Elimination of Interferences in the Determination of Palladium,Platinum and Rhodium Mass Fractions in Moss Samples using ICP‐MS/MS

Moss samples (Pleurozium schreberi) exposed to traffic‐related emission of Pd, Pt and Rh were analysed in this study. Successful elimination of interferences was achieved in the determination of Pd, Pt and Rh mass fractions in these samples using inductively coupled plasma‐tandem mass spectrometry (ICP‐MS/MS). Based on the results, a reliable determination of Pd, Pt and Rh mass fractions in microwave‐digested moss samples was obtained using ammonia (10% NH₃ in He) in the collision/reaction cell when ¹⁰³Rh was measured either on‐mass (103→103) or with mass‐shift (103→171) and mass‐shifts for ¹⁰⁸Pd (108→159) and ¹⁹⁵Pt (195→229) were used. The ICP‐MS/MS procedure was validated using BCR‐723 (road dust) as a reference material. In addition, a good agreement between the ICP‐MS/MS results and the results obtained with cloud point extraction and quadrupole ICP‐MS was observed for the moss samples.     

Research Progress of Leaf-wax Hydrogen Isotope Paleoaltimetry

Leaf waxes/lipids which are derived from terrestrial higher plants are ubiquitous in fluvial, lake, and marine sediments. N-alkanes are an important component of leaf waxes. Modern leaf wax n-alkanes from terrestrial higher plants are characterized with long chains with 27 to 33 carbon atoms (nC₂₇-nC₃₁) and high carbon preference index (CPI) values (>5). The hydrogen isotopes in n-alkanes are determined by meteoric water compositions, which makes them a potential proxy in paleoaltimetry studies. The lapse rates at which n-alkane hydrogen isotopes in modern soils change with altitude vary in different areas, implying that local calibration has to be conducted. The enrichment due to evapotranspiration and difference in fractionation during biosynthesis also influence n-alkane hydrogen isotopes values. When using long-chain n-alkanes to reconstruct paleoaltitude, many factors such as paleoclimate, paleolatitude and paleobotany should be considered.     

湖南产铀花岗岩体的某些特征

湖南产铀花岗岩体主要分布在湘南和湘东南地区,属扬子板块南缘至华夏板块湘东南加里东褶皱区,主要有诸广山、九嶷山、苗儿山等产铀岩体,岩体是由志留、三叠纪、侏罗―白垩纪岩浆侵入体构成的大型复式花岗岩体,花岗岩具有富碱、富钾和铁镁成分较高的特征,原始铀含量高,铀钍分异明显,铀趋向侏罗纪补体富集,在较晚期次侵入体的内外接触带是铀成矿有利空间。     

滇西象达地区蚌渺岩体地球化学特征及其构造意义

蚌渺花岗岩体出露于保山微地块与腾冲微地块之间的泸水―潞西海槽内;该海槽是古生代地史时期保山微地块西侧的一个半深水沉积盆地,随着中三叠世时期古特提斯主洋盆的关闭及弧-陆碰撞作用,该海槽内的岩层普遍发生褶皱、断裂及不同程度的变质作用;在三台山一带还发育有蛇绿混杂岩。蚌渺岩体的主量元素显示了堇青石过铝花岗岩(CPG)的特点,稀土及微量元素资料表明其属典型的高Sr低Yb花岗岩类,具有类似于埃达克岩的地球化学特征。蚌渺岩体形成于中侏罗世,是三叠纪碰撞造山作用结束之后陆内应力松弛阶段的岩浆活动,属后碰撞花岗岩。可能涉及俯冲板片或造山带山根在榴辉岩相温-压条件下的部分熔融作用,是造山运动加厚的地壳向正常地壳恢复的重要机制;也是滇西地区晚中生代大规模中酸性岩浆活动及相关成矿作用的前奏。     

岩石矿物中锆的测定方法研究

测定岩石类样品中的Zr含量,酸溶经常结果偏低,碱溶通常较难获得较低的检出限。本文选取了不同岩性的岩石类国家标准物质GBW07104、GBW07106、GBW07107、GBW07114、GBW07835、GBW07836、GBW07837作为实验样品,分别采用酸溶后复溶、Na2O2碱熔、赶硅后Na2CO3和Na2B4O7三种前处理方法,对电感耦合等离子体质谱仪进行参数优化后上机测定,结果表明:对样品赶硅后加入少量Na2CO3和Na2B4O7混合试剂高温熔融处理岩石样品后,锆的测量值准确度高,而且获得了最低的检出限,同时缩短了方法流程,操作快捷。该方法更适用于各类岩石样品锆的测定。     

Study on engineering-hydrogeological problems of hydroelectric project

Engineering-hydrogeological problems arise from the interaction between engineering activities and geological environment, in which rock-soil mass and groundwater are especially important constituents. However, up-to-date research on them is relatively dispersive and simple due to their complexity and lack of comprehensive and systematic study methods. Starting from geological analysis of mechanism to geological model based on geological regularities, the paper predicts the tendency of geological evolvement and puts forward proper measures to solve problems. In this paper, elevated water-sensitive structure in rock-soil mass, which mainly causes engineering hydrogeological problems, and problems in hydropower is discussed based on unique construction in Chinese Western hydropower projects. Engineering hydrogeological problems are reservoir induced earthquakes leakage from reservoir bottom in karst, stability of high slope at reservoir banks, sliding of dam foundation and dam abutment, and confined water at key positions which are introduced and determined by using water-sensitive factors (or structure) according to special hydrogeological conditions.     

