Polymetallic Mineralization at the Shin-Ohtoyo Deposit, Harukayama District, Hokkaido, Japan

Abstract: The Shin-Ohtoyo Cu–Au deposit is located in the Harukayama district, 20 km west of Sapporo, Hokkaido, Japan. Both acid-type disseminated and adularia–quartz–type vein Au mineralizations have been recognized within a small distance of less than 500 m in the district. Mineralogical characteristics of sulfide ores from the Shin-Ohtoyo deposit have been proved to be polymetallic. Ore minerals containing Sn, V, Bi and Te are recognized. Nine ore types are recognized in terms of characteristic mineral assemblage; (1) chalcedonic quartz veinlets in silicified zone around the deposit, (2) bismuthinite, emplectite, friedrichite and tetrahedrite, (3) an unnamed Cu–Sn–Fe–Zn sulfide, colusite-series minerals, stannoidite, emplectite and tetrahedrite, (4) bournonite, Se-bearing galena and tetrahedrite, (5) luzonite/famatinite and Ag-bearing tetrahedrite, (6) colusite-series minerals, emplectite, aikinite and tetrahedrite/goldfieldite, (7) luzonite/famatinite, colusite-series minerals, mawsonite and tetra–hedrite/goldfieldite, (8) enargite, luzonite/famatinite and tetrahedrite, and (9) colusite-series minerals and tetrahedrite. The first occurrence of friedrichite and stibiocolusite from Japan are reported. The chemical formula of the unnamed phase corresponds to Cu₆(Cu, Fe, Zn)Sn₃S₁₀. Sulfur isotopic ratios (δ³⁴S) of sulfides from the stockpile range from –0. 5% to +1. 9%, and those from drill cores recovered by Metal Mining Agency of Japan (MMAJ) vary from –2. 7% to +0. 8%. Sulfur isotopic ratio of barite in a cavity in the silicified tuff breccia collected from the stock pile yields +27. 1%, while that of barite collected from MMAJ core is +21. 7%. Sulfur isotopic thermometry applied for a pair of barite (+21. 7%) and associated pyrite (+1. 8%) indicates about 300°C. High–Te tetrahedrite composition from both the chalcedonic quartz vein in the silicified zone around the Shin-Ohtoyo deposit and the polymetallic sulfide ores from the adit of the deposit, suggests that the Au mineralization in the former is attributed to a hydrothermal system marginal to the polymetallic mineralization.     

山东省兰陵县车辋地区铜铅多金属矿地质特征及找矿标志

车辋地区铜铅多金属矿区位于山东省兰陵县车辋镇东部,区内寒武奥陶纪碳酸盐岩地层分布广泛,中生代岩浆活动频繁,构造活动强烈、层间破碎带发育。激电异常明显,且具低阻高极化特征。铜铅多金属矿化期为岩浆期后热液阶段,岩体边部和外侧的构造破碎带、层间破碎带为成矿热液的运移、储存提供了有利空间,是寻找多金属矿的有利部位。     

闽西南多金属成矿带地质地球物理特征综合研究——以永定大排多金属矿区为例

闽西南地区位于福建武夷山成矿带西南部,自远古宙以来经历了多期次的构造演化.该区地处东南沿海构造-岩浆-成矿带上,为环太平洋大陆边缘多金属成矿带与南岭多金属成矿带复合部位,是我国重要的多金属矿产地.永定大排多金属矿区作为近年来武夷山成矿带新发现的大型多金属矿,区内叠加作用和控矿作用相对复杂,现有的地质地球物理工作程度不足以满足对该区域成矿规律的深入认识,一些基础地质问题亟待解决.因此,本文在深入收集永定大排矿区地质地球物理资料基础上,综合分析区域成矿背景与成矿构造,在重点区域布设综合地球物理勘探工作,包括1：1万高精度磁测、可控源音频大地电磁剖面及反射地震剖面.基于上述工作：1）开展了研究区航磁数据三维磁化率反演与分布特征分析与大地电磁二维电阻率反演与分布特征分析,开展了地震资料真地表深度偏移成像,获得了更加准确的地震剖面成像结果.2）结合推覆体控矿特征,地震剖面和电阻率剖面、航磁反演结果相互验证和约束,勾画了地下构造形态.地表地质剖面延伸和标定了构造形态的地质内涵,获得了从地表到3000 m深度的构造解释结果.解释结果清晰地显示了与推覆相关的构造、控矿层位以及岩体信息,为三位一体的找矿思路提供了地球物理依据.     

