胶东金矿幔源成矿流体深部演化与深部找矿

目前,胶东金矿成矿流体研究主要集中在成矿流体的来源及其成矿过程研究,但是对于其侵位前的物化状态及分异演化研究尚浅。该文提出胶东金矿矿集区幔源成矿流体深部演化的一种形成机制,并认为胶东金矿幔源成矿流体在侵位前发生了富集作用。正是由于幔源成矿流体的富集作用才使得胶东地区形成现在规模、品位的金矿。胶东金矿幔源成矿流体的侵位机制主要受华北东部构造转折体制制约。根据胶东地区金矿幔源成矿流体分异演化特征、构造特征及现有深部探测实例表明：胶东地区在1000m以下极有可能存在另一个大型金矿带。     

Viscoelastic relaxation of the upper mantle and afterslip following the 2014 MW8.1 Iquique earthquake

An improved understanding of postseismic crustal deformation following large subduction earthquakes may help to better understand the rheological properties of upper mantle and the slip behavior of subduction interface. Here we construct a three-dimensional viscoelastic finite element model to study the postseismic deformation of the 2014 M_W8.1 Iquique, Chile earthquake. Elastic units in the model include the subducting slab, continental and oceanic lithospheres. Rheological units include the mantle wedge, the oceanic asthenosphere and upper mantle. We use a 2 ​km thick weak shear zone attached to the subduction fault to simulate the time-dependent stress-driven afterslip. The viscoelastic relaxation in the rheological units is represented by the Burgers rheology. We carry out grid-searches on the shear zone viscosity, thickness and viscosity of the asthenosphere, and they are determined to be 10¹⁷ ​Pa ​s, 110 ​km and 2 ​× ​10¹⁸ ​Pa ​s, respectively. The stress-driven afterlsip within the first two years is up to ~47 ​cm and becomes negligible after two years (no more than 5 ​cm/yr). Our results suggest that a thin, low-viscosity oceanic asthenosphere together with a weak shear zone attached to the fault are required to better reproduce the observed postseismic deformation.     

Transport and dispersion of particulate Hg associated with a river plume in coastal Northern Adriatic environments

The role of suspended particulate matter (SPM) as an important carrier of mercury (Hg) dispersed into the Gulf of Trieste and in the adjacent Grado lagoon (Northern Adriatic Sea) was studied during a high Isonzo River inflow and the resulting river plume formation. Despite the fact that extreme flood events are rare during the year, they account for most of the PHg influx (37-112 ngL(-1)) into the Gulf of Trieste. When the river plume is diverted to the SW under the influence of an E-NE wind, the tidal flux acts as a "transport belt" carrying the PHg, mostly inorganic, into the Grado lagoon. A preliminary estimation indicates that the amount of PHg entrapped in the lagoon basin following a tidal semi-cycle accounts for 1.4 kg/12h, which corresponds to about 49% of the total Hg carried by the tidal flow. These findings should be considered in future remediation strategies in the lagoon environment.     

S, C, O, H Isotope Data and Noble Gas Studies of the Maoniuping LREE Deposit, Sichuan Province, China： A Mantle Connection for Mineralization

