 10.78%~25.25% （平均18.64%）、FeO含量1.43%~1.90% （平均1.69%），Fe2O3/FeO比值平均为10.99，有可能受到后期氧 化。黄铁矿化蚀变岩在Isocon图解上等浓度线斜率小于1，表明整体发生了组分的带入，带入的主要组分为大量的TFeO （131倍），成矿元素Mo（884倍）、Pb（11倍）、U（4.9倍）、V（2.8倍）、Ta（0.44倍）、Cu（0.64倍），碱金属Na2O（0.45 倍），以及Cd（424倍）、Bi（13倍） 等；带出的主要组分有碱金属Li（-0.73）、K2O（-0.17），成矿元素Zn（-0.38）、Cr （-0.37），以及Eu（-0.58）、Sc（-0.25） 等。其中SiO2略微减少（-0.03），带入的Mo含量远大于U的含量，据此认为黄铁 矿化与钼成矿关系更为密切。     

三峡工程永久船闸边坡岩体卸荷特性

从地貌学角度,分析了三峡工程永久船闸边坡岩体的自然及人为卸荷特性,指出了地表侵蚀、河流下切、开挖船闸等自然及人为地貌过程诱发了岩体的基本卸荷过程,构筑了一个三峡工程永久船闸边坡岩体卸荷特性的宏观模式。实地调砥及数值计算成果均表明,地貌分析法在分析实际岩体工程中,岩体卸荷特性方面具有较强的应用价值。     

The Zihuatanejo, Mexico, earthquake of 1994 December 10 (M= 6.6): source characteristics and tectonic implications

An analysis of the Zihuatanejo, Mexico, earthquake of 1994 December 10 ( M = 6.6), based on teleseismic and near-source data, shows that it was a normal-faulting, intermediate-depth ( H = 50 ± 5 km) event. It was located about 30 km inland, within the subducted Cocos plate. The preferred fault plane has an azimuth of 130°, a dip of 79° and a rake of −86°. The rupture consisted of two subevents which were separated in time by about 2 s, with the second subevent occurring downdip of the first. The measured stress drop was relatively high, requiring a Δσ of about a kilobar to explain the high-frequency level of the near-source spectra. A rough estimate of the thickness of the seismogenic part of the oceanic lithosphere below Zihuatanejo, based on the depth and the rupture extent of this event, is 40 km.
This event and the Oaxaca earthquake of 1931 January 15 ( M = 7.8) are the two significant normal-faulting, intermediate-depth shocks whose epicentres are closest to the coast. Both of these earthquakes were preceded by several large to great shallow, low-angle thrust earthquakes, occurring updip. The observations in other subduction zones show just the opposite: normal-faulting events precede, not succeed, updip, thrust shocks. Indeed, the thrust events, soon after their occurrence, are expected to cause compression in the slab, thus inhibiting the occurrence of normal-faulting events. To explain the occurrence of the Zihuatanejo earthquake, we note that the Cocos plate, after an initial shallow-angle subduction, unbends and becomes subhorizontal. In the region of the unbending, the bottom of the slab is in horizontal extension. We speculate that the large updip seismic slip during shallow, low-angle thrust events increases the buckling of the slab, resulting in an incremental tensional stress at the bottom of the slab and causing normal-faulting earthquakes. This explanation may also hold for the 1931 Oaxaca event.     

锦屏Ⅰ级水电站坝区岩体结构面特征研究

本文根据锦屏Ⅰ级水电站坝区体结构面野外调资料，对坝区结构面优势方位、间距、张开度、连通率、隙间充填物及形态特征进行了分析，为坝区岩体分类及其物理力学参数的确定提供了重要依据。     

利用相关分析划分重力异常

本文从理论上对相关分析法区分重力异常的可行性进行了论述，并从一元线性回归方程着手，对大地水准面上的重力值与相应的地形高程作了相关分析，通过分析，认为在区域性小比例主均衡补偿基本完善的条件下，重力值与高程有极好的线性相关关系；当计算窗口较大时，地下的局部不均匀体，不足以破坏重力值与高程的相头发一，所以，在实际工作中，利用相关分析处理重力资料的叠加场，可以收到较好的效果，且方法简单易行。     

岩盐及芒硝中各种化合物质量分数的计算

本文以等物质的量的反应规则建立了岩盐、芒硝中各种化合物的质量分数的计算公式。这些公式既符合法定计量单位的要求，又方便计算。     

Transport in a 2-D saturated porous medium: A new method for particle tracking

A new method for solving the transport equation based on the management of a large numbe of particles in a discretized 2-D domain is presented. The method uses numerical variables to represent the number of particles in a given mesh and is more complex than the 1-D problem. The first part of the paper focuses on the specific management of particles in a 2-D problem. The method also would be valid for three dimensions as long as the medium can be modeled similar to a layered system. As the particles are no longer tracked individually, the algorithm is fast and does not depend on the number of particles present. The numerical tests show that the method is nearly numerical dispersion free and permits accurate calculations even for simulations of low-concentration transport. Because each mesh is considered as a closed system between two successive time steps, it is easy to add adsorption phenomenon without any problem of numerical stability. The model is tested under conditions that are extremely demanding for its operating mode and gives a good fit to analytical solutions. The conditions in which it can be used to best advantage are discussed.     

Surface chemical analysis in coal preparation research: complementary information from XPS and ToF-SIMS

The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface.     

Multifractal modeling and spatial statistics

In general, the multifractal model provides more information about measurements on spatial objects than a fractal model. It also results in mathematical equations for the covariance function and semivariogram in spatial statistics which are determined primarily by the second-order mass exponent. However, these equations can be approximated by power-law relations which are comparable directly to equations based on fractal modeling. The multifractal approach is used to describe the underlying spatial structure of De Wijs 's example of zinc values from a sphalerite-bearing quartz vein near Pulacayo, Bolivia. It is shown that these data are multifractal instead of fractal, and that the second-order mass exponent (=0.979±0.011 for the example) can be used in spatial statistical analysis.