东太平洋多金属结核中铁、锰元素的分形演化及其意义

运用分形理论,通过建立不同的相空间,计算了东太平洋多金属结核中的铁、锰元素的时间序列在各相空间中的关联分维,并与其在沉积物岩心中的关联分维进行了对比.通过研究发现,多金属结核中铁、锰元素和沉积物中Fe₂O₃及MnO在分形演化过程中均存在分维吸引子,认为沉积物中的Fe₂O₃和MnO可以用3个变量来描述,它们可能代表了火山、生物和陆地的三种来源,而描述结核中的铁、锰元素却需要14个变量,反映多金属结核中铁、锰元素的来源和/或赋存非常复杂,至少有14个因素在起作用,可能暗示了结核在形成过程中存在复杂的生物化学作用,为多金属结核的生物成因提供了间接的数学证据,同时也合理解释了结核生长结构所具有的自相似韵律现象.     

宁镇中段夕卡岩型铜多金属矿床多元信息成矿预测初步研究

宁镇中段铜多金属矿床主要为接触交代型矿床.文章以地质环境和成矿规律研究为基础,采用逻辑信息法综合提取地质、遥感、地球物理和地球化学多层次成矿预测信息,构建逻辑信息法成矿预测要素组合.并以此为指导,按照地质成矿条件有利程度、物化探异常强度与规模、环形构造发育程度、遥感解译蚀变显现强度与规模,进行综合判别确定成矿有利位置,...     

陕西镇坪地区唐家垭子钼钒多金属矿床地质特征与成因

陕西镇坪地区唐家垭子钼钒多金属矿床是近年来新发现的钼钒矿床,含矿地层及矿化带延伸情况显示其具有达到大型规模的潜力。矿体产于寒武系下统鲁家坪组黑色岩系,与地层展布方向一致,受黑色岩系控制;矿石类型有含炭板岩型、粉砂质板岩型及含炭硅质岩型3种;矿石含钼矿物主要有铁钼华、钼华、胶硫钼矿等,钒主要存在于钒云母中,其次为高岭土、电气石等;矿石化学成分以Mo、V2O5为主,主成矿元素为Mo、V,伴生金属元素有Ag等。矿床地球化学综合分析认为,寒武系下统鲁家坪组为(较封闭的)浅海盆地相;含矿地层鲁家坪组的Mo、Cu、Ni、Pb含量分析表明,沉积的深度可能大于250m;w(Ni)/w(Ti)、w(Cu)/w(Ti)值表明,沉积的离岸距离为100~300km;w(V)/w(Ni)、w(V)/(w(V)+w(Ni))值反映成矿期处于缺氧—强缺氧的还原沉积环境;矿床地质地球化学分析表明,该矿床为明显的深海冷水沉积型矿床。     

吉林延边红太平铜多金属矿床脉型矿化的成矿时代与构造背景

吉林延边红太平铜多金属矿床位于兴蒙造山带东段,区内发育产于晚古生代火山沉积岩系中的层状铜多金属矿体和受岩体及构造控制的脉状铅锌矿体。为了确定脉型铅锌矿化的成矿时代与构造背景,本文对与脉状铅锌矿体相关的英安岩开展了LA-ICP-MS锆石U-Pb定年及岩石地球化学研究,并对脉状铅锌矿体中金属硫化物开展了Rb-Sr同位素定年。结果表明,英安岩中28个锆石测点的~(206)Pb/~(238)U加权平均年龄为204.1±2.0Ma(MSWD=0.24),脉状铅锌矿石中4件金属硫化物的Rb-Sr等时线年龄为206.8±9.0Ma(MSWD=2.0),二者在误差范围内基本一致,表明红太平矿床脉型铅锌矿化的成矿时代为晚三叠世末期。英安岩的稀土元素配分模式呈明显的轻稀土元素(LREEs)富集,轻重稀土分馏明显[(La/Yb)N=7.59～8.28],存在弱的Eu异常(δEu=0.65～0.68);微量元素以富集大离子亲石元素(LILEs:Rb、Ba和K)和不相容元素(U、Th),亏损高场强元素(HFSEs:Nb、Ta、P和Ti)为特征,表明原始岩浆应为壳-幔混源;脉状铅锌矿体中4件金属硫化物初始Sr同位素比值(87Sr/86Sr)i为0.705954～0.707101(均值0.706390),表明脉型铅锌矿化与壳-幔混源的岩浆作用密切相关。根据Rb-(Yb+Ta)及La/Yb-Th/Yb图解判别结果,结合区域构造演化分析,认为红太平矿区英安岩及相关的脉型铅锌矿化形成于活动大陆边缘的构造环境,与晚三叠世-早侏罗世(T_3-J_1)古太平洋板块向欧亚板块的俯冲作用密切相关。     

