海水中磷酸盐在固体粒子上阴离子交换作用 海水中磷酸盐-固体粒子相互作用的台阶型等温线

通过研究氯化钠溶液中磷酸盐在4种固体粒子（针铁矿、δ－氧化锰、伊利石和高岭石）上的交换等温线及钙对上述交换等温线的影响，发现磷酸盐液－固界面作用的台阶型等温线（2个台阶），可用分级离子／配位子交换等温式定量描述。钙能够促进磷酸盐在针铁矿和δ－氧化锰上的交换作用，其机理是交换在固体粒子上的钙再结合溶液中的磷酸盐，形成表面无机三元络合物。     

Submarine canyon development in the Izu-Bonin forearc: A SeaMARC II and seismic survey of Aoga Shima Canyon

SeaMARC II sidescan (imagery and bathymetry) and seismic data reveal the morphology, sedimentary processes, and structural controls on submarine canyon development in the central Izu-Bonin forearc, south of Japan. Canyons extend up to 150 km across the forearc from the trench-slope break to the active volcanic arc. The canyons are most deeply incised (1200–1700 m) into the gentle gradients (1–2°) upslope on the outer arc high (OAH) and lose bathymetric expression on the steep (6–18°) inner trench-slope. The drainage patterns indicate that canyons are formed by both headward erosion and downcutting. Headward erosion proceeds on two scales. Initially, pervasive small-scale mass wasting creates curvilinear channels and pinnate drainage patterns. Large-scale slumping, evidenced by abundant crescent-shaped scarps along the walls and tributaries of Aoga Shima Canyon, occurs only after a channel is present, and provides a mechanism for canyon branching. The largest slump has removed >16 km³ of sediment from an 85 km² area of seafloor bounded by scarps more than 200 m high and may be in the initial stages of forming a new canyon branch. The northern branch of Aoga Shima Canyon has eroded upslope to the flanks of the arc volcanoes allowing direct tapping of this volcaniclastic sediment source. Headward erosion of the southern branch is not as advanced but the canyon may capture sediments supplied by unconfined (non-channelized) mass flows.Oligocene forearc sedimentary processes were dominated by unconfined mass flows that created sub-parallel and continuous sedimentary sequences. Pervasive channel cut-and-fill is limited to the Neogene forearc sedimentary sequences which are characterized by migrating and unconformable seismic sequences. Extensive canyon formation permitting sediment bypassing of the forearc by canyon-confined mass flows began in the early Miocene after the basin was filled to the spill points of the OAH. Structural lows in the OAH determined the initial locus of canyon formation, and outcropping basement rocks have prevented canyon incision on the lower slope. A major jog in the canyon axis, linear tributaries, and a prominent sidescan lineament all trend NW-NNW, reflecting OAH basement influence on canyon morphology. This erosional fabric may reflect joint/fracture patterns in the sedimentary strata that follow the basement trends. Once the canyons have eroded down to more erosion-resistant levels, channel downcutting slows relative to lateral erosion of the canyon walls. This accounts for the change from a narrow canyon axis in the thickly sedimented forearc basin to a wider, more rugged canyon morphology near the OAH. About 9500 km³ of sediment has been eroded from the central, 200 km long, segment of the Izu-Bonin forearc by the formation of Aoga Shima, Myojin Sho and Sumisu Jima canyons. The volume of sediment presently residing in the adjacent trench, accretionary wedge, and lower slope terrace basin accounts for <25% of that eroded from the canyons alone. This implies that a large volume (>3500 km³ per 100 km of trench, ignoring sediments input via forearc bypassing) has been subducted beneath the toe of the trench slope and the small accretionary prism. Unless this sediment has been underplated beneath the forearc, it has recycled arc material into the mantle, possibly influencing the composition of arc volcanism.     

Estuary/ocean exchange and tidal mixing in a Gulf of Maine Estuary: A Lagrangian modeling study

A Lagrangian particle method embedded within a 2-D finite element code, is used to study the transport and ocean–estuary exchange processes in the well-mixed Great Bay Estuarine System in New Hampshire, USA. The 2-D finite element model, driven by residual, semi-diurnal and diurnal tidal constituents, includes the effects of wetting and drying of estuarine mud flats through the use of a porous medium transport module. The particle method includes tidal advection, plus a random walk model in the horizontal that simulates sub-grid scale turbulent transport processes. Our approach involves instantaneous, massive [O(500,000)] particle releases that enable the quantification of ocean–estuary and inter-bay exchanges in a Markovian framework. The effects of the release time, spring–neap cycle, riverine discharge and diffusion strength on the intra-estuary and estuary–ocean exchange are also investigated.The results show a rather dynamic interaction between the ocean and the estuary with a fraction of the exiting particles being caught up in the Gulf of Maine Coastal Current and swept away. Three somewhat different estimates of estuarine residence time are calculated to provide complementary views of estuary flushing. Maps of residence time versus release location uncover a strong spatial dependency of residence time within the estuary that has very important ramifications for local water quality. Simulations with and without the turbulent random walk show that the combined effect of advective shear and turbulent diffusion is very effective at spreading particles throughout the estuary relatively quickly, even at low (1 m²/s) diffusivity. The results presented here show that a first-order Markov Chain approach has applicability and a high potential for improving our understanding of the mixing processes in estuaries.     