The Maoniuping REE deposit, located about 22 km to the southwest of Mianning, Sichuan Province, is the second largest light REE deposit in China, subsequent to the Bayan Obo Fe-Nb-REE deposit in the Inner Mongolia Autonomous Region. Tectonically, it is located in the transitional zone between the Panxi rift and the Longmenshan-Jinpingshan orogenic zone. It is a carbonatite vein-type deposit hosted in alkaline complex rocks. The bastnaesite-barite, bastnaesite-calcite, and bastnaesite-microcline lodes are the main three types of REE ore lodes. Among these, the first lode is distributed most extensively and its REE mineralization is the strongest. Theδ34Sv-CDT values of the barites in the ore of the deposit vary in a narrow range of +5.0 to +5.1‰in the bastnaesite-calcite lode and +3.3 to +5.9‰in the bastnaesite-barite lode, showing the isotopic characteristics of magma-derived sulfur. Theδ13Cv-PDB values and theδ518OV-SMOW values in the bastnaesite-calcite lode range from -3.9 to -6.9‰and from +7.3 to +9.7‰, respectively, which fall into the range of "primary carbonatites", showing that carbon and oxygen in the ores of the Maoniuping deposit were derived mainly from a deep source. Theδ13Cv-PDB values of fluid inclusions vary from -3.0 to -5.6‰, with -3.0 to -4.0‰in the bastnaesite-calcite lode and -3.0 to -5.6‰in the bastnaesite-barite lode, which show characteristics of mantle-derived carbon. TheδDv-SMOW values of fluid inclusions range from -57 to -88‰, with -63 to -86‰in the bastnaesite-calcite lode and -57 to -88‰in the bastnaesite-barite lode, which show characteristics of mantle-derived hydrogen. Theδ18OH2OV-SMOW values vary from +7.4 to +8.6‰in the bastnaesite calcite lode, and +6.7 to +7.8‰in the bastnaesite-barite lode, almost overlapping the range of +5.5 to +9.5‰for magmatic water. The 4He content, R/Ra ratios are (13.95 to 119.58×10-6 (cm3/g)STP and 0.02 to 0.11, respectively, and 40Ar/36Ar is 313±1 to 437±2. Considering the 4He increase caused by high contents of radioactive elements, a mantle-derived fluid probably exists in the inclusions in the fluorite, calcite and bastnaesite samples. The Maoniuping deposit and its associated carbonatite-alkaline complex were formed in 40.3 to 12.2 Ma according to K-Ar and U-Pb data. All these data suggest that large quantities of mantle fluids were involved in the metallogenic process of the Maoniuping REE deposit through a fault system.     

The Origin of HIMU in the SW Pacific: Evidence from Intraplate Volcanism in Southern New Zealand and Subantarctic Islands

This paper presents field, geochemical and isotopic (Sr, Nd,Pb) results on basalts from the Antipodes, Campbell and ChathamIslands, New Zealand. New ⁴⁰Ar/³⁹Ar age determinations alongwith previous K–Ar dates reveal three major episodes ofvolcanic activity on Chatham Island (85–82, 41–35,5 Ma). Chatham and Antipodes samples comprise basanite, alkaliand transitional basalts that have HIMU-like isotopic (²⁰⁶Pb/²⁰⁴Pb>20·3–20·8, ⁸⁷Sr/⁸⁶Sr <0·7033,¹⁴³Nd/¹⁴⁴Nd >0·5128) and trace element affinities(Ce/Pb 28–36, Nb/U 34–66, Ba/Nb 4–7). Thegeochemistry of transitional to Q-normative samples from CampbellIsland is explained by interaction with continental crust. Thevolcanism is part of a long-lived (100 Myr), low-volume, diffusealkaline magmatic province that includes deposits on the Northand South Islands of New Zealand as well as portions of WestAntarctica and SE Australia. All of these continental areaswere juxtaposed on the eastern margin of Gondwanaland at >83Ma. A ubiquitous feature of mafic alkaline rocks from this regionis their depletion in K and Pb relative to other highly incompatibleelements when normalized to primitive mantle values. The inversionof trace element data indicates enriched mantle sources thatcontain variable proportions of hydrous minerals. We proposethat the mantle sources represent continental lithosphere thathost amphibole/phlogopite-rich veins formed by plume- and/orsubduction-related metasomatism between 500 and 100 Ma. Thestrong HIMU signature (²⁰⁶Pb/²⁰⁴Pb >20·5) is consideredto be an in-grown feature generated by partial dehydration andloss of hydrophile elements (Pb, Rb, K) relative to more magmaphileelements (Th, U, Sr) during short-term storage at the base ofthe lithosphere. KEY WORDS: continental alkaline basalts; lithospheric mantle, mantle metasomatism; New Zealand; OIB, HIMU; Sr, Nd and Pb isotopes; West Antarctica     

Magmatic Evolution and Ascent History of the Aries Micaceous Kimberlite, Central Kimberley Basin, Western Australia: Evidence from Zoned Phlogopite Phenocrysts, and UV Laser 40Ar/39Ar Analysis of Phlogopite-Biotite

