Fractionation of platinum group elements in upper mantle: Evidence from peridotite xenoliths from Wangqing

The peridotite xenoliths from Wangqing display a downward-concave PGE pattern with Pt at maximum due to Pt-Pd fractionation, which is different from the flat or negatively sloped patterns commonly observed for worldwide peridotite xenoliths and massifs. Taking into account the difference in partition coefficients of Pt and Pd between alloy and sulfide melt, it is suggested that some of the Wangqing peridotites must have been equilibrated with a melt in which alloy and sulfide coexisted. Segregation of Pt-rich alloy from Pd-sulfide melts due to density contrast and extraction of residual melts without sulfide saturation resulted in the fractionation of Pt from Pd. Project supported by the Ministry of Human Affairs and a part of an international collaboration program between the Chinese Academy of Sciences and Centre National de Recherche Scientifique (CNRS, France), and Australian Institute of Nuclear Sciences and Engineering (AINSE) grant to SJR.     

Is there a first-order discontinuity in the lowermost mantle?

In 1983, Lay and Helmberger [Geophys. J. R. Astron. Soc. 75 (1983) 799–837] reported the detection of a precursor to the seismic phase ScS. They attributed this precursor to a sharp seismic discontinuity located several hundred kilometers above the core–mantle boundary. Such a lowermost mantle discontinuity implies the existence of a sharp phase change or a chemical boundary. Precursors to ScS and, less frequently, PcP have since been observed in numerous locations, but are not a global phenomenon. Frequently, PcP precursors are weak or absent when ScS precursors are observed in the same location, and vice versa. There can be significant variations in the amplitude and arrival time of the precursor relative to the main phase. The presence or absence of these precursors has led to speculations about the nature of the lowermost mantle. Here we demonstrate that ScS or PcP precursors may be produced by gradients in seismic wave speed associated with large-scale lowermost mantle heterogeneity. Rather than a phase or chemical boundary with substantial topography, such gradients require lateral variations in temperature and, close to the core–mantle boundary, composition.     

Helium isotope composition of the early Iceland mantle plume inferred from the Tertiary picrites of West Greenland

Picrites from the 61 million year old Vaigat Formation of the Nuussuaq Peninsula in West Greenland have ³He/⁴He ratios trapped in olivine phenocrysts which range up to 30 times the atmospheric ratio. These high values, measured during gas extraction by crushing in vacuum, are similar to the highest magmatic ³He/⁴He ratios found in young terrestrial volcanic rocks. By analogy with young basalts, in which crushing selectively extracts magmatic helium, any significant cosmogenic ³He appears to be absent in these picrites. Additional evidence for the absence of cosmogenic helium is provided by fusion results on the crushed olivine powders and by a single stepwise crushing experiment, in which only magmatic and radiogenic helium components are resolvable. The West Greenland picrites have Pb, Nd and Sr isotope compositions which overlap those found in picrites from Iceland and in basalts from Loihi Seamount, localities which today also have high ³He/⁴He ratios. Isotopic variations in He, Pb, Nd and Sr for the West Greenland picrites are interpreted to largely result from interaction of the early Iceland mantle plume with the upper mantle during plume ascent and dispersion beneath the continental lithosphere. The presence of high ³He/⁴He ratios in West Greenland, and the onset of magmatism across the North Atlantic Volcanic Province near 62 Ma, supports the hypothesis for very rapid dispersion (>1 m/year) of mantle plume head material during the earliest stages of plume impact, as predicted in recent numerical simulations of plume behavior during thermal mantle convection with non-Newtonian rheology.     

Edge-driven convection

We consider a series of simple calculations with a step-function change in thickness of the lithosphere and imposed, far-field boundary conditions to illustrate the influence of the lithosphere on mantle flow. We consider the effect of aspect ratio and far-field boundary conditions on the small-scale flow driven by a discontinuity in the thickness of the lithosphere. In an isothermal mantle, with no other outside influences, the basic small-scale flow aligns with the lithosphere such that there is a downwelling at the lithospheric discontinuity (edge-driven flow); however, the pattern of the small-scale flow is strongly dependent on the large-scale thermal structure of a much broader area of the upper mantle. Long-wavelength temperature anomalies in the upper mantle can overwhelm edge-driven flow on a short timescale; however, convective motions work to homogenize these anomalies on the order of 100 million years while cratonic roots can remain stable for longer time periods. A systematic study of the effect of the boundary conditions and aspect ratio of the domain shows that small-scale, and large-scale flows are driven by the lithosphere. Edge-driven flow produces velocities on the order of 20 mm/yr. This is comparable to calculations by others and we can expect an increase in this rate as the mantle viscosity is decreased.     

