由MgMn_2O_4制备新型离子筛吸附剂及其对锂的吸附性质

从Mg、Mn混合溶液制备了镁锰氧化物MgMn_2O_4,并由此制得新型离子筛氧化锰HMnO(Mg)。它在碱金属及碱土金属离子中对Li~+显示了很高的选择性,pH8时分配系数Kd值顺序为Li>>Ca>Mg>K>Na,可以从实际卤水中将Li~+选择性吸附,吸附容量达20.4mg/g,用稀HCI溶液易于将吸附的Lj~+洗脱并使吸附剂再生。经用卤水和HCI五次吸附——洗脱循环,Li~+吸附容量没有降低,洗脱率总是大于90％。     

新疆莫托萨拉铁锰矿的物质成分

莫托萨拉铁锰矿中铁矿石的化学成分以Ｆｅ２Ｏ３为主,ω（Ｆｅ２Ｏ３）可达７８．７６％,其次为ω（ＳｉＯ２）（１０￣５０％）,ω（ＦｅＯ）含量多〈５％。矿物成分以赤铁矿为主,次为玉髓、磁铁矿、镜铁矿、云母等。微量元素以Ｐｂ、Ｚｎ较高,局部Ｃｕ含量较高。稀土元素含量较低。锰矿石中以ＭｎＯ２为主,ω（ＭｎＯ２）可达６０％左右,其次ω（ＳｉＯ２）（１０￣２０％）和Ｆｅ２Ｏ３;矿物组合分为两种类型;一种以菱锰     

江西黄连坑锰矿成矿特征及成因探讨

江西省武宁县境内分布了众多的小型铁、锰矿床(点),前人称之为“武宁式”铁矿。通过对黄连坑锰矿区地层的含矿性、控矿构造及容矿构造、矿体特征、矿石类型等地质特征的论述,认为震旦系地层是“初始矿源层”,滑脱构造对成矿物质起迁移、富集及容矿作用。并与萍—乐断陷盆地内的沉积加热液叠改型乐华锰矿床进行了对比分析,二者在矿体规模、矿石类型、锰品位等方面存在显著差别,应属不同成因类型的矿床。初步认为黄连坑锰矿床属构造控矿、风化淋滤成因。     

单柱离子色谱测定二氧化锰产品中无机阴离子杂质

采用了单柱离子色谱法测ＭｎＯ２产品中无机离子杂质；提出了消除干扰的可行途径，将Ｌａ（ＯＨ）３加入后能同时消除进样峰的干扰和溶剂峰的出现。选用１．７５ｍｍｏｌ／Ｌ邻苯二甲酸１．７５ｍｍｏｌ／Ｌ三羟甲基氨基甲烷为混合淋洗剂测定Ｆ＾－，Ｃｌ＾－，ＮＯ３＾和ＳＯ＾２－４，其标准加入回收率为９５％－１０５％；ＲＳＤ（ｎ＝７）为２．４７％－８．０８％。     

Composition and Useful Properties of Tailings of Marine Manganese Nodules and Crusts

ABSTRACT

Marine manganese nodules and crusts, when processed, yield tailings which may be utilized for environmental and economic benefit. The key to the reasonable and effective utilization of these tailings lies in making a systematic appraisal of their composition and properties. This article gives an introduction to the investigation of manganese tailings properties. The tailings have a high iron and/or manganese content, high surface area, high porosity, and fine grain size. Some tailings have a high rare earth element content which is valuable. They may also have high SO₃, arsenic, and uranium contents which are harmful. Depending on the process used to produce the tailings, there will likely be some differences in chemical composition, mineral assemblages, surface area and adsorption capability, pore diameter and volume, density and pH. In assigning potentially beneficial applications for these tailings, these differences should be taken into account to optimize utilization.     

