Equation of state of MgGeO3 perovskite to 65 GPa: comparison with the post-perovskite phase

The equation of state of MgGeO₃ perovskite was determined between 25 and 66 GPa using synchrotron X-ray diffraction with the laser-heated diamond anvil cell. The data were fit to a third-order Birch–Murnaghan equation of state and yielded a zero-pressure volume (V ₀) of 182.2 ± 0.3 Å³ and bulk modulus (K ₀) of 229 ± 3 GPa, with the pressure derivative (K′₀ = (?K ₀/?P) _T ) fixed at 3.7. Differential stresses were evaluated using lattice strain theory and found to be typically less than about 1.5 GPa. Theoretical calculations were also carried out using density functional theory from 0 to 205 GPa. The equation of state parameters from theory (V ₀ = 180.2 Å³, K ₀ = 221.3 GPa, and K′₀ = 3.90) are in agreement with experiment, although theoretically calculated volumes are systematically lower than experiment. The properties of the perovskite phase were compared to MgGeO₃ post-perovskite phase near the observed phase transition pressure (～65 GPa). Across the transition, the density increased by 2.0(0.7)%. This is in excellent agreement with the theoretically determined density change of 1.9%; however both values are larger than those for the (Mg,Fe)SiO₃ phase transition. The bulk sound velocity change across the transition is small and is likely to be negative [?0.5(1.6)% from experiment and ?1.2% from theory]. These results are similar to previous findings for the (Mg,Fe)SiO₃ system. A linearized Birch–Murnaghan equation of state fit to each axis yielded zero-pressure compressibilities of 0.0022, 0.0009, and 0.0016 GPa^?1 for the a, b, and c axis, respectively. Magnesium germanate appears to be a good analog system for studying the properties of the perovskite and post-perovskite phases in silicates.     

东昆仑东段新生代高原隆升重大事件的沉积响应

根据新生代沉积盆地的地层序列、环境演变及地貌和水系变迁分析将研究区新生代高原隆升过程划分为5个重大事件.首次在研究区内海拔5400m的主夷平面上发现古土壤、岩溶角砾岩及钟乳石等, 认为沱沱河组上段细碎屑沉积及五道梁组石膏沉积(中新世) 是主夷平面形成期的沉积响应, 提出了主夷平面的高程具有东西向排列的盆岭地貌特点, 这种高程差异反映了后期构造隆升的不均衡, 应该是上新世以来差异断块抬升的结果; 早更新世中期(1525.5ka后) 一套河流砂砾卵石沉积是青藏运动C幕的沉积响应, 体现在布尔汗布达山的强烈上升和成山; 早更新世晚期(1113.9~836.3ka) 先湖滨砾石沉积, 后转为河流砂砾卵石沉积, 是昆黄运动在研究区的沉积响应, 并体现在马尔争-布青山的强烈上升和成山, 中更新世早期冰碛物的发育说明昆黄运动后研究区已隆升达到"水汽冻结高度"; 研究区T5阶地沉积前的强烈下蚀, 柴达木盆地内陆水系溯源侵蚀切过布尔汗布达山主分水岭, 袭夺了昆南断裂带原由西向东流向共和古湖的东西向水系并到达阿拉克湖一带, 晚更新世洪冲积角度不整合于中更新世洪冲积之上等是共和运动的具体表现.      

Lithosphere structure of European sedimentary basins from regional three-dimensional gravity modelling

A three-dimensional (3D) density model, approximated by two regional layers—the sedimentary cover and the crystalline crust (offshore, a sea-water layer was added), has been constructed in 1° averaging for the whole European continent. The crustal model is based on simplified velocity model represented by structure maps for main seismic horizons—the “seismic” basement and the Moho boundary. Laterally varying average density is assumed inside the model layers. Residual gravity anomalies, obtained by subtraction of the crustal gravity effect from the observed field, characterize the density heterogeneities in the upper mantle. Mantle anomalies are shown to correlate with the upper mantle velocity inhomogeneities revealed from seismic tomography data and geothermal data. Considering the type of mantle anomaly, specific features of the evolution and type of isostatic compensation, the sedimentary basins in Europe may be related into some groups: deep sedimentary basins located in the East European Platform and its northern and eastern margins (Peri-Caspian, Dnieper–Donets, Barents Sea Basins, Fore–Ural Trough) with no significant mantle anomalies; basins located on the activated thin crust of Variscan Western Europe and Mediterranean area with negative mantle anomalies of −150 to −200×10⁻⁵ ms⁻² amplitude and the basins associated with suture zones at the western and southern margins of the East European Platform (Polish Trough, South Caspian Basin) characterized by positive mantle anomalies of 50–150×10⁻⁵ ms⁻² magnitude. An analysis of the main features of the lithosphere structure of the basins in Europe and type of the compensation has been carried out.     

