铝对铬成矿地球化学的依存性和对抗性

基于岩浆铬矿床与超镁铁质岩石的关系，从元素亲合性和共生规律的角度揭示了铝对铬成矿制约的主导作用，分析了铝和铬亲石、亲氧的二重性及其晶体化学的依存关系。论证了超镁铁Ｓｉ－Ｏ体系中铝丰度过高或过低均不利于铬的成矿。揭示了制约元素分散富集的因素都是在一定条件下互为依存和转化的，是在动态中的矛盾的对立和统一。     

联合古陆演化周期中超大型含煤及含油气盆地的形成

联合古陆———Ｐａｎｇｅａ的拼合与裂解反映了地球系统内部的巨大变革，这一过程根本上改变了浅部圈层的构造和环境。地史上超大型含煤盆地及含油气盆地与Ｐａｎｇｅａ的演化周期密切相关。在石炭纪及二叠纪拼合过程中形成了一系列超大型聚煤盆地；晚侏罗世Ｐａｎｇｅａ开始裂解，出现全球性裂陷作用期，大西洋张开，许多与裂陷有关的大型叠合盆地形成。在这些盆地中已发现十余个与晚侏罗世烃源岩有关的巨型含油气系统。上述情况表明Ｐａｎｇｅａ演化过程中出现了对能源资源聚集极为有利的古构造、古环境和古气候条件。     

地幔流体及其成矿作用

地幔流体作为一种重要成矿介质在某些矿床形成过程中起到过重要作用。根据目前地幔流体研究的某些成果，介绍了地幔流体可能与成矿的方式和成矿机制，并举例说明地幔流体与超大型，大型矿床之间的成因联系。     

The use of GPR and VES in delineating a contamination plume in a landfill site: a case study in SE Brazil

This paper presents the results of the application of the Ground Penetrating Radar (GPR) method, or Georadar, in outlining a zone of contamination due to solid residues at the waste burial site of Rio Claro in the state of São Paulo, SE Brazil. A total of eight GPR profiles with 50- and 100-MHz antennae were surveyed. Six profiles were located within the landfill site and the remaining two were outside. The main objective of the GPR survey was to evaluate the side extension of contamination. A Vertical Electric Sounding (VES) survey was performed at four points within the site in order to investigate the vertical extent of the contamination plume and to define the bottom of the landfill. Two additional VESs were done outside the landfill with the purpose of determining the top of the ground water table and the geoelectric stratigraphy of the background. From the interpretation of the GPR profiles, it was possible to locate the top of the contamination plume and to infer that it was migrating laterally beyond the limits of the waste disposal site. This was observed along the profile situated close to the highway SP-127, which was about 20 m from the limit of the site. The signature of the contaminant appears as a discontinuous reflector that is believed to be a shallow ground water table. The discontinuity is marked by a shadow zone, which is characteristic of conductive contaminant residues. The contamination did not move far enough to reach a sugar cane plantation located at approximately 100 m from the border of the site. In the regions free from contamination, the ground water table was mapped at approximately 10 m of depth, and it was characterized by a strong and continuous reflector. The radar signal penetrated deep enough and enabled the identification of a second reflector at approximately 14 m deep, interpreted as the contact between the Rio Claro and the Corumbataí formations. The contact is marked by the presence of gravel characterized by ferruginous concretes, which cause the strong amplitude reflection in the GPR profile. Within the landfill site, the quantitative interpretation of the VES results showed the contamination zone. The base of the landfill varies between 11 and 15 m deep. Outside the landfill site, the VES results showed no indication of contamination and allowed the determination of the top of the ground water table and the contact between the Rio Claro and the Corumbataí formations. The results of GPR and VES showed a good agreement and the integrated interpretations were supported by local geology and information from several boreholes, about 17 m depth, on average. The bottom of the landfill reaches a maximum of 14.5 m depth.     

Magmatic effects of the lunar late heavy bombardment

Large volumes of mare basalts are present on the surface of the moon, located preferentially in large impact basins. Mechanisms relating impact basins and mare basalt eruptions have previously been suggested: lunar impacts removed low-density material that may have inhibited eruption, and created cracks for fluid flow [Icarus 139 (1999) 246], and lunar basins have long been described as catchments for magma (e.g., [Rev. Geophys. Space Phys. 18 (1980) 107] and references therein). We present a new model for melt creation under near side lunar basins that is triggered by the impacts themselves. Magma can be produced in two stages. First, crater excavation depressurizes underlying material such that it may melt in-situ. Second, the cratered lithosphere rises isostatically, warping isotherms at the lithosphere-asthenosphere boundary which may initiate convection, in which adiabatic melting can occur. The first stage produces by far the largest volume of melt, but convective melting can continue for up to 350 Ma. We propose that giant impacts account for a large portion of the volume and longevity of mare basalt volcanism, as well as for several compositional groups, including high alumina, high titanium, KREEP-rich, and picritic magmas.     