敞开酸溶和偏硼酸锂碱熔ICP-MS法测定多金属矿中的稀土元素及铌钽锆铪

用电感耦合等离子体质谱法(ICP-MS)测定地质样品中的稀土及难熔元素,混合酸敞开酸溶法和碱熔融法是两种主要的溶样方法。但地质样品组分复杂,元素之间存在相互共生的现象,对于特殊元素、特殊样品用传统酸溶法会造成部分元素消解不完全,使测定结果不准确;而碱熔法的操作过程繁琐,且溶液盐度高,易产生基体干扰和堵塞仪器进样系统。本文改进了传统四酸和五酸体系,采用氢氟酸-硝酸-硫酸敞开酸溶体系,用国家一级标准物质制作标准曲线测定15种稀土元素,方法准确度(ΔlgC)为0.001～0.027。同时改进了偏硼酸锂碱熔法,样品用偏硼酸锂碱熔提取,加入氢氧化钠调节溶液至碱性条件,所测元素与偏硼酸锂共沉淀后过滤分离熔剂,再用硝酸复溶测定15种稀土元素及铌钽锆铪。两种溶样方法的测定值与认定值的相对误差为1.09%～9.30%。将混合酸敞开酸溶法测定稀土元素、偏硼酸锂碱熔法测定铌钽锆铪的结果与其他实验室密闭酸溶法相比,两组数据的相对偏差为0.13%～15.32%。本实验表明,混合酸敞开酸溶法适用于测定地质样品中的稀土元素,偏硼酸锂碱熔法不仅适用于测定地质样品中的稀土元素及铌钽锆铪,也适用于测定如古老高压变质岩石及铝含量高的样品中的铌钽锆铪。     

内蒙古呼伦西白地区铌稀土多金属矿成矿特征及找矿标志

北山成矿带东缘的内蒙古呼伦西白地区近年来发现了多处铌稀土矿床(点),矿床(点)产于二叠纪二长花岗岩外接触带上,矿体赋存于滨浅海相碳酸盐岩-变碎屑岩内,其形态、产状、规模受构造-岩浆活动控制,并与磁异常对应,其中灰石山东北铌稀土矿区Nb2O5品位0.02%～0.56%、平均0.11%,REO品位0.13%～2.63%,平均0.93%,辉森乌拉西铌金矿区Nb2O5品位0.01%～0.1%,与白云鄂博Nb-REE-Fe超大型矿床特征类似,成矿潜力巨大。结合区域地质背景及铌稀土多金属矿成矿特征,初步认为区内该类型矿床的找矿标志为:二叠系滨浅海相碳酸盐岩-变碎屑岩地层、构造挤压形成的虚脱空间或韧-脆性转换部位、二叠纪二长花岗岩外接触带、放射性异常梯度带-磁异常位置、岩石蚀变(褐铁矿化、硅化、碳酸盐化等)和石英细网脉发育地段。对该地区铌稀土多金属矿成矿特征和找矿标志的研究有利于拓展北山地区三稀矿产的找矿思路,也可为此类矿产的找矿方向提供借鉴。     

Gravity and magnetic field characteristics and regional ore prospecting of the Yili ancient continent,West Tianshan,Xinjiang Uygur Autonomous Region,China

Gold, iron, copper, lead-zinc and other mineral exploration in West Tianshan, Xinjiang Uygur Autonomous Region, has made remarkable progress in recent years. However, due to the dispute on the tectonic division of West Tianshan, the ore-controlling factors and the regional metallogenic laws are controversial. The authors analyze regional gravity data and notice that the high-value region corresponds to the Yili ancient continent, thus the southeastern boundary of the Yili ancient continent is delineated. Comparative analysis of gravity, aeromagnetic and geologic data reveals that the Tulasu basin, where some medium to large epithermal gold deposits locate, lies above the Yili ancient continent; the Yili Carboniferous-Permian rift extends in E-W direction, numbers of copper deposits have been found in the mid-west section of the rift which lies above the Yili ancient continent, whereas few copper deposits have been discovered in the east section which is outside the Yili ancient continent. Accordingly, the Yili ancient continent may he rich in gold, copper and other metal elements; the metal-bearing hydrothermal solution moves up with the activity of magmatism, and deposits in the favorable places (the Tulasu basin and the Yili Carboniferous-Permian rift), forming numerous small and medium gold, copper deposits, as well as some large and super-large gold deposits. Therefore, the tectonic-magmatic hydrothermal zone above the Yili ancient continent should be the prospective area for epithermal gold and copper polymetallic deposits.