珠江口水体中铜与悬浮颗粒物相互作用的研究

使用无机离子交换法研究珠江口水体中铜与悬浮颗粒物的相互作用，测出钢与悬浮颗粒物相互作用的ｐＨ曲线呈Ｓ形，其分级离子交换等温线是一种新的“台阶”型；从分级离子交换理论求得分级平衡常数Ｋ１为５．０，Ｋ２为７８．１，珠江口水体中铜的表观络合容量为０．９２μｍ及其条件稳定常数为３．５×１０７。     

闽南：台湾浅滩渔场变性水团的初步分析

根据聚类方法，对闽南－台湾浅滩渔场变性水团进行划分，本海区共有６个变性水团。讨论各个变性水团在不同季节消长变化规律。     

长江口及济州岛邻近海域温、盐、密度的跃层现象

本文根据CTD观测资料,分析了研究海区的温、盐、密度跃层的分布与变化,讨论了逆温逆盐层的分布区域,并从跃层角度出发,分析了深层水的涌升,黄海冷水团的上边界以及台湾暖流在东海北部的影响范围。     

Relative molar mass distributions of chromophoric colloidal organic matter in coastal seawater determined by Flow Field-Flow Fractionation with UV absorbance and fluorescence detection

A new method for the characterization of chromophoric colloidal organic matter in seawater has been applied to samples from the Baltic Sea, Kattegatt and Skagerrak seas. Size fractionation of the sample by Flow Field-Flow Fractionation and measurement of the fluorescent and UV absorbing properties of the individual size fractions result in a relative molar mass distribution (RMM) of the optical properties. The RMM distributions have been used to estimate number and weight average relative molar masses, and polydispersity indices. At least two sources of coloured organic matter were identified from the ratio of fluorescence to UV: the Baltic surface water and the Skagerrak deep water. The dominating processes were mixing and dilution, but processes such as photo bleaching of fluorescence are also believed to be important. The RMM distribution derived from UV detection (1150–1300 Dalton) increased with increasing salinity while that derived for fluorescence (1500–1250 Dalton) decreased with increasing salinity. The specific UV absorbance taken as a proxy of the aromaticity of the chromophoric organic material showed decreasing trend with both increasing salinity and increasing UV derived weight average relative molar mass. Increasing polydispersity of the colloidal material was also observed as a function of salinity.     

An alternative approach to the structural motion analysis of wedge-beam offshore structures supporting a load

For convenience of dynamic analysis, some offshore structures such as fixed-type platforms are often modeled as the wedge beams supporting tip lumped masses. It is well-known that, due to the effect of the surrounding water, the natural frequencies of a beam in air (or dry beam) are different from those of the same beam immersed in water (or wet beam). However, if the natural frequencies and the associated mode shapes of a dry beam are calculated by taking account of the “added mass” for the immersed beam, then the last natural frequencies and mode shapes will be equal to the corresponding ones of the wet beam. Based on the last concept, the closed form solutions for natural frequencies and the associated mode shapes of the dry beam were determined first, then the partial differential equation of motion for the wet beam was transformed into a matrix equation by using the expansion theorem and the foregoing closed form solutions of free vibration responses for the dry beam. Solving the last matrix equation will give the required natural frequencies and the associated mode shapes of the wet beam. The formulation of this paper is available for the fully or partially immersed double tapered beams with either circular, square or rectangular cross-sections. The taper ratio for width and that for depth may be equal or unequal. The numerical results of this paper were compared with the existing results or the finite-element-method results and good agreement was achieved.     

The Formation and Circulation of the Intermediate Water in the Japan Sea

In order to clarify the formation and circulation of the Japan/East Sea Intermediate Water (JESIW) and the Upper portion of the Japan Sea Proper Water (UJSPW), numerical experiments have been carried out using a 3-D ocean circulation model. The UJSPW is formed in the region southeast off Vladivostok between 41°N and 42°N west of 136°E. Taking the coastal orography near Vladivostok into account, the formation of the UJSPW results from the deep water convection in winter which is generated by the orchestration of fresh water supplied from the Amur River and saline water from the Tsushima Warm Current under very cold conditions. The UJSPW formed is advected by the current at depth near the bottom of the convection and penetrates into the layer below the JESIW. The origin of the JESIW is the low salinity coastal water along the Russian coast originated by the fresh water from the Amur River. The coastal low salinity water is advected by the current system in the northwestern Japan Sea and penetrates into the subsurface below the Tsushima Warm Current region forming a subsurface salinity minimum layer. This revised version was published online in August 2006 with corrections to the Cover Date.