我国石墨矿产地质特征及资源潜力分析

石墨是我国重要的大宗优势非金属矿产,其既具有非金属矿物的一般性能,又兼有金属和有机塑料的某些特性,是用途广泛的特殊的非金属矿物原料,是我国新兴产业的重要原材料。我国石墨成因类型主要为区域变质型,其工业价值较大。文章通过对我国石墨矿产分布特征、成矿规律分析进而总结石墨资源潜力特征,认为我国黑龙江、内蒙古、四川等省资源潜力巨大,可实行保护性开采,从而获取经济效益。     

珠江三角洲地区地下水锰的分布特征及其成因

为了解珠江三角洲地区地下水中锰的含量及其成因,笔者采集并分析了352组地下水样和13组地表水样。结果表明:珠江三角洲地区地下水的锰含量在未检出至8.32mg/L之间,平均浓度为0.34mg/L,超标率达49.4%。在该区9个地级市范围都存在地下水锰超标现象。区内地下水的锰含量与总溶解固体(TDS)、化学需氧量(COD)以及HCO3ˉ都呈极显著的正相关关系,而与Eh呈极显著的负相关关系。珠江三角洲地区地下水中锰含量的分布与该地区的工业化程度以及所处的补、径、排条件密切相关。影响该地区地下水锰含量分布的因素主要有氧化还原环境、酸碱条件、地下水的总溶解固体、上覆盖层性质、地下水径流条件以及含水层介质等。     

内蒙古自治区重要矿种成矿规律综述

2007~2013年开展的内蒙古矿产资源潜力评价项目,对铁、铜、铅锌、金、银、钨、钼、铬、镍等重要矿种进行了区域成矿规律总结,为矿产资源潜力评价提供了基础资料。文章即是对该项工作部分成果的概括总结。主要进展包括:在全国Ⅲ级成矿区带划分的基础上,首次进行了覆盖全自治区的Ⅳ级成矿亚带的划分,共划分出34个Ⅳ级成矿亚带;对内蒙古铁、铜等11个重要矿种的主要矿床类型及成矿特征进行了概述,对其时空分布规律做了归纳,认为全区70%以上的矿床数量和资源储量均集中在Ⅲ_5、Ⅲ_6、Ⅲ_8、Ⅲ_10和Ⅲ_11五个成矿区带。此外,不同矿种甚至同一矿种,由于成矿地质背景的差异,在不同的三级区带中的分布也不一样。主要成矿期为元古宙和中生代,次为太古宙和晚古生代,不同矿种的重要成矿期也不完全相同。从区域演化的角度探讨了构造与成矿的关系,认为不同的构造演化阶段形成不同的矿床类型和不同矿种的矿床,其中,古大陆边缘裂谷带以白云鄂博式铁_稀土元素矿床为代表,而大兴安岭岩浆岩带则以产出与燕山期中酸性火山侵入杂岩有关的多金属矿产为特点。     

硫化物固—液界面电化学效应实验探讨

硫化物作为一类重要的常见矿物，目前国内外对其表面矿物学特征研究有限。具体到硫化物固－液界面处的行为机理，前人的研究程度就更低了。笔者自行设计了一个Fe1-xS-Cr^6 原电池，通过实测电动势（E），t-E关系曲线，溶液可见光吸收谱及其λ－A关系曲线，阐明硫化物与Cr^6＋溶液间的界面行为机理。认为其界面行为过程为；硫化物溶解→离子反应（氧化还原）→吸附Cr^3 。该原电池与一般原电池结构不同，其主要差别在于将反应电极和测量电极分开，从而解决电极反应过程中的浓度极化问题，提高了电化学实验的精度。该研究成果有助于揭示矿物－液体相互作用机理，完善和丰富表面矿物学研究内容，深化化界面成矿理论，并对环境治理，矿物材料应用等开发领域具有重要的参考价值。     

