Measurements of peroxyacetylnitrate in the marine boundary layer over the Atlantic

The atmospheric concentration of peroxyacetylnitrate (PAN) was measured during a cruise of the R.S. Polarstern from Bremerhaven (Germany) to Rio Grande do Sul (Brazil) in September/ October 1988. The measurements were made in-situ by a combination of electron capture gaschromatography with a cryogenic preconcentration step. The theoretical lower limit of detection (3) was 0.4 ppt. The mixing ratios of PAN varied by more than three orders of magnitude from 2000 ppt in the English Channel to less than 0.4 ppt south of the Azores (38° N). South of 35° N, PAN levels were below the detection limit, except at 30–31° S off the eastern coast of South America. Here, PAN mixing ratios of 10 to 100 ppt were detected in continentally influenced air masses. Detectable levels of PAN were mostly observed in air masses of continental or high northern origin. Changes in the wind directions were usually associated with substantial changes in the PAN mixing ratios.     

Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.     

Ophiomorpha irregulaire, rare trace fossil in shallow marine sandstones, Cretaceous Atane Formation, West Greenland

Ophiomorpha irregulaire is a large and extremely rare trace fossil. The type section is in the Book Cliffs, Utah, USA. A second on-shore locality is reported here, in the Nuussuaq Basin of West Greenland. Both occurrences date from the Late Cretaceous. Other reports of O. irregulaire are restricted to two-dimensional sections in well cores and are mostly Jurassic in age. The West Greenland occurrence is in the Atane Formation in shallow marine clean sandstone. The two on-shore localities lie in the same biogeographical region, in connection with the Cretaceous Western Interior Seaway of North America. O. irregulaire is characterized by a sinuous, branched meander maze lying mostly within a single horizontal plane, probably not far beneath the seafloor. The burrow lining has remarkably elongate pellets that probably were emplaced by the burrower. In some cases, diagenetic compression may have deformed the lining pellets to produce their elongated shape. The muddy sediment comprising the lining is almost unrepresented in the clean sands of the substrate, and it was probably trapped from suspension during suspension-feeding activity.     

Lermontovskoe Tungsten Skarn Deposit: the Oldest Mineralization in the Sikhote-Alin Orogen, Far East Russia

Abstract. Lermontovskoe tungsten skarn deposit in central Sikhote-Alin is concluded to have formed at 132 Ma in the Early Cretaceous, based on K-Ar age data for muscovite concentrates from high-grade scheelite ore and greisenized granite. Late Paleozoic limestone in Jurassic - early Early Cretaceous accretionary complexes was replaced during hydrothermal activity related to the Lermontovskoe granodiorite stock of reduced type. The ores, characterized by Mo-poor scheelite and Fe^3+- poor mineral assemblages, indicate that this deposit is a reduced-type tungsten skarn (Sato, 1980, 1982), in accordance with the reduced nature of the granodiorite stock.
The Lermontovskoe deposit, the oldest mineralization so far known in the Sikhote-Alin orogen, formed in the initial stage of Early Cretaceous felsic magmatism. The magmatism began shortly after the accretionary tectonics ceased, suggesting an abrupt change of subduction system. Style of the Early Cretaceous magmatism and mineralization is significantly different between central Sikhote-Alin and Northeast Japan; reduced-type and oxidized-type, respectively. The different styles may reflect different tectonic environments; compressional and extensional, respectively. These two areas, which were closer together before the opening of the Japan Sea in the Miocene, may have been juxtaposed under a transpressional tectonic regime after the magmatism.     

与全球变化有关的几个北极海洋地质问题

极地区域是全球变化研究的重点区域 ,在北极地区与全球变化有关的地质问题主要是北极地区的海陆变化对全球变化的影响 ,以及全球变化在地层中的记录。这涉及到北极形态变化及与其它大洋沟通的水道开闭情况 ,地形起伏对大气、大洋环流的影响 ,地壳升降与海平面变化对河流流量和海岸稳定性的影响 ,气体水合物及有机碳等变化对全球碳循环的影响 ,以及这些影响与气候变化信息在极地沉积物中的记录。文章在对上述影响及海洋地质研究状况进行探讨后 ,又简要介绍了中国的首次北极考察海洋地质研究状况     

