Creep of saturated materials as a chemically enhanced rate‐dependent damage process

Material behaviour that exhibits characteristics of creep induced by a spontaneous mineral dissolution enhanced by material damage is studied. It is believed that the characteristic rates of the chemical processes involved determine the time‐rate dependence of the resulting strain. A basic model of a combined chemo‐plastic softening and chemically enhanced deviatoric strain hardening for saturated geomaterials is presented. Chemical softening is postulated to occur as a consequence of the net mass removal resulting from dissolution and precipitation of specific minerals occurring at the damage‐generated inter‐phase interfaces. Closed and open systems are discussed. In the former case, deformation at constant stress results entirely from a local compensation mechanism between the chemical softening and strain hardening. The classical three stages of creep are interpreted in terms of mechanisms of dissolution and precipitation, as well as the variation in the reaction surface areas involved in the mass exchange. In an open system, the above local mechanism is enhanced by the removal of mass via diffusion of species affecting the mass balance. Such a system is addressed via a boundary value problem as shown in an example. Copyright © 2007 John Wiley & Sons, Ltd.     

New Methods of Fitting the Membership Function of Oceanic Water Masses

1　Introduction　Watermassanalysisisanimportantsubjectinphys icaloceanographystudies (PickardandEmery ,1 990 ;YeandLi,1 992 ) .Helland Hansenplottedin 1 91 6theT Scurve ,whichisafterwardsknownasoneoftheT Sdiagrams ,andsuggestedthatawatermasscanbedefinedby…     

Interannual sea level variability in the South China Sea and its response to ENSO

Sea level observed by altimeter during the 1993–2004 period, thermosteric sea level from 1945 through 2004, and tide gauge records are analyzed to investigate the interannual variability of sea level in the South China Sea (SCS) and its relationship with ENSO (El Niño and Southern Oscillation). Both the interannual variations of the observed sea level and the thermosteric sea level are closely related to ENSO. An ‘enigma’ that the SST and sea level in the SCS have inverse response to ENSO is revealed. It is found that the thermosteric sea level has an excellent correspondence to seawater temperature at 100 m depth, and their variations are unsynchronized to SST. Detailed analysis denotes that the warming of seawater occurs only in the upper 75 m during and after the mature phase of El Niño, while the cooling appears in the layers deeper than 75 m during El Niño years. The volume transports between the SCS and the adjacent oceans and the anomalous Ekman pumping contribute a lot for the sea level fall in the developing stage of El Niño, while the mass exchange, which is dominated by precipitation, plays a more significant role in the following continuous negative sea level anomalies.     

Continuous inline mapping of a dissolved methane plume at a blowout site in the Central North Sea UK using a membrane inlet mass spectrometer – Water column stratification impedes immediate methane release into the atmosphere

The dissolved methane (CH₄) plume rising from the crater of the blowout well 22/4b in the Central North Sea was mapped during stratified water column conditions. Geochemical surveys were conducted close to the seafloor at 80.3 m water depth, below the thermocline (61.1 m), and in the mixed surface layer (13.2 m) using membrane inlet mass spectrometry (MIMS) in combination with a towed CTD. Seawater was continuously transferred from the respective depth levels of the CTD to the MIMS by using an inline submersible pump. Close to the seafloor a well-defined CH₄ plume extended from the bubble release site ∼460 m towards the southwest. Along this distance CH₄ concentrations decreased from a maximum of 7872 nmol l⁻¹ to less than 250 nmol l⁻¹. Below the thermocline the well-defined CH₄ plume shape encountered at the seafloor was distorted and filaments were observed that extended towards the west and southwest in relation to current direction. Where the core of the bubble plume intersected this depth layer, footprints of high CH₄ concentrations of up to 17,900 nmol l⁻¹ were observed. In the mixed surface layer the CH₄ distribution with a maximum of up to 3654 nmol l⁻¹ was confined to a small patch of ∼60 m in diameter. The determination of the water column CH₄ inventories revealed that CH₄ transfer across the thermocline was strongly impeded as only ∼3% of the total water column inventory was located in the mixed surface layer. Best estimate of the CH₄ seabed release from the blowout was 1751 tons yr⁻¹. The fate of the trapped CH₄ (∼97%) that does not immediately reach the atmosphere remains speculative. In wintertime, when the water column becomes well mixed as well as during storm events newly released CH₄ and the trapped CH₄ pool can be transported rapidly to the sea surface and emitted into the atmosphere.     

Associations of decimetric type Ⅲ bursts with coronal mass ejections and Hα flares

We present a statistical study of decimetric type Ⅲ radio bursts,coronal mass ejections(CMEs),and Hα flares observed in the period from July 2000 to March2005.In total,we investigated 395 decimetric type Ⅲ radio burst events,21% of which showed apparent correlation to CMEs that were associated with Hα flares.We noticed that the Hα flares which were strongly associated with CMEs were gradual events,and82% of them took place before CMEs appeared in the field of view of LASCO C2;that most of the CME-associated radio bursts started in the frequency range around750 MHz with a frequency drifting rate of several hundred MHz s-1,of which both positive and negative ones were recognized; and that the correlation of type Ⅲ radio bursts to CMEs without associated flares is fairly vague,less than 9%.     