加权Logistic回归模型在火山岩型铜矿预测中的应用:以宁芜盆地中段为例

文中探讨了加权Logistic回归模型在宁芜盆地中段火山岩型铜矿预测中的应用。首先,结合研究区的成矿地质背景,提取地质体、构造、围岩蚀变三大类证据因子;其次,分析各证据因子与铜矿点之间的空间关系,认为姑山旋回、娘娘山旋回火山机构控制了本区火山岩型铜矿的空间分布,根据计算结果,选取与火山岩型铜矿密切相关的龙王山组、姑山组地层,姑山旋回粗面斑岩、娘娘山旋回二长斑岩、NW向构造1.5 km缓冲区、NE向构造1.3 km缓冲区、EW向构造4.5 km缓冲区、硅化、褐铁矿化、黄铜矿化等作为模型自变量;最后采用加权Logistic回归模型进行成矿概率计算,并结合成矿地质背景,圈定四个成矿远景区,分别为P1、P2、P3、P4,其中P1、P2、P3呈北东向展布,主要受娘娘山和姑山火山机构控制,P4为东西向分布,主要受龙王山火山机构控制,在这些预测区中,均存在已发现的铜矿体,说明预测可信度较高。     

花岗岩上发育的亚热带红土岩石磁学特征

本文对发育于花岗岩上的两个亚热带红土剖面进行了系统的岩石磁学研究,测试了磁化率、频率磁化率、等温剩磁、非磁滞剩磁、磁滞回线等常温磁学参数,选取代表性样品进行了高低温岩石磁学分析,拟探讨亚热带红土磁性矿物的特征及湿热环境下土壤中磁性矿物的转化规律。实验结果表明：亚热带红土的强磁性矿物为磁铁矿、磁赤铁矿;弱磁性矿物为赤铁矿和针铁矿,滞水土层中含有纤铁矿。花岗岩具有较强的磁性,在其上发育的红土也因此具有较强的磁性。花岗岩中的亚铁磁性矿物的磁畴以多畴占主导地位,随着风化强度的增强,逐渐形成较细粒的超顺磁与单畴磁性矿物。亚热带红土中的磁赤铁矿与位于半干旱区黄土高原成土作用形成的磁赤铁矿存在着磁学性质上的差异,表现为具有更高的居里点（约600℃和640℃）,可能说明亚热带红土中的磁赤铁矿粒径更粗。两个剖面在磁学性质上存在着明显的差异,泉州剖面磁性矿物以磁铁矿为主,磁化率最高可达1823×10-8m3/kg,平均值为1033.1×10-8m3/kg,具有较低的剩磁矫顽力;福州剖面磁性矿物以磁铁矿和部分热稳定磁赤铁矿为主,磁化率最高为385.73×10-8m3/kg,平均值为91.5×10-8m3/kg。基于磁学参数分析,认为母质与后期成土作用共同造成了两个剖面的磁学性质差异,但后者起主导作用。磁化率在两个剖面中,均随着深度减小而减小,与温带地区表层土磁化率增强有很大区别。湿热环境条件下,强磁性矿物溶解或转化为弱磁性矿物的程度主导剖面磁化率变化。     

泌阳凹陷地质流体对砂岩储集层中黏土矿物形成和分布的控制作用

运用扫描电镜观察和X射线衍射分析等技术,在对泌阳凹陷核桃园组砂岩储集层中黏土矿物分布特征研究的基础上,从黏土矿物的形成条件和形成过程入手,详细分析了地质流体的性质、组成、流动方式、迁移速度等对砂岩储集层中黏土矿物形成和分布的影响,指出砂岩储集层中参与成岩反应的碎屑活性组分和地质流体对砂岩储集层中黏土矿物的形成和分布具有控制作用,并讨论了它们的形成机理.研究表明,黏土矿物的形成和分布能够不同程度地影响砂岩储集层的孔渗性和含油气性;高岭石发育层段与次生孔隙的发育和渗透率的增加以及油气的富集层段具有良好的对应关系.     