Resource recovery and remediation of highly alkaline residues: A political-industrial ecology approach to building a circular economy

Highly alkaline industrial residues (e.g., steel slag, bauxite processing residue (red mud) and ash from coal combustion) have been identified as stocks of potentially valuable metals. Technological change has created demand for metals, such as vanadium and certain rare earth elements, in electronics associated with renewable energy generation and storage. Current raw material and circular economy policy initiatives in the EU and industrial ecology research all promote resource recovery from residues, with research so far primarily from an environmental science perspective. This paper begins to address the deficit of research into the governance of resource recovery from a novel situation where re-use involves extraction of a component from a bulk residue that itself represents a risk to the environment. Taking a political industrial ecology approach, we briefly present emerging techniques for recovery and consider their regulatory implications in the light of potential environmental impacts. The paper draws on EU and UK regulatory framework for these residues along with semi-structured interviews with industry and regulatory bodies. A complex picture emerges of entwined ownerships and responsibilities for residues, with past practice and policy having a lasting impact on current possibilities for resource recovery.     

Obituary

Geological sections are still best drawn at natural scale. Sections with vertical exaggerations are rarely drawn correctly, and even when computed carefully give a false notion of the structural features. Many schematic sections which are not drawn to scale and are supposed to explain a proposed new tectonic interpretation give such a distorted and frequently absurd picture of the structural features that they cannot be regarded as valid.     

云南省鹤庆县小天井锰矿的地质特征及盆地控制

小天井锰矿是滇西地区最大的锰矿床, 产于滇西上三叠统松桂组碎屑岩建造中, 由氧化锰矿石和碳酸锰矿石组成, 矿石成份较单一。碳和氧同位素的特征揭示了成矿物源的多来源及成矿的多阶段特征。稀土配分模式属轻稀土富集型。鹤庆锰矿形成于扬子地块西缘三叠纪诺利期盐源—丽江盆地中的丽江凹陷带之内的一个次级叠加盆地。盆地和成矿作用受控于同生断裂活动。建立了成矿模式。     

氧化锰矿物的生物成因及其性质的研究进展

土壤中的氧化锰矿物是原生矿物风化和成土过程的产物,是最具反应活性的一类矿物,决定着环境中许多物质的形态、迁移和转化,在元素生物地球化学循环中起着重要的作用,其形成机制和环境效应备受关注。已有的研究表明,环境中氧化锰的形成与微生物作用紧密相关,微生物作用可使自然环境中的Mn(Ⅱ)氧化速率提高105倍。参与Mn(Ⅱ)氧化的微生物在环境中广泛存在,已知的典型锰氧化细菌分布在变形菌门、放线菌门或厚壁菌门,它们均通过胞外聚合物中的多铜氧化酶来催化氧化Mn(Ⅱ)。细菌氧化Mn(II)成Mn(Ⅳ)是酶催化的两个连续的快速单电子传递过程,Mn(Ⅲ)在溶液中以与酶结合的瞬时中间态出现。生物形成氧化锰的最初形态为层状锰矿物,与δ-MnO2或酸性水钠锰矿很类似,且结晶弱,粒径小,锰氧化度高,结构中的八面体空穴多,因而比化学形成的氧化锰具有更强的吸附、氧化等表面活性。环境中Mn(Ⅱ)微生物氧化及形成的Mn(Ⅲ)中间体与碳、氮、硫等生命元素的地球化学循环的关系令人关注。     

广西忻城县里苗-塘岭锰矿床控矿因素及成矿模式

广西宜州市龙头锰矿是我国石炭系锰矿的典型代表。2014~2016年,中国冶金地质总局广西地质勘查院在南丹-宜州地区开展矿产地质调查工作取得了新的突破,圈定了弄竹、塘岭找矿靶区。两个靶区经后续广西地勘资金勘查,在里苗-塘岭一带估算锰矿资源量达8000多万吨,成为我国石炭系最大的锰矿。为了揭示该矿床的成矿机制,本文从区域成矿地质背景、矿床地质特征、构造环境、岩相古地理、锰质来源、矿化富集规律等方面分析了其控矿因素,圈定了成锰盆地边界线,建立了成矿模式。认为里苗-塘岭锰矿床是受NE向同沉积断裂控制的海底热水沉积矿床,是走滑拉张断陷-含锰热水-台沟相沉积环境耦合作用的产物。