Lacustrine massive mudrock in the Eocene Jiyang Depression,Bohai Bay Basin,China: Nature,origin and significance

Massive mudrock refers to mudrock with internally homogeneous characteristics and an absence of laminae. Previous studies were primarily conducted in the marine environment, while notably few studies have investigated lacustrine massive mudrock. Based on core observation in the lacustrine environment of the Jiyang Depression, Bohai Bay Basin, China, massive mudrock is a common deep water fine-grained sedimentary rock. There are two types of massive mudrock. Both types are sharply delineated at the bottom and top contacts, abundant in angular terrigenous debris, and associated with oxygen-rich (higher than 2 ml O₂/L H₂O) but lower water salinities in comparison to adjacent black shales. In addition, type 1 is laterally isolated and contains abundant sand injections and contorted layers formed in the depositional process, but type 2 exactly distributes in the distal part of deep water gravity-driven sandstone units, and shows scoured bases, high-angle mineral crytsals, and fining-upward trend. It is suggested that type 1 is a muddy mass transport deposit (MMTD) formed by slide, slump, and/or debris flow, and type 2 is a turbiditic mudrock deposited by settling from dilute turbidity currents. A warm and humid climate and high subsidence rate are two main triggering events. Because of its mass movement nature, MMTD preserves the mineralogic composition and organic matter characteristics of the source sediment. By contrast, dilute turbidity currents are able to greatly entrain biochemically-formed micrite and planktonic organisms from the water column, and deposit them in the turbiditic mudrock. Because of their different ability to deposit organic matter, MMTD have poor or fair source rock potential, but the turbiditic mudrock is able to be a potentially effective source rock. The minerals in the massive mudrock are disorganized and chaotic, which cause fractures to develop in various directions, thereby, enhancing the vertical migration of oil and gas molecules to horizontal wellbore in shale reservoir exploitation.     

基于能量平衡对额尔齐斯河流域融雪过程的研究

为定量描述额尔齐斯河流域积雪的消融过程,建立了利用基于能量平衡的积雪模型,对流域内库威积雪站2014年1月4日-3月28日积雪的积累和消融过程进行了模拟.结果表明:模型能够很好的模拟出融雪期净辐射能量的变化过程,对雪水当量的模拟结果也非常好,雪水当量的观测值和模拟值之间的Nash系数达到了0.989.在积雪的积累期,雪表的净辐射、感热、潜热通量的绝对值以及地表热通量明显低于积雪的消融期.在积累期,感热和潜热通量以及土壤热通量受到雪层厚度的影响.当雪水当量小于10 mm时,感热和潜热通量的绝对值偏高,土壤热通量的波动性也偏大.在积累期积雪的物质损失全部为升华损失,升华量为2.74 mm;在消融期,积雪的融化量为66.26 mm,升华量为2.04 mm.净辐射对积雪物质损失的贡献达到了83.1%,湍流通量对积雪物质损失的贡献达到16.9%.由于在融化期土壤热通量为正值,因此土壤热通量对融雪没有贡献.     

质量守恒的订正算法在GRAPES_GFS中的应用

如何在长时间积分的过程中保证模式大气的质量守恒是数值模式动力框架面临的基本问题之一,对于半拉格朗日动力框架来说, 在理论上要满足质量守恒面临着诸多的困难,质量订正方案不失为一种简单可行的选择。中国气象局数值预报中心的GRAPES_GFS (Global-Regional Assimilation and PrEdiction System, Global Forecast System) 在长时间积分过程中质量损失问题较为明显,该研究工作借鉴C-CAM (Climate-Community Atmosphere Model) 中对地面气压进行订正控制模式质量守恒的思路,在GRAPES_GFS中开发了一种对每个网格内的质量按照不同权重系数进行调整、控制模式大气总质量守恒的算法。经过一系列的试验,验证了该方法在GRAPES_GFS中的可行性,在保证模式质量守恒的情况下可有效减小高度场的预报偏差,缓解模式预报结果中天气系统偏弱的问题,在实际业务预报中有一定应用价值。     

固相萃取—高温裂解—气相色谱质谱法测定西台晶间卤水中溶解性有机质

采用3种固相萃取材料(C18、XAD-8/4和PPL)分离富集西台吉乃尔盐湖卤水中的溶解性有机物(DOM),通过总有机碳/总氮分析(TOC/TN)、紫外—可见光谱分析、元素分析、傅里叶变换红外光谱分析(FTIR)、高温裂解—气相色谱质谱联用仪(Py-GC/MS)等对富集的有机物进行表征和分析方法比较。结果表明,西台吉乃尔盐湖卤水中的溶解性有机物主要有多糖类,芳香类、含氮类有机物,烷烃烯烃类化合物。PPL,C18和XAD-8/4的回收率分别为40±2%,7±2%和16±1%,虽然C18和XAD-8/4回收率较低,但3种吸附剂都有各自的特点,C18较易吸附烷烃烯烃类有机物,XAD-8/4较易吸附芳香类有机物,PPL较易吸附含N类有机物和多糖类有机物。