The influence of thermochemical convection on the fixity of mantle plumes

A general feature of both isochemical and thermochemical studies of mantle convection is that horizontal plume velocities tend to be smaller than typical convective velocities, however, it is not clear which system leads to a greater fixity of mantle plumes. We perform two- and three-dimensional numerical calculations and compare both thermochemical and isochemical cases with similar convective vigor to determine whether presence of a dense component in the mantle can lead to smaller ratios of horizontal plume velocity to surface velocity. We investigate different viscosity and density contrasts between chemical components in the thermochemical calculations, and we perform isochemical calculations with both free-slip and no-slip bottom boundary conditions. We then compare both visually and quantitatively the results of the thermochemical and isochemical calculations to determine which leads to greater plume fixity. We find that horizontal plume velocities for thermochemical calculations are similar to those from isochemical calculations with no-slip bottom boundary conditions. In addition, we find that plumes tend to be more fixed for isochemical cases with free-slip bottom boundary conditions for two-dimensional calculations, however, in three dimensions, we find that plume fixity is similar to that observed in thermochemical calculations.     

Molecular modeling of the 10-Å phase at subduction zone conditions

Molecular dynamics (MD) modeling of the 10-Å phase, Mg₃Si₄O₁₀(OH)₂·xH₂O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures.     

大别山沙村中生代A型花岗岩和基性岩的源区演化关系

A型花岗岩的成因虽存在不同的认识模式,但对大别山沙村A型花岗岩的岩石化学和地球化学研究结果表明,其物质源自大陆岩石圈地幔的部分熔融,含有古老地壳信息。结合被侵入基性岩的地球化学和年代学资料,推测大别造山带中生代岩石圈地幔的地球化学性质与下扬子地幔相似。花岗岩中锆石SHRIMP法U-Pb年龄为119.0±3.2Ma,说明其岩浆侵位于早白垩世,与邻近的基性岩侵位时间相近但稍晚。在三叠纪因大陆俯冲碰撞增厚的岩石圈在早白垩世被拉张减薄,含有古老地壳成分的扬子陆下岩石圈地幔及其上覆下地壳发生部分熔融,形成了不同成分的碰撞后岩浆岩。其中部分基性岩浆分异结晶成为辉长岩,而A型花岗岩可能是同一地幔源区物质小比例部分熔融后分异结晶的产物。     

南太行山闪长岩的SHRIMP锆石U-Pb年龄及岩石成因研究

南太行山符山和东冶角闪闪长岩岩体的精细SHRIMP锆石U-Pb定年和元素-同位素地球化学研究表明:符山角闪闪长岩体形成于126.7±1.1Ma,东冶角闪闪长岩体形成于125.9±0.9Ma,与区内基性侵入岩和北太行地区侵入杂岩具有相似的形成年龄,表明晚中生代(±130Ma左右)太行山地区经历了与华北陆块同期的重要构造岩浆事件。区内闪长质岩石SiO_2=54.84％～65.75％,MgO=1.31％～3.89％,K_2O Na_2O=6.53％～11.40％,mg值=0.36～0.58,(La/Yb)_(cn)=9.86～22.77,(Gd/Yb)_(cn)=1.51～2.00;Eu/Eu=1.00～1.23,以富集LREE、LILE元素和明显亏损Nb-Ta、Zr-Hf-Ti等高场强元素为特征。~(87)Sr/~(86)Sr(t)=0.705363～0.706165,ε_(Nd)(t)=-13.8～-16.8,源自于EMI型富集岩石圈地幔,可解释为新生地幔底侵物质熔融后经过结晶分异作用的产物。与华北克拉通内部其他地区一样,早白垩世南太行山地区处于软流圈上涌的岩石圈伸展构造背景。     

中国东部中新生代构造格局和岩浆岩带的形成与演化

在研究印支期秦岭-大别-苏鲁造山带的形成与地幔差速环流的基础上，系统综合了中国东部中新生代的基底构造对断裂构造的控制，深层构造对隆凹与断陷盆地的制约，伸展构造在陆内及陆缘外的表现，岩浆岩带的时空分布及展布特点等规律，依据中国东部中新生代构造格局与岩浆岩带在时空分布上的宽阔性、方向性、迁移性、分带性，特别是深层构造对浅层断裂构造、伸展构造的制约，以及岩浆岩带、隆起与盆地等自西向东迁移特点，提出其形成机制可能与强大地幔东向差速环流有关。