四阶△－∑过抽样电路原理及其在微弱地学信号检测中的应用

传统的测量电路无法解决诸如海底大地电磁场这样微弱地学信号的检测问题。近几年诞生了一种称之为△-∑的电路理论以及相应的硬件芯片，给微伏级的弱信号检测开辟一条新的技术路径。文章介绍与地学探测有关的一种△-∑电路类型，该类型以低频段微弱信号为检测对象。采用系统理论和电路分析方法对△-∑原理作了较深入的讨论，阐明这种电路技术对提高微弱信号观测的分辨率是有效的。结合海底大地电磁探测中的信号采集问题，介绍了在仪器中把多路的被测模拟量变为数字量的技术过程。经对实际采集的海底信息的频谱曲线进行分析，证实所采用的△-∑技术以及多路信号采集的电路方案是合理的。     

公婆泉盆地局部排泄源氧化还原属性与铀矿化关系探讨

在系统分析公婆泉盆地地质背景、水文地质条件的基础上，对该区局部排泄源氧化还原属性与铀矿化的关系进行了探讨。研究结果表明，局部排泄源的存在对铀矿化具有重要作用，当局部排泄源属于还原性质时，铀矿体常常分布于该排泄源上游；若属氧化性质，排泄源铀矿体通常位于其下游或附近。公婆泉盆地存在相对氧化和相对还原的二种局部排泄源，北骆驼泉区的沙泉沟与平沙地、麻黄沟、北骆驼泉沟排泄源之间应为有利的铀矿化地段。     

鄂尔多斯盆地奥陶系马家沟组溶斑形成机理

鄂尔多斯盆地中部气田奥陶系马家沟组属蒸发边缘海相地层,其风化壳是中部气田的主要产气层段。该层中广泛发育毫米级、厘米级的溶斑,这些溶斑的产状、大小、成分以及溶孔内的充填物十分复杂,有的具多期充填,充填物为石膏、石英、方解石、白云石、高岭石、黄铁矿等多种矿物。溶斑中下半部残留的岩石经溶蚀后的白云石晶粒形成的渗流砂示底构造十分明显。研究表明,溶斑的形成不仅具有适宜的岩相古地理环境和其复杂的生成演化史,而且与原始沉积以及不同地史阶段的岩溶作用相关。     

A review of the physics and ecological implications of the thermal bar circulation

Following recent applications of numerical modelling and remote sensing to the thermal bar phenomenon, this paper seeks to review the current state of knowledge on the effect of its circulation on lacustrine plankton ecosystems. After summarising the literature on thermal bar hydrodynamics, a thorough review is made of all plankton observations taken in the presence of a thermal bar. Two distinct plankton growth regimes are found, one with production favoured throughout the inshore region and another with a maximum in plankton biomass near the position of the thermal bar. Possible explanations for the observed distributions are then discussed, with reference to numerical modelling studies, and the scope for future study of this interdisciplinary topic is outlined.     

Simulation of marine boundary layer characteristics using a 1-D PBL model over the Bay of Bengal during BOBMEX-99

The characteristic features of the marine boundary layer (MBL) over the Bay of Bengal during the southwest monsoon and the factors influencing it are investigated. The Bay of Bengal and Monsoon Experiment (BOBMEX) carried out during July–August 1999 is the first observational experiment under the Indian Climate Research Programme (ICRP). A very high-resolution data in the vertical was obtained during this experiment, which was used to study the MBL characteristics off the east coast of India in the north and south Bay of Bengal. Spells of active and suppressed convection over the Bay were observed, of which, three representative convective episodes were considered for the study. For this purpose a one-dimensional multi-level PBL model with a TKE-ε closure scheme was used. The soundings, viz., the vertical profiles of temperature, humidity, zonal and meridional component of wind, obtained onboard ORV Sagar Kanya and from coastal stations along the east coast are used for the study. The temporal evolution of turbulent kinetic energy, marine boundary layer height (MBLH), sensible and latent heat fluxes and drag coefficient of momentum are simulated for different epochs of monsoon and monsoon depressions during BOBMEX-99.The model also generates the vertical profiles of potential temperature, specific humidity, zonal and meridional wind. These simulated values compared reasonably well with the observations available from BOBMEX.