The Neoproterozoic Aries kimberlite was emplaced in the centralKimberley Basin, Western Australia, as a N–NNE-trendingseries of three diatremes infilled by lithic-rich kimberlitebreccias. The breccias are intruded by hypabyssal macrocrysticphlogopite kimberlite dykes that exhibit differentiation toa minor, high-Na–Si, olivine–phlogopite–richteritekimberlite, and late-stage macrocrystic serpentine–diopsideultramafic dykes. Mineralogical and geochemical evidence suggeststhat the high-Na–Si, olivine–phlogopite–richteritekimberlite was derived from the macrocrystic phlogopite kimberliteas a residual liquid following extended phlogopite crystallizationand the assimilation of country rock sandstone, and that themacrocrystic serpentine–diopside ultramafic dykes formedas mafic cumulates from a macrocrystic phlogopite kimberlite.Chemical zonation of phlogopite–biotite phenocrysts indicatesa complex magmatic history for the Aries kimberlite, with theearly inheritance of a range of high-Ti phlogopite–biotitexenocrysts from metasomatized mantle lithologies, followed bythe crystallization of a population of high-Cr phlogopite phenocrystswithin the spinel facies lithospheric mantle. A further oneto two phlogopite–biotite overgrowth rims of distinctcomposition formed on the phlogopite phenocrysts at higher levelsduring ascent to the surface. Ultra-violet laser ⁴⁰Ar/³⁹Ar datingof mica grain rims yielded a kimberlite eruption age of 815·4± 4·3 Ma (95% confidence). ⁴⁰Ar/³⁹Ar laser profilingof one high-Ti phlogopite-biotite macrocryst revealed a radiogenic⁴⁰Ar diffusive loss profile, from which a kimberlite magma ascentduration from the spinel facies lithospheric mantle was estimated(assuming an average kimberlite magma temperature of 1000°C),yielding a value of 0·23–2·32 days for thenorth extension lobe of the Aries kimberlite. KEY WORDS: ⁴⁰Ar/³⁹Ar; diamond; kimberlite; mantle metasomatism; phlogopite–biotite     

Cr-Saturation Arrays in Concentrate Garnet Compositions from Kimberlite and their Use in Mantle Barometry

The spinel–garnet transition in Cr/Al-enriched peridotiticbulk compositions is known from experimental investigationsto occur at 20–70 kbar, within the pressure range sampledby kimberlites. We show that the Cr₂O₃–CaO compositionsof concentrate garnets from kimberlite have maximum Cr/Ca arrayscharacterized by Cr₂O₃/CaO 0·96–0·81, andinterpret the arrays as primary evidence of chromite–garnetcoexistence in Cr-rich harzburgitic or lherzolitic bulk compositionsderived from depth within the lithosphere. Under Cr-saturatedconditions on a known geotherm, each Cr/Ca array implicitlydelineates an isobar inside a garnet Cr₂O₃–CaO diagram.This simplification invites a graphical approach to calibratean empirical Cr/Ca-in-pyrope barometer. Carbonaceous chromite–garnetharzburgite xenoliths from the Roberts Victor kimberlite tightlybracket a graphite–diamond constraint (GDC) located atCr₂O₃ = 0·94CaO + 5·0 (wt %), representing a pivotalcalibration corresponding to 43 kbar on a 38 mW/m² conductivegeotherm. Additional calibration points are established at 14,17·4 and 59·1 kbar by judiciously projecting garnetcompositions from simple-system experiments onto the same geotherm.The garnet Cr/Ca barometer is then simply formulated as follows(in wt %):

if Cr₂O₃ 0·94CaO + 5, then P₃₈ (kbar) = 26·9+ 3·22Cr₂O₃ – 3·03CaO, or

if Cr₂O₃ <0·94CaO + 5, then P₃₈ (kbar) = 9·2+ 36[(Cr₂O₃+ 1·6)/(CaO + 7·02)].

A small correction to P₃₈ values, applicable for 35–48mW/m² conductive geotherms, is derived empirically by requiringconventional thermobarometry results and garnet concentratecompositions to be consistent with the presence of diamondsin the Kyle Lake kimberlite and their absence in the Zero kimberlite.We discuss application of the P₃₈ barometer to estimate (1)real pressures in the special case where chromite–garnetcoexistence is known, (2) minimum pressures in the general casewhere Cr saturation is unknown, and (3) the maximum depth ofdepleted lithospheres, particularly those underlying Archaeancratons. A comparison with the P_Cr barometer of Ryan et al.(1996, Journal of Geophysical Research 101, 5611–5625)shows agreement with P₃₈ at 55 ± 2 kbar, and 6–12%higher P_Cr values at lower P₃₈. Because the P_Cr formulationsystematically overestimates the 43 kbar value of the GDC by2–6 kbar, we conclude that the empirical Cr/Ca-in-garnetbarometer is preferred for all situations where conductive geothermsintersect the graphite–diamond equilibrium. KEY WORDS: Cr-pyrope; chromite; P₃₈ barometer; mantle petrology; lithosphere thickness     