Neotectonic Crustal Uplift on the Continents and its Possible Mechanisms. The Case of Southern Africa

According to a large volume of data an intensive crustal uplift began in the Oligocene over most of the continental areas after a long period of relative tectonic stability. This Neotectonic uplift formed most of the present positive topographic features on the continents, and its strong acceleration took place during the last several million years. In many regions the uplift was associated with magmatism. The main methods of studying the Neotectonic uplift are considered together with the data on the uplift of Southern Africa. In this area the uplift took place in the Early Miocene (up to 300 m) and in the Late Pliocene and Pleistocene (up to 900 m). It occurred without stretching or shortening of the crust. Rapid erosion of the lower part of mantle lithosphere by a plume material is proposed as a mechanism of the uplift. This material ascended from below and rapidly spread along the base of the lithosphere. Its spreading for 1000 km during a few million years is possible only under a low viscosity of normal asthenosphere (1019 Pa s) and a much lower viscosity of a plume material (2 × 1016 Pa s). As in Southern Africa, in most of the regions the Neotectonic uplift was associated with insignificant shortening or stretching of the crust. This indicates that in some regions a plume material ascended from below and rapidly spread along the base of the lithosphere and eroded the mantle lithosphere in vast areas beneath the continents. In regions with a hot asthenosphere a strong weakening of the mantle lithosphere which allows its erosion can be associated with a high temperature of the plume material. In regions where the asthenosphere is at moderate temperature weakening of the mantle lithosphere can result from infiltration of volatiles from the plume material.     

Petrology and geochemistry of potassic rocks in the Gölcük area (Isparta, SW Turkey): genesis of enriched alkaline magmas

The Lower Pliocene volcanic rocks occurring in the Gölcük area of SW Turkey exhibit alkaline major element trends with a general potassic character. The development of volcanism can be divided into 2 major stages such as trachytic ancient lavas/domes and tephriphonolitic, trachyandesitic to trachytic Gölcük eruptions (ignimbrites, lava/dome extrusions, phreatomagmatic deposits, and finally, young domes). Volcanic rocks consist primarily of plagioclase, clinopyroxene (which ranges in composition from diopside to augite and are commonly zoned), biotite, and phlogopite. Amphibole phenocrysts are restricted to the pyroclastic deposits. Pseudoleucites are also seen only in the lava/dome extrusions. Oxides and apatites are common accessory phenocryst phases. As would be expected from their potassic–alkaline nature, the volcanic rocks of the Gölcük area contain high amounts of LILE (Ba, Sr, Rb and K), LREE, and Zr. Concentrations of compatible elements such as Cr, Ni and V are very low, possibly indicating fractionation of olivine and clinopyroxene. Correlation of SiO₂, Rb/Sr and MgO with ⁸⁷Sr/⁸⁶Sr (0.703506–0.704142) exhibit an increasing trend in the direction of crustal contamination. However, the isotopic compositions of Sr are not as high to indicate a high level of crustal contamination. Geochemical data are consistent with the derivation of Gölcük volcanic rocks from a metasomatized and/or enriched lithospheric mantle source during crustal extension in the area. This metasomatism was probably occurred by fluids released from the northward subduction between African and Eurasian plates during Tertiary, as the Gölcük volcanic rocks display features of island-arc magmas with having high Ba/Nb (>28) ratios, and Nb and Ti depletions. Lower Pliocene volcanism in the Gölcük was response to extensional tectonics.     

Upper mantle P wave velocity structure of the northern part of China and Mongolia

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The alkaline–peralkaline granitic post-collisional Tin Zebane dyke swarm (Pan-African Tuareg shield, Algeria): prevalent mantle signature and late agpaitic differentiation

The Tin Zebane dyke swarm was emplaced at the end of the Pan-African orogeny along a mega-shear zone separating two contrasting terranes of the Tuareg shield. It is located along the western boundary of the Archaean In Ouzzal rigid terrane, but inside the adjacent Tassendjanet terrane, strongly remobilized at the end of the Precambrian. The Tin Zebane swarm was emplaced during post-collisional sinistral movements along the shear zone at 592.2±5.8 Ma (19WR Rb–Sr isochron). It is a dyke-on-dyke system consisting of dykes and stocks of gabbros and dykes of metaluminous and peralkaline granites. All rock types have Sr and Nd isotopic initial ratios (Sr_i=0.7028 and _Nd=+6.2) typical of a depleted mantle source, similar to the prevalent mantle (PREMA) at that period. No crustal contamination occurred in the genesis of the Tin Zebane swarm. Even the samples showing evidence of fluid interaction (essentially alkali mobility) have the same isotopic signature. The peralkaline granites have peculiar geochemical characteristics that mimic subduction-related granites: this geochemical signature is interpreted in terms of extensive differentiation effects due to late cumulates comprising aegirine, zircon, titanite, allanite and possibly fergusonite, separated from the liquid in the swarm itself due to magmatic flow turbulence. The Tin Zebane dyke swarm is thus of paramount importance for constraining the differentiation of mantle products to generate highly evolved alkaline granites without continental crust participation, in a post-collisional setting.     

岩石钾质变化及钾交代与成矿关系

钾质高低及变化可反映岩石演化程度和钾交代作用。发生钾交代的岩石为成矿有利岩石和找矿标志。岩石钾交代与钾质升高归根于富碱的地幔流体活动。上升的地幔流体交代上地幔和地壳岩石形成富碱岩石和碱交代岩,并活化迁移不同围岩中成矿元素形成各种矿床。大地构造单元边缘与陆内张裂活动带是地幔流体交代活动场所和大型矿床形成地。许多矿床包括金矿床和钾交代关系密切。     

用数字地震资料探测上地幔深部间断面的研究

对利用数字地震波形资料探测上地幔深部间断面的研究进行了综述,并特别对利用宽频带资料的研究结果进行了介绍。在对80年代以来的研究状况进行概述的基础上,对目前存在的困难进行了分析。