Mafic dykes derived from Early Cretaceous depleted mantle beneath the Dabie orogenic belt: implications for changing lithosphere mantle beneath Eastern China

SHRIMP zircon U–Pb geochronological, elemental and Sr–Nd isotopic data from Early Cretaceous mafic dykes in North Dabie orogenic belt elucidate a change of Mesozoic lithospheric mantle in eastern China. The dykes are predominantly dolerite with the major mineral assemblage clinopyroxene + hornblende + plagioclase and yield a SHRIMP zircon U–Pb age of 111.6 ± 5.3 Ma. They have a narrow range of SiO₂ from 46.16% to 49.78%, and relative low concentrations of K₂O (1.07−2.62%), Na₂O (2.45−3.54%), Al₂O₃ (13.04−14.07%), and P₂O₅ (0.42−0.55%) but relatively high concentration of MgO (5.94–6.61%) with Mg^# 52–54. All the samples are characterized by enrichment of large ion lithophile elements (LILE, e.g., Ba, Th) and high field strength elements (HFSE, e.g., Nb, Ti). (⁸⁷Sr/⁸⁶Sr)_i ratios from 0.704 to 0.705, ε_Nd values from 3.36 to 4.33 and mantle‐depletion Nd model ages (T_2DM) in the range 0.56–0.64 Ga indicate that the magma of the Baiyashan mafic dykes was derived from a young depleted mantle source. This finding is different from previous research on mafic dykes in the age range 120–138 Ma that revealed enrichment of LILE and depletion of HFSE, high initial Sr isotopic ratios and negative ε_Nd, value which represents an old enriched mantle source. Ours is the first report of the existence of Early Cretaceous depleted mantle in eastern China and it implies that changing of enriched mantle to depleted mantle occurred at ca. 112 Ma, associated with back‐arc extension which resulted from the subduction of the Palaeo‐Pacific Plate towards the Asian Continent. Copyright © 2010 John Wiley & Sons, Ltd.     

新疆博格达白杨沟的枕状熔岩：岩石地球化学和Sr-Nd-Pb同位素特征

新疆博格达造山带北段东侧白杨沟地区分布有大面积的晚石炭世至早二叠世的火山岩,岩石主要由亚碱性玄武岩和安山岩组成,其中分布有大量保存极好的枕状熔岩。枕状熔岩主要为基性熔岩,SiO2含量50.17%～54.66%,Al2O3为13.10%～16.44%,MgO为4.62%～7.89%,TiO2为1.23%～2.79%,CaO为7.06%～13.07%,Na2O为2.76%～4.99%,K2O为0.07%～0.82%。基性熔岩的大离子亲石元素(LILE)一组为富集如Rb和Ba,另一组相对亏损;高场强元素(HFSE)如Nb和Ta在N-MORB标准化图解上都具有明显的负异常。熔岩的稀土元素在球粒陨石标准化配分图解中表现为总体平坦,轻稀土元素(LREE)轻微富集的右倾曲线,δEu为0.89～1.12。从Sr-Nd-Pb同位素组成来看,εNd(t)为+2.8～+3.1,143Nd/144Nd(i)为0.512407～0.512422,εSr(t)为-14.0～-17.5、87Sr/86Sr(i)为0.70293～0.70317、206Pb/204Pb(i)为17.622～17.835、207Pb/204Pb(i)为15.3...     