Mineral chemistry,crystallization conditions and magma mixing‐mingling at Orduzu volcano (Malatya), Eastern Anatolia,Turkey

The Middle Miocene Orduzu volcanic suite, which is a part of the widespread Neogene Yamadağ volcanism of Eastern Anatolia, consists of a rhyolitic lava flow, rhyolitic dykes, a trachyandesitic lava flow and basaltic trachyandesitic dykes. Existence of mafic enclaves and globules in some of the volcanic rocks, and microtextures in phenocrysts indicate that magma mingling and mixing between andesitic and basaltic melts played an important role in the evolution of the volcanic suite. Major and trace element characteristics of the volcanic rocks are similar to those formed in convergent margin settings. In particular, incompatible trace element patterns exhibit large depletions in high field strength elements (Nb and Ta) and strong enrichments in both large ion lithofile elements (Ba, Th and U) and light rare earth elements, indicating a strong subduction signature in the source of the volcanic rocks. Furthermore, petrochemical data obtained suggest that parental magmas of rhyolite lava and dykes, and trachyandesite lava and basaltic trachyandesite dykes were derived from subduction‐related enriched lithospheric mantle and metasomatized mantle (± asthenosphere), respectively. A detailed mineralogical study of the volcanic suite shows that plagioclase is the principal phenocryst phase in all of the rock units from the Orduzu volcano. The plagioclase phenocrysts are accompanied by quartz in the rhyolitic lava flows and by two pyroxenes in the trachyandesitic lava flows and basaltic trachyandesitic dykes. Oxide phases in all rocks are magnetite and ilmenite. Calculated crystallization temperatures range from 650°C to 800°C for plagioclase, 745°C–1054°C for biotite, 888°C–915°C for pyroxene and 736°C–841°C for magnetite–ilmenite pairs. Calculated crystallization pressures of pyroxenes vary between 1.24–5.81 kb, and oxygen fugacity range from −14.47 to −12.39. The estimates of magmatic intensive parameters indicate that the initial magma forming the Orduzu volcanic unit began to crystallize in a high‐level magma chamber and then was stored in a shallow reservoir where it underwent intermediate‐mafic mixing. The rhyolitic lava flow and dykes evolved in relatively shallower crustal magma chambers. Copyright © 2007 John Wiley & Sons, Ltd.     

Silicate‐oxide mineral chemistry of mafic–ultramafic rocks as an indicator of the roots of an island arc: The Chilas Complex,Kohistan (Pakistan)

The Chilas Complex is a major lower crustal component of the Cretaceous Kohistan island arc and one of the largest exposed slices of arc magma chamber in the world. Covering more than 8000 km², it reaches a current tectonic width of around 40 km. It was emplaced at 85 Ma during rifting of the arc soon after the collision of the arc with the Karakoram plate. Over 85% of the Complex comprises homogeneous, olivine‐free gabbronorite and subordinate orthopyroxene–quartz diorite association (MGNA), which contains bodies of up to 30 km² of ultramafic–mafic–anorthositic association (UMAA) rocks. Primary cumulate textures, igneous layering, and sedimentary structures are well preserved in layered parts of the UMAA in spite of pervasive granulite facies metamorphism. Mineral analyses show that the UMAA is characterized by more magnesian and more aluminous pyroxene and more calcic plagioclase than those in the MGNA. High modal abundances of orthopyroxene, magnetite and ilmenite (in MGNA), general Mg–Fe–Al spatial variations, and an MFA plot of whole‐rock analyses suggest a calc‐alkaline origin for the Complex. Projection of the pyroxene compositions on the Wo–En–Fs face is akin to those of pyroxenes from island arcs gabbros. The presence of highly calcic plagioclase and hornblende in UMAA is indicative of hydrous parental arc magma. The complex may be a product of two‐stage partial melting of a rising mantle diaper. The MGNA rocks represent the earlier phase melting, whereas the UMAA magma resulted from the melting of the same source depleted by the extraction of the earlier melt phase. Some of the massive peridotites in the UMAA may either be cumulates or represent metasomatized and remobilized upper mantle. The Chilas Complex shows similarities with many other (supra)subduction‐related mafic–ultramafic complexes worldwide.     

多源数据融合技术及其在地质矿产调查中应用

针对地质矿产调查的特点,介绍了多源数据融合技术的概念、基本方法,总结归纳了其在地质矿产调查中工作流程、实施步骤、注意事项,分析了多源数据融合技术在地质矿产调查中的应用意义。结合新疆黑山岭东南一带1：50000区域地质矿产调查项目,采用多源数据融合技术,在构造信息和矿化蚀变信息提取中,对遥感图像数据和地质、地球物理、地球化学数据进行了融合处理和叠合显示,取得了较好的地质效果。