In situ U–Pb SIMS (IN-SIMS) micro-baddeleyite dating of mafic rocks: Method with examples

An in situ U–Pb SIMS (IN-SIMS) method to date micro-baddeleyite crystals as small as 3 μm is presented with results from three samples that span a variety of ages and geologic settings. The method complements ID-TIMS geochronology by extending the range of dateable crystals to sizes smaller than can be recovered by physical separation. X-ray mapping and BSE imaging are used to locate target grains in thin section, followed by SIMS analysis on a CAMECA ims 1270, using the field aperture in the transfer column to screen out ions from host phases. Internal age precisions for the method are anticipated to range from 0.1% for Precambrian rocks to 3–7% for Phanerozoic rocks. Results establish a 2689 ± 5 Ma age for mafic dikes in the Wyoming craton, USA, a 1540 ± 30 Ma age for a subaerial lava flow from the Thelon Basin of northern Canada, and a 457 ± 34 Ma age for mafic dikes in the platform sequence of southeastern Siberia. The method is ideal for relatively non-destructive dating of small samples such as extraterrestrial rocks and precious terrestrial samples.     

Laboratory plasma dynamos, astrophysical dynamos and magnetic helicity evolution

The term 'dynamo' means different things to the laboratory fusion plasma and astrophysical plasma communities. To alleviate the resulting confusion and to facilitate interdisciplinary progress, we pinpoint conceptual differences and similarities between laboratory plasma dynamos and astrophysical dynamos. We can divide dynamos into three types: 1. magnetically dominated helical dynamos which sustain a large-scale magnetic field against resistive decay and drive the magnetic geometry towards the lowest energy state, 2. flow-driven helical dynamos which amplify or sustain large-scale magnetic fields in an otherwise turbulent flow and 3. flow-driven non-helical dynamos which amplify fields on scales at or below the driving turbulence. We discuss how all three types occur in astrophysics whereas plasma confinement device dynamos are of the first type. Type 3 dynamos require no magnetic or kinetic helicity of any kind. Focusing on Types 1 and 2 dynamos, we show how different limits of a unified set of equations for magnetic helicity evolution reveal both types. We explicitly describe a steady-state example of a Type 1 dynamo, and three examples of Type 2 dynamos: (i) closed volume and time dependent; (ii) steady state with open boundaries; (iii) time dependent with open boundaries.     

广西来宾蓬莱滩二叠纪瓜德鲁普统—乐平统界线剖面元素和同位素地球化学研究及地质意义

广西来宾蓬莱滩二叠系瓜德鲁普统-乐平统界线剖面已被国际地质科学联合会确定为国际界线层型标准剖面,在该界面附近发生了一次重要的全球性生物绝灭事件。蓬莱滩剖面样品采自乐平统合山组底部(由硅质岩和透镜状灰岩组成)和瓜德鲁普统茅口组上部来宾灰岩(由硅质灰岩、灰岩和少量硅质岩组成)。它们具有高的SiO2含量(除3个样品低于10%以外,其余样品均大于17%,平均为43.44%)、m值(>50)与Sr/Ba值(>1.0)和低的MgO/CaO(绝大部分低于02)与 V/(V+Ni)值(<046); Ce和Eu亏损明显。这些地球化学特征反映它们是在相对氧化的浅海环境中形成的,硅的来源非常丰富。样品的εNd(t)值(-7.5~-3.3)和(87Sr/86Sr)i值(0.70705~0.70739)都位于全球大洋Nd、Sr同位素演化曲线晚二叠纪时期区域内。有机碳的δ13Corg值变化明显(-26.7‰~-23.2‰),尤其是在瓜德鲁普统与乐平统以及茅口组与合山组界线附近发生显著的负漂移(达34‰),而且与无机碳的δ13C值呈现大致平行的变化趋势,证实在该界线附近发生过生物绝灭事件。虽然对瓜德鲁普统—乐平统交替时期发生的生物绝灭事件已提出过包括海平面下降在内的多种假设,但本文认为,由地幔柱上升引起的、以峨嵋山玄武岩喷发为代表的超级火山活动以及由此引起的环境效应是该时期生物绝灭的主要原因。     

Simultaneous Determination of Fluorine,Chlorine, Bromine and Iodine in Six Geochemical Reference Materials Using Pyrohydrolysis,Ion Chromatography and Inductively Coupled Plasma‐Mass Spectrometry

Concentrations of halogens (fluorine, chlorine, bromine and iodine) were determined in six geochemical reference materials (BHVO‐2, GS‐N, JG‐1, JR‐1, JB‐1b, JB‐2). Halogens were first extracted from powdered samples using a pyrohydrolysis technique, then hydrolysis solutions were analysed by ion chromatography for F and Cl and inductively coupled plasma‐mass spectrometry for Br and I. The detection limits in solutions were 100 μg l^?1 for both F and Cl and 10 ng l^?1 for Br and I. Considering the extraction procedure, performed on a maximum of 500 mg of sample and producing 100 ml of pyrohydrolysis solution, detection limits in rock samples were 20 mg kg^?1 for F and Cl and 2 μg kg^?1 for Br and I. The mean analytical errors on the studied composition ranges were estimated at 10 mg kg^?1 for F and Cl, 100 μg kg^?1 for Br and 25 μg kg^?1 for I. The concentration values, based on repeated (generally > 10) sample analysis, were in good agreement generally with published values and narrowed the mean dispersion around mean values. Large dispersions are discussed in terms of samples heterogeneity and contaminations during sample preparation. Basaltic RMs were found to be more suitable for studies of halogen compositions than differentiated rock material, especially granites – the powders of which were heterogeneous in halogens at the 500 mg level.