The Himalayan Collisional Orogeny: A Metamorphic Perspective

This paper introduces how crustal thickening controls the growth of the Himalaya by summarizing the P-T-t evolution of the Himalayan metamorphic core. The Himalayan orogeny was divided into three stages. Stage 60–40 Ma: The Himalayan crust thickened to ~40 km through Barrovian-type metamorphism (15–25 °C/km), and the Himalaya rose from <0 to ~1000 m. Stage 40–16 Ma: The crust gradually thickened to 60–70 km, resulting in abundant high-grade metamorphism and anatexis (peak-P, 15–25 °C/km; peak-T, >30 °C/km). The three sub-sheets in the Himalayan metamorphic core extruded southward sequentially through imbricate thrusts of the Eo-Himalayan thrust, High Himalayan thrust, and Main Central thrust, and the Himalaya rose to ≥5,000 m. Stage 16–0 Ma: the mountain roots underwent localized delamination, causing asthenospheric upwelling and overprinting of the lower crust by ultra-high-temperature metamorphism (30–50 °C/km), and the Himalaya reached the present elevation of ~6,000 m. Underplating and imbricate thrusting dominated the Himalaya’ growth and topographic rise, conforming to the critical taper wedge model. Localized delamination of mountain roots facilitated further topographic rise. Future Himalayan metamorphic studies should focus on extreme metamorphism and major collisional events, contact metamorphism and rare metal mineralization, metamorphic decarbonation and the carbon cycle in collisional belts.     

Geochemical Characteristics and Tectonic Significance of Aoyougou Group Basalts in Western North Qilian

The North Qilian orogenic belt is a typical plate suture zone, which is studded with numerous different sizes of fragments of micro-continental crust consisting of pre-Sinian metamorphic rocks and the North Qilian orogenic belt provides important study carrier for studying the pre-orogenic tectonic process of the North Qilian. The relatively complete volcanic-clastic-carbonate rocks formation of Zhulongguan Group, Changchengian System, Mesoproterozoic are distributed in the Kawa-Qiqing area, Western North Qilian orogenic belt. Geochemical characteristics of the Aoyougou Group basalts in the North Qilian indicated that the contents of major element were relatively stable, high K₂O contents(4.27%~6.07%), TFe₂O₃(10.49%~13.01%),TiO₂(1.96%~2.90%)and middle MgO(5.37%~6.71%,Mg^# 48~51), CaO(2.57%~5.51%)content. Thus, the Aoyougou Group basalts belong to potassium alkaline basalt. The contents of Cr and Ni of the basalts decreased with the decreasing of Mg^#, and there was a positive correlation between CaO and CaO/Al₂O₃, Furthermore, the Eu anomaly of samples was slightly negative, high contents of high field strength elements (HFSE, Nb, Ta, Ti), and the ratios of Gd/Yb(2.5~3.0), Zr/Y(8.6~10.2), Ta/Yb(0.96~1.23), Ti/Yb(5 074~6 021), Zr/Yb(81~97), Ce/Nb(1.87), Zr/Nb(6.41)indicated that the Aoyougou Group basalts had obvious OIB-type magmatic affinity. In combination with the regional geological background, the study results showed that Aoyougou Group alkaline basalt generated from deep enrichment mantle similar to the source of OIB, with fractional crystallization of olivine and monoclinic pyroxene and a certain degree of contamination of continental crust in the process of magmatism, formed in the background of continental rift, might response to the Proterozoic Columbia supercontinent rifting, which further provides important petrological evidences for the relationship between North China Craton rifting events and Columbia supercontinent rifting during Proterozoic.     

Lithosphere formation in the central Slave Craton (Canada): plume subcretion or lithosphere accretion?

Major-element compositions of minerals in peridotite xenoliths from the Lac de Gras kimberlites provide constraints on the mode of lithosphere formation beneath the central Slave Craton, Canada. Magnesia contents of reconstructed whole rocks correlate positively with NiO and negatively with CaO contents, consistent with variable partial melt extraction. Alumina and Cr₂O₃ contents are broadly positively correlated, suggestive of melt depletion in the absence of a Cr–Al phase. Garnet modes are high at a given Al₂O₃ content (a proxy for melt depletion), falling about a 7 GPa melt depletion model. These observations, combined with high olivine Mg# and major-element relationships of FeO-poor peridotites (<7.5 wt%) indicative of melt loss at pressures >3 GPa (residual FeO content being a sensitive indicator of melt extraction pressure), and similar high pressures of last equilibration (∼4.2 to 5.8 GPa), provide multiple lines of evidence that the mantle beneath the central Slave Craton has originated as a residue from high-pressure melting, possibly during plume subcretion. Apparent low melt depletion pressures for high-FeO peridotites (>7.5 wt%) could suggest formation in an oceanic setting, followed by subduction to their depth of entrainment. However, these rocks, which are characterised by low SiO₂ contents (<43 wt%), are more likely to be the result of post-melting FeO-addition, leading to spuriously low estimates of melt extraction pressures. They may have reacted with a silica-undersaturated melt that dissolved orthopyroxene, or experienced olivine injection by crystallising melts. A secular FeO-enrichment of parts of the deep mantle lithosphere is supported by lower average Mg# in xenolithic olivine (91.7) compared to olivine inclusions in diamond (92.6).     