Supra-subduction Zone Pyroxenites from San Jorge and Santa Isabel (Solomon Islands)

Peridotites associated with pyroxenites (with rare olivine andspinel) are exposed on the islands of San Jorge and Santa Isabelin the Solomon Islands. Orthopyroxenite occurs in large outcrops(100 m²) whereas websterite and clinopyroxenite occur as layersand veins/dykes in peridotites. The bulk compositions of thepyroxenites are characterized by high Mg²⁺/(Mg²⁺ + Fe²⁺) (0·78–0·91)and low Al₂O₃ (<2·7 wt %). Low rare earth elementabundances are coupled with large ion lithophile element enrichmentsand positive Sr and Pb anomalies (primitive mantle-normalized)relative to adjacent rare earths. Temperatures of equilibrationfor the pyroxenites are between 950 and 1050°C. These relativelylow temperatures, combined with the occurrence of primary fluidinclusions, suggest that the pyroxenites formed by interactionof peridotite protoliths with an aqueous fluid. Bulk-rock andmineral compositions of the orthopyroxenites are similar tothose of mantle-derived pyroxenites, whereas the websteriteshave closer chemical affinity with crustal arc cumulates. Nevertheless,field relationships plus petrological, textural and geochemicalevidence are consistent with formation of all pyroxenite typesin supra-subduction zone mantle, resulting from metasomatismof peridotite by subducted Pacific Plate-derived fluid. Sucha setting for pyroxenite has not previously been reported indetail. We propose that these processes produce mantle pyroxenitewith compositions similar to crustal pyroxenite. KEY WORDS: mantle metasomatism; pyroxenite; supra-subduction zone     

新疆阿舍勒盆地泥盆纪火成岩与构造-岩浆演化

阿舍勒泥盆纪火山盆地是阿尔泰西南缘重要的矿集区,产出我国著名的火山成因块状硫化物型(VMS)矿床——阿舍勒铜矿.其内部发育的火山岩和侵入岩地球化学特征记录了阿舍勒盆地的构造岩浆演化和成岩、成矿作用过程,但其形成构造背景和成岩成矿机制一直存在争论.本文报道了阿舍勒矿集区萨尔朔克铜金多金属矿区深部英云闪长岩的LA-MC-I...     

中国大陆构造及动力学若干问题的认识

中国(东亚)大陆受特提斯、古亚洲和太平洋构造体系的制约,具有复杂的地体构架和特殊的岩石圈结构。本文从地学前沿——大陆动力学的视野出发,围绕中国大陆构造及动力学四个方面的研究,总结已有的进展并提出新的思考:①中国大陆板块下的构造和整个地幔运动的构架:地震层析资料揭示西太平洋板片向西俯冲到东亚大陆之下,其倾角逐渐减小,最后近水平地插进400～600km深度的地幔过渡带中,成为箕状几何形态的超深俯冲板片。印度岩石圈板片超深俯冲至青藏高原之下～800km的深度,在喜马拉雅西构造结部位发生双向不对称深俯冲,印度岩石圈板片向东俯冲至东构造结东侧之下300～500km的深度。②中国大陆变质基底的再活化:中国大陆的大部分陆块未受显生宙以来构造、变质和岩浆事件的改造与激活,在冈瓦纳大陆北缘的印度陆块和阿拉伯陆块北缘还发育有形成于泛非期(530～470Ma)的造山带,其影响范围至高喜马拉雅、拉萨地体和三江地区。新生代的变质活化普遍出现在喜马拉雅、南迦巴瓦、拉萨地体和三江-缅甸地区,最新的变质年龄仅2～1Ma(南迦巴瓦)。③中国主要高压-超高压变质带的大地构造背景及深俯冲-折返机制:中国及邻区含榴辉岩的高压-超高压(HP/UHP)变质带有洋壳(深)俯冲和陆壳(深)俯冲之分。青藏高原中,大部分洋壳俯冲形成的高压/超高压变质带与原-古特提斯洋盆中诸多微陆块之间的小洋盆的汇聚碰撞有关,陆壳深俯冲作用有两种机制,它们分别是大陆块之间剪式碰撞和撕裂式岩石圈舌形板片的深俯冲。④中国大陆造山带的深部物质可经3类机制挤出,即深部地壳物质"牙膏式"挤出、侧向挤出和"挤压转换式"挤出。