扩径率与入岩深度对岩基挖孔基础抗拔承载特性影响的试验研究

扩径率和入岩深度是影响岩基挖孔基础抗拔承载特性的两个重要因素。通过开展8个不同扩径率、不同入岩深度挖孔基础的现场真型上拔静载试验,从荷载位移变化规律、抗拔承载力和地基岩体破坏模式三方面分析了扩径率与入岩深度对基础抗拔承载特性的影响,结果表明扩径率对荷载位移曲线初始线性阶段影响显著。采用图解法分别获得代表基础低、中、高3种承载能力的抗拔承载力QL1、QDLI、QL2,分析表明,随着扩径率与入岩深度的增加,基础抗拔承载力均有不同程度提高,但两种因素对基础承载力影响机制不同,扩径率可明显提高初始弹性阶段的承载力QL1,而入岩深度可明显提高塑性阶段的承载力QDLI和QL2。通过分析地基破坏时地表岩体裂缝的分布特征,得出岩基中上拔岩体的破坏模式与基础结构型式无关,均是从基底开始出现裂缝,沿着一定角度的开口延伸至地面,直至地基发生破坏,并且破坏范围随着入岩深度的增加而减小。综合考虑基础施工安全性、经济性和机械化程度,建议优先选择加深入岩深度的措施来提高基础抗拔承载力。     

Thermomechanical maturation of the continental crust and its effects on the late Eocene–early Oligocene volcanic record of the Sierra Madre del Sur Province,southern Mexico

We interpret the voluminous late Eocene–early Oligocene volcanic successions of the north-central Sierra Madre del Sur as the eruptive manifestation of a progressive thermomechanical maturation of the crust, driven by sustained igneous activity that affected the region since the early Eocene. Widespread Eocene magmatism and injection of mantle-derived melts into the crust beneath the Michoacán-Puebla area promoted the development of a hot zone extending to upper crustal levels, and the formation of a mature intracrustal magmatic system. Within this context, the intermediate siliceous compositions of the Tilzapotla, Muñeca, and Goleta explosive centres were generated through fractional crystallization, crustal contamination, and anatexis. In particular, decreasing bulk-rock Sr and Eu concentrations and Nd isotopes with increasing silica in the Tilzapotla and Muñeca suites document an evolution through low-pressure fractional crystallization of plagioclase-dominated assemblages, simultaneous with the assimilation of middle–upper crustal materials. In contrast, marked Eu, Sr, and Ba depletions coupled with high and variable Rb/Nd at constant ¹⁴³Nd/¹⁴⁴Nd in the Goleta rhyolites suggest their derivation from partial melting of biotite-bearing quartz-feldspathic lithologies. Ascent of the thermal anomaly induced by magma emplacement and accumulation at shallow depths shifted the brittle–ductile crustal transition close to the surface, and produced an ignimbrite flare-up through caldera-forming eruptions. A different petrogenetic–volcanologic scenario developed in north-western Oaxaca, where less profuse early–middle Eocene igneous activity and an ancient lower crustal basement made up of refractory granulitic lithologies inhibited the expansion of the hot zone to shallow levels, and constrained magmatic evolution at depth. Here, composite and monogenetic volcanoes with intermediate compositions were produced through high-pressure fractional crystallization and crustal contamination. Specifically, increasing La/Yb and Sm/Yb with increasing silica in the Oaxaca suite, and negative correlations of Nd isotopes with SiO₂ at low Rb/Nd, suggest garnet fractionation from parental basalts, coupled with the assimilation of Rb-depleted lower crustal materials.